ACS Nano,
Journal Year:
2021,
Volume and Issue:
15(12), P. 19600 - 19612
Published: Nov. 17, 2021
As
interest
continues
to
grow
in
Ti3C2Tx
and
other
related
MXenes,
advancement
methods
of
manipulation
their
surface
functional
groups
beyond
synthesis-based
terminations
(Tx:
-F,
-OH,
═O)
can
provide
mechanisms
enhance
solution
processability
as
well
produce
improved
solid-state
device
architectures
coatings.
Here,
we
report
a
chemically
important
modification
approach
which
"solvent-like"
polymers,
polyethylene
glycol
carboxylic
acid
(PEG6-COOH),
are
covalently
attached
onto
MXenes
via
esterification
chemistry.
Surface
with
PEG6-COOH
large
ligand
loading
(up
14%
by
mass)
greatly
enhances
dispersibility
wide
range
nonpolar
organic
solvents
(e.g.,
2.88
mg/mL
chloroform)
without
oxidation
two-dimensional
flakes
or
changes
the
structure
ordering.
Furthermore,
cooperative
interactions
between
polymer
chains
improve
nanoscale
assembly
uniform
microstructures
stacked
MXene-PEG6
into
ordered
thin
films
excellent
electrical
conductivity
(∼16,200
S·cm-1).
Most
importantly,
our
covalent
ω-functionalized
PEG6
ligands
(ω-PEG6-COOH,
where
ω:
-NH2,
-N3,
-CH═CH2)
allows
for
control
over
degree
functionalization
(incorporation
valency)
MXene.
We
believe
that
installing
valency
through
short,
ion
conducting
PEG
compromising
MXenes'
features
such
processability,
structural
stability,
further
chemistry
tunability
performance
widens
applications.
Micromachines,
Journal Year:
2023,
Volume and Issue:
14(2), P. 247 - 247
Published: Jan. 18, 2023
The
first
two-dimensional
(2D)
substance
sparked
a
boom
in
research
since
this
type
of
material
showed
potential
promise
for
applications
field
sensors.
A
class
2D
transition
metal
nitrides,
carbides,
and
carbonitrides
are
referred
to
as
MXenes.
Following
the
2011
synthesis
Ti3C2
from
Ti3AlC2,
much
has
been
published.
Since
these
materials
have
several
advantages
over
conventional
materials,
they
extensively
researched,
synthesized,
studied
by
many
organizations.
To
give
readers
general
understanding
well-liked
review
examines
structures
MXenes,
discusses
various
procedures,
analyzes
physicochemistry
properties,
particularly
optical,
electronic,
structural,
mechanical
properties.
focus
is
analysis
modern
advancements
development
MXene-based
sensors,
including
electrochemical
gas
biosensors,
optical
wearable
Finally,
opportunities
challenges
further
study
on
creation
MXenes-based
sensors
discussed.
ACS Nano,
Journal Year:
2023,
Volume and Issue:
17(20), P. 19526 - 19549
Published: Oct. 7, 2023
The
reconstruction
engineering
of
tissue
defects
accompanied
by
major
diseases
including
cancer,
infection,
and
inflammation
is
one
the
important
challenges
in
clinical
medicine.
development
innovative
strategies
such
as
multifunctional
bioactive
materials
presents
a
great
potential
to
overcome
challenge
disease-impaired
regeneration.
As
representative
two-dimensional
nanomaterials,
MXenes
have
shown
physicochemical
properties
been
diffusely
studied
multimodal
nanoplatforms
field
biomedicine.
This
review
summarized
recent
advances
integrated
regeneration-therapy
applications
MXene-based
biomaterials,
regeneration-tumor
therapy,
regeneration-infection
regeneration-inflammation
therapy.
recognized
good
candidates
for
promoting
regeneration
treating
through
photothermal
regulating
cell
behavior,
drug
gene
delivery.
current
future
perspectives
biomaterials
are
also
discussed
well
this
review.
In
summary,
promising
disease
treatment
due
their
favorable
functions.
However,
there
still
many
obstacles
that
must
be
addressed
understanding
mechanism,
ensuring
long-term
biosafety,
improving
targeting
therapy
capacity.
The Chemical Record,
Journal Year:
2024,
Volume and Issue:
24(4)
Published: Feb. 22, 2024
Abstract
MXenes
are
two‐dimensional
nanomaterials
with
unique
properties
that
widely
used
in
various
fields
of
research,
mostly
the
field
energy.
Fewer
publications
devoted
to
MXene
application
biomedicine
and
question
is:
safe
for
use
biological
systems?
The
sharp
edges
provide
structure
”nanoknives“
which
cause
damage
direct
physical
contact
cells.
This
is
effectively
antibacterial
research.
However,
on
other
hand,
most
studies
cultured
cells
rodents
report
they
do
not
obvious
signs
cytotoxicity
fully
biocompatible.
aim
our
review
was
consider
whether
can
really
be
considered
non‐toxic
Often
last
two
concepts
confused.
We
first
reviewed
aspects
such
as
stability
biodegradation
MXenes,
then
analyzed
mechanisms
toxicity
their
consequences
bacteria,
cells,
rodents,
subsequent
conclusions
regarding
biocompatibility.
Journal of Materials Chemistry A,
Journal Year:
2024,
Volume and Issue:
12(29), P. 17992 - 18046
Published: Jan. 1, 2024
Supercapacitors
are
widely
recognized
as
a
favorable
option
for
energy
storage
due
to
their
higher
power
density
compared
batteries,
despite
lower
density.
ACS Applied Nano Materials,
Journal Year:
2024,
Volume and Issue:
7(9), P. 9847 - 9867
Published: May 1, 2024
MXene
Ti3C2Tx
is
a
two-dimensional
(2D)
nanosheet
material
from
the
family
formed
by
selective
etching
of
aluminum
atoms
in
ternary
carbide
Ti3AlC2
sheet.
This
process
results
2D
with
titanium
and
fluorine
on
surface.
has
several
attractive
properties
for
various
applications,
such
as
excellent
electrical
conductivity
mechanical
good
chemical
stability.
also
large
surface
area
can
be
easily
functionalized
introducing
different
groups
onto
its
Some
notable
applications
include
supercapacitors
batteries
owing
to
high
area.
been
explored
catalyst
reactions,
including
hydrogen
evolution
CO2
reduction.
The
main
emphasis
this
review
centered
around
exploring
electrical,
magnetic,
optical
characteristics
MXenes.
Additionally,
it
provides
concise
overview
approaches
used
synthesizing
these
materials,
specifically
top-down
bottom-up
methods.
Furthermore,
thoroughly
examines
significant
MXenes
across
multiple
fields,
encompassing
biology,
water
remediation,
sensors,
catalysis,
energy
storage,
membrane
separation,
wearable
electronics.
considers
challenges
that
arise
when
working
offers
insights
into
potential
future
directions
perspectives
field.
Overall,
promising
widespread
application
research
ongoing.
Advances in Colloid and Interface Science,
Journal Year:
2024,
Volume and Issue:
331, P. 103243 - 103243
Published: June 24, 2024
The
recent
rise
of
2D
materials
has
extended
the
opportunities
tuning
a
variety
properties.
Tribo-corrosion,
complex
synergy
between
mechanical
wear
and
chemical
corrosion,
poses
significant
challenges
across
numerous
industries
where
are
subjected
to
both
tribological
stressing
corrosive
environments.
This
intricate
interplay
often
leads
accelerated
material
degradation
failure.
review
critically
assesses
current
state
utilizing
nanomaterials
enhance
tribo-corrosion
-oxidation
behavior.
paper
summarizes
fundamental
knowledge
about
mechanisms
before
assessing
key
contributions
materials,
including
graphene,
transition
metal
chalcogenides,
hexagonal
boron
nitride,
MXenes,
black
phosphorous,
regarding
resulting
friction
protective
roles
these
against
corrosion
oxidation
investigated,
highlighting
their
potential
in
mitigating
degradation.
Furthermore,
we
delve
into
nuanced
factors
specific
application
for
protection.
synthesis
findings
underscores
advancements
achieved
through
integrating
nanomaterials.
An
outlook
future
research
directions
is
provided,
identifying
unexplored
avenues,
proposing
strategies
propel
field
forward.
analysis
aims
at
guiding
investigations
developments
dynamic
intersection
nanomaterials,
tribo-corrosion,
