Simulating Detection of Dioxin-like Pollutants with 2D Surface Enhanced Raman Spectroscopy using h-BNC Substrates DOI Open Access

Raúl Alvarado,

Nicolás Otero, Marcos Mandado

et al.

Published: April 5, 2023

The ability of 2D hybrid structures formed by boron, nitrogen and carbon atoms (h-BNCs) as potential substrates for surface enhanced Raman spectroscopy (SERS) detection dioxin-like pollutants is theoretically analyzed. strong confinement high tunability the electromagnetic response nanostructures embedded within h-BNC sheets point out that these could be promising applications in optical spectroscopies, such SERS. In this work, two model pollutants, TCDD TCDF, a composed nanodisk ninety-six surrounded string borazine rings, BNC96, are employed simulation adsorption complexes static pre-resonance spectra adsorbed molecules. A large affinity BNC96 reflected on interaction energies obtained most stable stacking complexes, with dispersion being important contribution to their stability. vibrational coupling some active modes TCDF and, specially, makes display ‘pure’ chemical enhancement one order magnitude. On other hand, due confined nanodisk, factors 108 107, respectively. Promisingly, laser excitation wavelengths frequently used SERS experiments also provoke significant enhancements, around 104, signals. Both domains modulation resonance visible and/or UV ranges h-BNCs should lead higher sensitivity than graphene white parent structures, solving main disadvantages using applications.

Language: Английский

Recent Trends in SERS-Based Plasmonic Sensors for Disease Diagnostics, Biomolecules Detection, and Machine Learning Techniques DOI Creative Commons
Reshma Beeram,

Kameswara Rao Vepa,

S. Venugopal Rao

et al.

Biosensors, Journal Year: 2023, Volume and Issue: 13(3), P. 328 - 328

Published: Feb. 27, 2023

Surface-enhanced Raman spectroscopy/scattering (SERS) has evolved into a popular tool for applications in biology and medicine owing to its ease-of-use, non-destructive, label-free approach. Advances plasmonics instrumentation have enabled the realization of SERS’s full potential trace detection biomolecules, disease diagnostics, monitoring. We provide brief review on recent developments SERS technique biosensing applications, with particular focus machine learning techniques used same. Initially, article discusses need plasmonic sensors advantage over existing techniques. In later sections, are organized as SERS-based diagnosis focusing cancer identification respiratory diseases, including SARS-CoV-2 detection. then discuss progress sensing microorganisms, such bacteria, detecting biohazardous materials view homeland security. At end article, we (a) identification, (b) classification, (c) quantification applications. The covers work from 2010 onwards, language is simplified suit needs interdisciplinary audience.

Language: Английский

Citations

80

Plasmonic coupling of silver nanospheres loaded on cobalt–iron layered double hydroxides: a robust SERS probe for 4-nitrophenol detection DOI
Thangavelu Kokulnathan,

Kalingarayanpalayam Matheswaran Arun Kumar,

Tzyy‐Jiann Wang

et al.

Journal of Materials Chemistry A, Journal Year: 2024, Volume and Issue: 12(12), P. 7287 - 7299

Published: Jan. 1, 2024

The development of surface enhanced Raman spectroscopy (SERS) substrates capable sensing organic pollutants at low concentrations with high sensitivity has always been demanding.

Language: Английский

Citations

14

Double transition metal carbide Mo2TiC2Tx MXene architectured with in-situ synthesized gold nanoparticles for SERS enhancement DOI

Prachi Rajput,

Rajeev K. Sinha, Pooja Devi

et al.

Inorganic Chemistry Communications, Journal Year: 2025, Volume and Issue: unknown, P. 114047 - 114047

Published: Feb. 1, 2025

Language: Английский

Citations

1

Plasmonic nanosensors for pharmaceutical and biomedical analysis DOI
Semra Akgönüllü, Adil Deni̇zli̇

Journal of Pharmaceutical and Biomedical Analysis, Journal Year: 2023, Volume and Issue: 236, P. 115671 - 115671

Published: Aug. 22, 2023

Language: Английский

Citations

20

Optically active two-dimensional MoS2-based nanohybrids for various biosensing applications: A comprehensive review DOI
Sandip Ghosh,

Chia-Jung Yang,

Jui‐Yang Lai

et al.

Biosensors and Bioelectronics, Journal Year: 2023, Volume and Issue: 246, P. 115861 - 115861

Published: Nov. 21, 2023

Language: Английский

Citations

18

Raman Spectroscopy-Based Chemometrics for Pesticide Residue Detection: Current Approaches and Future Challenges DOI

Shailja Sharma,

Stefan Kolašinac, Xingyi Jiang

et al.

ACS Agricultural Science & Technology, Journal Year: 2024, Volume and Issue: 4(4), P. 389 - 404

Published: March 22, 2024

Inappropriate pesticide usage leads to unsustainable agricultural practices and deteriorates the quality of fruits vegetables by introducing potentially hazardous substances. Raman spectroscopy, specifically surface-enhanced spectroscopy (SERS), offers high-sensitivity in situ monitoring residues. This review emphasizes importance advanced databases algorithms interpreting signals. Various statistical models are introduced for spectral analysis, including self-modeling curve resolution, multivariate mixture analysis. Additionally, this study provides comprehensive information on different SERS substrates shows great potential determination food However, a multicomponent analysis is needed mixtures. The overlapping bands needs be considered due complex matrices biological samples. Artificial neural networks (ANNs) applied as nonlinear when analytes mixture. Further research establish standardized protocols SERS-based quantitative detection, sample preparation data

Language: Английский

Citations

4

SERS-Active Micro/Nanomachines for Biosensing DOI Creative Commons

Chenbing Li,

Wenqing Zhang,

Kai Zheng

et al.

Biosensors, Journal Year: 2025, Volume and Issue: 15(2), P. 115 - 115

Published: Feb. 16, 2025

Surface-enhanced Raman spectroscopy (SERS) has emerged as a powerful noninvasive analytical technique with widespread applications in biochemical analysis and biomedical diagnostics. The need for highly sensitive, reproducible, efficient detection of biomolecules complex biological environments driven significant advancements SERS-based biosensing platforms. In this context, micro/nanomachines (MNMs) have garnered attention versatile SERS-active substrates due to their unique structural motional characteristics at the micro- nanoscale. This review explores advantages integrating MNMs SERS biosensing, discussing recent technological advances, various propulsion strategies, potential range applications.

Language: Английский

Citations

0

Simple and sensitive SERS platform for Staphylococcus aureus one-pot determination by photoactivated CRISPR/Cas12a cascade system and core–shell DNA tetrahedron@AuNP@Fe3O4 reporter DOI
Rui Fan, Shihua Luo, Yide He

et al.

Microchimica Acta, Journal Year: 2025, Volume and Issue: 192(4)

Published: March 18, 2025

Language: Английский

Citations

0

Temperature-Dependent SERS Detection Using CVD-Grown MoSe2 Nanoflakes DOI

Jay Deep Gupta,

Priyanka Jangra,

Ashish Kumar Mishra

et al.

ACS Applied Nano Materials, Journal Year: 2025, Volume and Issue: unknown

Published: April 3, 2025

Language: Английский

Citations

0

Development of a simple SERS substrate for the detection of pollutants and nanoplastics DOI
Lara Mikac, Hrvoje Gebavi, Justin R. Perrault

et al.

Spectrochimica Acta Part A Molecular and Biomolecular Spectroscopy, Journal Year: 2025, Volume and Issue: 339, P. 126255 - 126255

Published: April 19, 2025

Language: Английский

Citations

0