Catalysts,
Journal Year:
2023,
Volume and Issue:
13(1), P. 175 - 175
Published: Jan. 11, 2023
Advanced
photocatalysts
that
can
utilize
solar
energy
for
water
purification
applications
are
always
needed.
The
present
article
reports
a
facile
fabrication
of
tungsten
oxide
(WO3)/bismuth
oxychloride
(BiOCl)
immobilized
on
polyaniline
(PAn)
(BiOCl/WO3@PAn)
heterojunction
nanocomposite
photocatalyst.
designed
nanocatalyst
was
tested
2-chlorophenol
(2-CP)
decontamination
from
the
aquatic
system.
Synthesized
WO3,
BiOCl,
and
BiOCl/WO3@PAn
nanocomposites
were
distinguished
via
UV-DSR,
photoluminescence,
SEM,
TEM,
XRD,
XPS
analysis.
combination
PAn
with
WO3
BiOCl
showed
synergistic
impact
photocatalytic
efficiency
nanocomposite.
synthesized
higher
visible
light
absorption
behavior
bandgap
reduction
than
BiOCl.
obtained
data
shows
2-CP
photocatalysis
by
is
controlled
degradation
time,
pH,
pollutant
amount
in
solution.
highest
(99.7%)
recorded
at
pH
5
25
mg/L
concentration
within
240
min.
mechanism
active
radical
scavenging
study
discovered
•O2−
•OH,
responsible
mineralization
onto
enhanced
properties
over
pristine
catalysts.
reusability
evaluated.
It
found
photocatalyst
could
be
recycled
up
to
four
cycles
without
significantly
losing
properties.
fabricated
catalyst
presented
exceptional
catalytic
recycling
properties,
indicating
an
effective
method
hazardous
organic
contaminants
under
irradiation
green
technology
wastewater
purification.
Biogeotechnics,
Journal Year:
2024,
Volume and Issue:
unknown, P. 100132 - 100132
Published: Aug. 1, 2024
Microbially
Induced
Carbonate
Precipitation
(MICP)
technology
offers
an
innovative
approach
for
the
solidification
and
stabilization
of
heavy
metal-contaminated
soils;
However,
mechanical
strength
long-term
stability
this
remediation
method
have
not
been
thoroughly
investigated.
This
study
introduces
curing
technique
using
MICP-activated
MgO
to
address
geotechnical
challenges
posed
by
zinc
ion-contaminated
soils.
To
investigate
effect
ions
on
soil
optimal
efficacy
in
contamination,
experiments
were
conducted
zinc-contaminated
soils
with
varying
ion
concentrations
(0.05%,
0.1%,
0.5%,
1.0%),
dry
densities
(1.35,
1.4,
1.45,
1.5
g/cm³),
activated
admixtures
(1%,
2%,
5%,
10%).
The
effectiveness
was
evaluated
through
macroscopic
analysis
tests,
including
unconfined
compressive
direct
shear
Toxicity
Characteristic
Leaching
Procedure
(TCLP).
results
indicated
that
disrupted
particle
cementation,
enlarged
inter-particle
pores,
significantly
reduced
both
strength.
dosage
determined
be
10%,
resulting
1.196
MPa
a
Zn2+
leaching
concentration
0.1414
mg/L.
combined
actions
facilitated
formation
alkaline
magnesium
carbonate,
calcium
hydroxide.
These
compounds
filled
pores
soil,
encapsulating
co-precipitating
ions,
thereby
enhancing
soil's
stability.
findings
establish
theoretical
foundation
engineering
application
Catalysts,
Journal Year:
2023,
Volume and Issue:
13(1), P. 175 - 175
Published: Jan. 11, 2023
Advanced
photocatalysts
that
can
utilize
solar
energy
for
water
purification
applications
are
always
needed.
The
present
article
reports
a
facile
fabrication
of
tungsten
oxide
(WO3)/bismuth
oxychloride
(BiOCl)
immobilized
on
polyaniline
(PAn)
(BiOCl/WO3@PAn)
heterojunction
nanocomposite
photocatalyst.
designed
nanocatalyst
was
tested
2-chlorophenol
(2-CP)
decontamination
from
the
aquatic
system.
Synthesized
WO3,
BiOCl,
and
BiOCl/WO3@PAn
nanocomposites
were
distinguished
via
UV-DSR,
photoluminescence,
SEM,
TEM,
XRD,
XPS
analysis.
combination
PAn
with
WO3
BiOCl
showed
synergistic
impact
photocatalytic
efficiency
nanocomposite.
synthesized
higher
visible
light
absorption
behavior
bandgap
reduction
than
BiOCl.
obtained
data
shows
2-CP
photocatalysis
by
is
controlled
degradation
time,
pH,
pollutant
amount
in
solution.
highest
(99.7%)
recorded
at
pH
5
25
mg/L
concentration
within
240
min.
mechanism
active
radical
scavenging
study
discovered
•O2−
•OH,
responsible
mineralization
onto
enhanced
properties
over
pristine
catalysts.
reusability
evaluated.
It
found
photocatalyst
could
be
recycled
up
to
four
cycles
without
significantly
losing
properties.
fabricated
catalyst
presented
exceptional
catalytic
recycling
properties,
indicating
an
effective
method
hazardous
organic
contaminants
under
irradiation
green
technology
wastewater
purification.