Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: unknown, P. 160151 - 160151
Published: Feb. 1, 2025
Language: Английский
Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: unknown, P. 160151 - 160151
Published: Feb. 1, 2025
Language: Английский
Frontiers in Energy, Journal Year: 2025, Volume and Issue: unknown
Published: Feb. 28, 2025
Language: Английский
Citations
1Sensors and Actuators B Chemical, Journal Year: 2023, Volume and Issue: 396, P. 134560 - 134560
Published: Sept. 8, 2023
Language: Английский
Citations
21Materials Chemistry Frontiers, Journal Year: 2023, Volume and Issue: 7(6), P. 1004 - 1024
Published: Jan. 1, 2023
This review focuses on the synthetic strategies and characterization methods of atomic cation vacancies in 2D nanosheets their energy-related applications.
Language: Английский
Citations
20Chemical Synthesis, Journal Year: 2023, Volume and Issue: 3(4)
Published: Nov. 3, 2023
Two-dimensional (2D) materials have garnered much interest due to their exceptional optical, electrical, and mechanical properties. Strain engineering, as a crucial approach modulate the physicochemical characteristics of 2D materials, has been widely used in various fields, especially for energy storage conversion. Herein, recent progress strain engineering is summarized conversion applications. The fundamental understanding first described. Then, some synthetic methods modulating properties via are introduced. Further, applications storage, photocatalysis, electrocatalysis discussed. Finally, challenges perspectives on also outlined.
Language: Английский
Citations
18Chemical Engineering Journal, Journal Year: 2023, Volume and Issue: 479, P. 147453 - 147453
Published: Nov. 16, 2023
Language: Английский
Citations
18Chinese Journal of Chemistry, Journal Year: 2023, Volume and Issue: 41(12), P. 1443 - 1449
Published: Feb. 17, 2023
Comprehensive Summary Copper (Cu) is recognized as one of the most efficient metal catalysts that can perform electrocatalytic CO 2 reduction reaction (CO RR) and its surface oxidation state determines pathway. The Cu δ + (0 < 1) species, are well known active sites in RR to produce hydrocarbons oxygenates. However, difficult control, it very easy be reduced 0 under operating conditions. Herein, we report a homo‐hetero doping strategy construct an samarium (Sm) sulfur (S) co‐doping catalyst (Sm x ‐CuS y ) for formic acid (HCOOH). At optimum conditions, Sm delivered high HCOOH Faradaic efficiency (FE) 92.1% at current density 300 mA·cm –2 using 1 mol/L KOH aqueous solution electrolyte, potential was low –0.52 V vs. reversible hydrogen electrode (RHE). S resulted excellent performance owing synergistic effect structure. homo‐doping could effectively adjust electronic structure favor formation abundant species. existence hetero‐Sm species not only stabilize sites, but also increase concentration H ions form favorable catalytic environment generation.
Language: Английский
Citations
17Journal of Colloid and Interface Science, Journal Year: 2024, Volume and Issue: 672, P. 600 - 609
Published: June 5, 2024
Language: Английский
Citations
8ACS Nano, Journal Year: 2024, Volume and Issue: 18(15), P. 10582 - 10595
Published: April 2, 2024
CO2 conversion with pure H2O into CH3OH and O2 driven by solar energy can supply fuels life-essential substances for extraterrestrial exploration. However, the effective production of is significantly challenging. Here we report an organozinc complex/MoS2 heterostructure linked well-defined zinc–sulfur covalent bonds derived structural deformation intensive coupling dx2 – y2(Zn)-p(S) orbitals at interface, resulting in distinctive charge transfer behaviors excellent redox capabilities as revealed experimental characterizations first-principle calculations. The synthesis strategy further generalized to more organometallic compounds, achieving various heterostructures photoreduction. optimal catalyst delivers a promising yield 2.57 mmol gcat–1 h–1 selectivity than 99.5%. reverse water gas shift mechanism identified methanol formation. Meanwhile, energy-unfavorable adsorption on MoS2, where photogenerated holes accumulate, ensures selective oxidation over methanol.
Language: Английский
Citations
7ACS Catalysis, Journal Year: 2024, Volume and Issue: 14(18), P. 14098 - 14109
Published: Sept. 10, 2024
Language: Английский
Citations
7Catalysts, Journal Year: 2024, Volume and Issue: 14(9), P. 575 - 575
Published: Aug. 29, 2024
This review critically examines the latest advancements in clay mineral-based photocatalysts for water purification. Clay minerals, owing to their natural abundance, low cost, and unique physicochemical properties, have emerged as promising candidates enhancing photocatalytic efficiency. article delves into various activation methods including acid, alkali, calcination, mechanochemical activation, highlighting roles surface area, creating active sites, improving performance. Moreover, explores modification strategies photocatalysts, such doping with metal non-metal ions, deposition of metals, design heterojunctions, further boost activity. In particular, utilization kaolinite, montmorillonite, attapulgite, sepiolite mineral supports is discussed detail, showcasing potential wastewater treatment. The underscores significant strides made development effectiveness degrading organic contaminants under light exposure. Nevertheless, there are persisting challenges optimization loading quantities, improvement compatibility between minerals reduction preparation costs large-scale applications. summary, this offers valuable insights current status purification, thereby stimulating future research field.
Language: Английский
Citations
6