ChemistrySelect,
Journal Year:
2020,
Volume and Issue:
5(37), P. 11698 - 11702
Published: Oct. 7, 2020
Abstract
A
novel
perylene
diimide
(PDI‐
C
8
SAc)
was
used
as
a
modifier
for
carbon
felt
electrode
(CFE)
and
prepared
modified
applied
dopamine
detection.
Obtained
electrochemical
current
almost
15‐fold
higher
compared
to
plain
CFE.
Also
cathodic
shift
in
the
peak
potential
obtained
indicating
electrocatalytic
effect
of
developed
sensor.
Under
optimized
experimental
conditions,
linear
range
observed
between
1–100
μM
with
limit
detection
value
0.084
(
n
=3).
The
fabricated
sensor
successfully
utilized
determination
based
medicines.
Journal of Materials Chemistry C,
Journal Year:
2022,
Volume and Issue:
10(5), P. 1698 - 1710
Published: Jan. 1, 2022
We
have
synthetized
a
series
of
perylene
imide
molecules
with
varying
structure
from
planar
to
three-dimensional.
The
best
photovoltaic
performance
is
obtained
when
each
acceptor
paired
donor
polymer
complementary
packing
tendency.
Frontiers of Optoelectronics,
Journal Year:
2023,
Volume and Issue:
16(1)
Published: April 23, 2023
Single
perylene
diimide
(PDI)
used
as
a
non-fullerene
acceptor
(NFA)
in
organic
solar
cells
(OSCs)
is
enticing
because
of
its
low
cost
and
excellent
stability.
To
improve
the
photovoltaic
performance,
it
vital
to
narrow
bandgap
regulate
stacking
behavior.
address
this
challenge,
we
synthesize
soluble
perylenetetracarboxylic
bisbenzimidazole
(PTCBI)
molecules
with
bulky
side
chain
at
bay
region,
by
replacing
widely
"swallow
tail"
type
alkyl
chains
imide
position
PDI
planar
benzimidazole
structure.
Compared
molecules,
PTCBI
exhibit
red-shifted
UV-vis
absorption
spectra
larger
extinction
coefficient,
one
magnitude
higher
electron
mobility.
Finally,
OSCs
based
on
PTCBI-type
NFA,
namely
MAS-7,
champion
power
conversion
efficiency
(PCE)
4.34%,
which
significantly
than
that
corresponding
PDI-based
highest
PCE
PTCBI-based
reported.
These
results
highlight
potential
derivatives
NFAs
OSCs.
Chemistry - An Asian Journal,
Journal Year:
2021,
Volume and Issue:
16(6), P. 690 - 695
Published: Jan. 25, 2021
Abstract
Curved
perylene
diimides
fused
with
seven‐membered
rings
have
been
synthesized
using
a
regioselective
bay‐functionalization
method
and
Pd‐catalyzed
intramolecular
C−H/C−Br
coupling
reaction.
X‐Ray
analysis
temperature‐dependent
NMR
spectroscopy
revealed
the
curved
molecular
structure
certain
degree
of
conformational
flexibility.
The
expanded
π‐conjugation
altered
electronic
properties
while
retaining
intrinsic
parent
diimide.
Despite
absence
solubilizing
N
‐substituents,
showed
sufficient
solubility
for
application
in
solution‐processed
organic
photovoltaic
devices.
devices
superior
performance
power
conversion
efficiency
up
to
2.76%
due
suppressed
charge
recombination.
Our
detailed
investigations
suggest
that
introduction
enables
removal
bulky
which
is
an
effective
way
achieve
thin‐film
morphology
suitable
photoelectric
conversion.
ChemPlusChem,
Journal Year:
2024,
Volume and Issue:
89(6)
Published: Feb. 8, 2024
Abstract
Solubility
enhancement
is
a
key
issue
for
developing
the
perylene
diimide‐based
functional
materials.
Introduction
of
curved
structure
proved
an
effective
solubilizing
method
without
employing
steric
repulsion.
In
this
work,
wavily
diimides
were
developed
as
new
family
highly
soluble
diimides.
Moreover,
their
conformational
dynamics,
aggregating
properties,
electronic
and
photovoltaic
performances
thoroughly
examined
in
comparison
to
previously
reported
isomer
exhibiting
arched
curvature.
The
waved
demonstrated
heightened
rigidity
greater
propensity
aggregation
compared
isomer,
likely
attributed
its
more
planar
structure.
Each
benzoxepin
unit
played
role
cancelling
out
curvature
on
opposite
side.
While
difference
molecular
did
not
cause
significant
alterations
photophysical
electron‐accepting
we
identified
that
modulation
controlling
morphology
photoelectric
conversion
layer.
Journal of Polymer Science,
Journal Year:
2021,
Volume and Issue:
59(24), P. 3150 - 3160
Published: Oct. 14, 2021
Abstract
Ring‐opening
metathesis
polymerization
(ROMP)‐derived
poly(oxanorbornene
imide)s
bearing
bay
‐linked
mono
‐
alkoxy
‐M1
and
1,7‐di‐alkoxy
M2
functionalized
perylene
diimides
(PDIs)
were
synthesized
using
Grubb's
third
(
G3
)
Hoveyda‐Grubbs
second
generation
HG2
ruthenium‐alkylidene
initiators.
The
mono‐alkoxy‐derived
PDI‐based
non‐ladderphane
polymer
poly
M1
displayed
67%
to
77%
of
the
trans
olefin
content
in
chain
depending
on
initiator
used
for
polymerization.
When
symmetrical
1,7‐di‐alkoxy‐derived
having
ladderphane
type‐structure,
this
a
significant
amount
cis
contents
chains,
irrespective
type
initiators
ROMP
both
monomers
proceeded
well‐controlled
manner
with
linear
dependence
molecular
weight
monomer/initiator
ratio
as
initiator.
Optical
properties
ladderphane‐based
non‐ladderphane‐based
characterized
solution
film
state.
X‐ray
diffraction
(XRD)
analysis
all
polymers
showed
π‐stacking
thin
state
ordered
packing
closer
values
d
‐spacing
.
Film
morphology
examined
by
AFM
elucidated
homogenous
smooth
surface
general,
but
some
irregularities
observed
In
addition,
CV
revealed
could
be
good
candidates
electron‐accepting
materials,
excellent
film‐forming
ability,
thermal
stability.
Physical Chemistry Chemical Physics,
Journal Year:
2022,
Volume and Issue:
24(42), P. 26254 - 26268
Published: Jan. 1, 2022
While
spin-orbit
coupling
does
not
play
a
decisive
role
in
the
photophysics
of
unsubstituted
perylene
diimides
(PDI),
this
changes
dramatically
when
two
phenylselenyl
or
phenyltelluryl
substituents
were
attached
to
PDI
bay
positions.
In
series
PhO-,
PhS-,
PhSe-,
and
PhTe-substituted
PDIs
we
observed
strongly
decreasing
fluorescence
quantum
yield
as
consequence
increasing
intersystem
crossing
(ISC)
rate,
measured
by
transient
absorption
spectroscopy
with
fs-
ns-time
resolution
well
broadband
upconversion.
Time-dependent
density
functional
calculations
suggest
due
internal
heavy-atom
effect
reason
for
fast
ISC.
case
selenium
derivative
found
significant
singlet
oxygen
sensitization
via
triplet
state.
The
corresponding
radical
anions
chalcogen
substituted
also
prepared
investigated
optical
EPR
spectroscopy.
Here,
SOC
results
an
increase
g-tensor
anisotropy,
isotropic
g-value
solution,
albeit
quasirelativistic
show
only
relatively
small
fraction
spin
be
located
on
atom.
ChemistrySelect,
Journal Year:
2020,
Volume and Issue:
5(47), P. 15028 - 15031
Published: Dec. 17, 2020
Abstract
The
work
presents
the
development
of
practical
synthetic
methods
toward
bay‐monobrominated
perylene
diimides
(PDIs)
that
have
been
regarded
as
important
intermediates
for
fabrication
new
photonic,
optoelectronic,
and
photovoltaic
materials.
In
case
PDIs
with
long
branched
N
‐alkyl
solubilizers,
bromination
using
‐bromosuccinimide
(NBS)
FeCl
3
successfully
provided
corresponding
monobromides.
This
protocol
improved
reaction
outcomes
in
terms
product
yield
operational
easiness,
superior
to
conventional
ones
liquid
bromine.
Alternatively,
imidation
dianhydride,
easily
prepared
through
monobromination
perylene‐3,4,9,10‐tetrabenzyl
ester
(PTE),
recorded
high
efficiency
generation
PDI
monobromides
without
solubilizing
‐substituents.
complementary
method
made
it
possible
access
a
series
which
had
unobtainable
existing
methods.
