Industrial carbon dioxide capture and utilization: state of the art and future challenges

Chemical Society Reviews, Journal Year: 2020, Volume and Issue: 49(23), P. 8584 - 8686

Published: Jan. 1, 2020

This review covers the sustainable development of advanced improvements in CO₂capture and utilization.

Language: Английский

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Highlights and challenges in the selective reduction of carbon dioxide to methanol

Nature Reviews Chemistry, Journal Year: 2021, Volume and Issue: 5(8), P. 564 - 579

Published: June 24, 2021

Language: Английский

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Accessing Organonitrogen Compounds via C–N Coupling in Electrocatalytic CO₂ Reduction

Journal of the American Chemical Society, Journal Year: 2021, Volume and Issue: 143(47), P. 19630 - 19642

Published: Nov. 17, 2021

Given the limited product variety of electrocatalytic CO2 reduction reactions solely from and H2O as reactants, it is desirable to expand scope by introducing additional reactants that provide elemental diversity. The integration inorganic heteroatom-containing into could, in principle, enable sustainable synthesis valuable products, such organonitrogen compounds, which have widespread applications but typically rely on NH3 derived energy-intensive fossil-fuel-dependent Haber–Bosch process for their industrial-scale production. In this Perspective, research progress toward building C–N bonds N-integrated highlighted, electrosyntheses urea, acetamides, amines are examined standpoints reactivity, catalyst structure, and, most fundamentally, mechanism. Mechanistic discussions coupling these advances emphasized critically evaluated, with aim directing future investigations improving yield broadening reduction.

Language: Английский

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Applications, challenges, and needs for employing synthetic biology beyond the lab

Nature Communications, Journal Year: 2021, Volume and Issue: 12(1)

Published: March 2, 2021

Abstract Synthetic biology holds great promise for addressing global needs. However, most current developments are not immediately translatable to ‘outside-the-lab’ scenarios that differ from controlled laboratory settings. Challenges include enabling long-term storage stability as well operating in resource-limited and off-the-grid using autonomous function. Here we analyze recent advances developing synthetic biological platforms outside-the-lab with a focus on three major application spaces: bioproduction, biosensing, closed-loop therapeutic probiotic delivery. Across the Perspective, highlight advances, areas further development, possibilities future applications, needs innovation at interface of other disciplines.

Language: Английский

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Enzymes, In Vivo Biocatalysis, and Metabolic Engineering for Enabling a Circular Economy and Sustainability

Chemical Reviews, Journal Year: 2021, Volume and Issue: 121(17), P. 10367 - 10451

Published: July 6, 2021

Since the industrial revolution, rapid growth and development of global industries have depended largely upon utilization coal-derived chemicals, more recently, petroleum-based chemicals. These developments followed a linear economy model (produce, consume, dispose). As world is facing serious threat from climate change crisis, sustainable solution for manufacturing, i.e., circular in which waste same or different can be used as feedstocks resources production offers an attractive industrial/business model. In nature, biological systems, microorganisms routinely use their enzymes metabolic pathways to convert organic inorganic wastes synthesize biochemicals energy required growth. Therefore, understanding how selected biobased into special (bio)chemicals serves important basis build on applications biocatalysis, engineering, synthetic biology enable processes that are greener cleaner environment. This review article highlights current state knowledge regarding enzymatic reactions converting (lignocellulosic biomass, sugar, phenolic acid, triglyceride, fatty glycerol) greenhouse gases (CO2 CH4) value-added products discusses progress made engineering. The commercial aspects life cycle assessment engineering also discussed. Continued field would offer diversified solutions renewable manufacturing valuable

Language: Английский

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Metabolic engineering strategies to enable microbial utilization of C1 feedstocks

Nature Chemical Biology, Journal Year: 2021, Volume and Issue: 17(8), P. 845 - 855

Published: July 26, 2021

Language: Английский

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Green Chemistry, Biocatalysis, and the Chemical Industry of the Future

ChemSusChem, Journal Year: 2022, Volume and Issue: 15(9)

Published: Jan. 13, 2022

In the movement to decarbonize our economy and move away from fossil fuels we will need harness waste products of activities, such as lignocellulose, methane, carbon dioxide. Our wastes be integrated into a circular where used are recycled manufacturing cycle. Key this recycling plastics at resin monomer levels. Biotechnology is well suited future chemical industry that must adapt widely distributed diverse biological feedstocks. increasing mastery biotechnology allowing us develop enzymes organisms can synthesize widening selection desirable bulk chemicals, including plastics, commercially viable productivities. Integration bioreactors with electrochemical systems permit new production opportunities enhanced productivities advantage using low-carbon electricity renewable sustainable sources.

Language: Английский

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Enzymatic Conversion of CO₂: From Natural to Artificial Utilization

Chemical Reviews, Journal Year: 2023, Volume and Issue: 123(9), P. 5702 - 5754

Published: Jan. 24, 2023

Enzymatic carbon dioxide fixation is one of the most important metabolic reactions as it allows capture inorganic from atmosphere and its conversion into organic biomass. However, due to often unfavorable thermodynamics difficulties associated with utilization CO

Language: Английский

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Light-driven CO2 sequestration in Escherichia coli to achieve theoretical yield of chemicals

Nature Catalysis, Journal Year: 2021, Volume and Issue: 4(5), P. 395 - 406

Published: April 29, 2021

Language: Английский

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Metabolic Engineering: Methodologies and Applications

Chemical Reviews, Journal Year: 2022, Volume and Issue: 123(9), P. 5521 - 5570

Published: Dec. 30, 2022

Metabolic engineering aims to improve the production of economically valuable molecules through genetic manipulation microbial metabolism. While discipline is a little over 30 years old, advancements in metabolic have given way industrial-level molecule benefitting multiple industries such as chemical, agriculture, food, pharmaceutical, and energy industries. This review describes design, build, test, learn steps necessary for leading successful campaign. Moreover, we highlight major applications engineering, including synthesizing chemicals fuels, broadening substrate utilization, improving host robustness with focus on specific case studies. Finally, conclude discussion perspectives future challenges related engineering.

Language: Английский

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