Materials Today Catalysis,
Journal Year:
2024,
Volume and Issue:
5, P. 100052 - 100052
Published: May 22, 2024
This
review
delves
into
the
underlying
principles,
advantages,
challenges,
and
recent
developments
in
photoelectrocatalysis
(PEC)
processes
for
wastewater
treatment
green
hydrogen
production.
PEC
is
an
emerging
technique
that
holds
great
promise
addressing
two
critical
challenges
simultaneously,
namely,
degradation
of
industrial
pollutants
generation
clean
energy
form
gas.
In
years,
many
studies
have
explored
use
photoanodes
to
harness
solar
treatment.
These
facilitate
breakdown
contaminants,
while
cathode
concurrently
produces
hydrogen.
The
enables
production
both
water
gas
from
wastewater.
dual
benefit
makes
it
attractive
avenue
sustainable
generation.
process
capitalizes
on
constructive
interaction
between
electrochemical
reactions
photocatalysis.
Solar
efficiently
converted
electron-hole
pairs,
which
play
a
pivotal
role
water-splitting
occurring
at
electrode
surfaces.
Achieving
best
performance
involves
scrutiny
various
parameters,
including
catalyst
loading,
pH,
light
intensity,
electrolyte
composition.
photoelectrocatalytic
system
shows
commendable
stability
durability
during
extended
operation,
reinforcing
its
practical
applicability.
provides
comprehensive
overview
process,
materials,
optimization
strategies,
driving
efficiency.
Considering
potential
benefits
costs
larger
scale
underscores
significance
environmental
concerns
energy-related
issues
concurrently.
Therefore,
promising
pathway
toward
energy,
bridging
gap
stewardship
technological
advancement.
Reactions,
Journal Year:
2024,
Volume and Issue:
5(1), P. 135 - 194
Published: Feb. 1, 2024
Contemporary
technological
and
industrial
advancements
have
led
to
increased
reliance
on
chemicals
for
product
innovation,
leading
heightened
contamination
of
water
sources
by
traditional
pollutants
(organic
dyes,
heavy
metals)
disease-causing
microorganisms.
Wastewater
treatment
processes
now
reveal
“emerging
pollutants”,
including
pharmaceuticals,
endocrine
disruptors,
agricultural
chemicals.
While
some
are
benign,
certain
emerging
can
harm
diverse
organisms.
Researchers
seek
cost-effective
purification
methods
that
completely
degrade
without
generating
harmful
by-products.
Semiconductor-based
photocatalytic
degradation,
particularly
using
titanium
dioxide
(TiO2),
is
popular
addressing
pollution.
This
study
focuses
recent
applications
TiO2
nanostructures
in
photocatalysis
eliminating
various
pollutants.
Structural
modifications,
like
doping
nanocomposite
formation,
enhance
photocatalyst
performance.
The
emphasizes
elimination
mechanisms
comprehensively
discusses
factors
impacting
both
the
mechanism
performance
nano-TiO2-based
photocatalysts.
Characteristics
TiO2,
such
as
crystal
structure
energy
band-gap,
along
with
its
activity
mechanism,
presented.
review
covers
advantages
limitations
different
nanostructure
production
approaches
addresses
potential
toxicity
human
health
environment.
In
summary,
this
provides
a
holistic
perspective
applying
nano-TiO2
materials
mitigate