Recent Progress in Enzyme Immobilization to Metal–Organic Frameworks to Enhance the CO2 Conversion Efficiency

Molecules, Journal Year: 2025, Volume and Issue: 30(2), P. 251 - 251

Published: Jan. 10, 2025

Climate change and the energy crisis, driven by excessive CO2 emissions, have emerged as pressing global challenges. The conversion of into high-value chemicals not only mitigates atmospheric levels but also optimizes carbon resource utilization. Enzyme-catalyzed technology offers a green efficient approach to conversion. However, free enzymes are prone inactivation denaturation under reaction conditions, which limit their practical applications. Metal-organic frameworks (MOFs) serve effective carriers for enzyme immobilization, offering porous crystalline structures that enhance stability. Moreover, high specific surface area facilitates strong gas adsorption, making enzyme@MOF composites particularly advantageous catalytic In this paper, we review synthesis technologies application enzyme@MOFs in Furthermore, strategies, including enhancement utilization, coenzyme regeneration efficiency, substrate mass transfer discussed further improve efficiency aim is present innovative ideas future research highlight potential applications achieving

Language: Английский

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Exploring enzyme-immobilized MOFs and their application potential: biosensing, biocatalysis, targeted drug delivery and cancer therapy

Journal of Materials Chemistry B, Journal Year: 2024, Volume and Issue: 12(40), P. 10198 - 10214

Published: Jan. 1, 2024

This review presents the various enzyme immobilization techniques and highlight their application in biosensing, bio-catalysis, drug delivery, cancer therapy.

Language: Английский

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Metal‐Organic Frameworks: A Potential Platform From Enzyme Immobilization to Mimetic Enzyme

Aggregate, Journal Year: 2024, Volume and Issue: unknown

Published: Dec. 26, 2024

ABSTRACT Metal‐organic frameworks (MOFs) are a new class of organic‐inorganic hybrid materials that have been widely studied in the past two decades for their potential catalysis. (1) In this review, we comprehensively summarize synthesis, application, and advancements MOFs enzyme immobilization mimetic enzymes. (2) We also discuss design principles behind various MOF‐based biocatalysts, such as enzyme@MOF composites, explore utility reactions. (3) Additionally, highlight advantages MOF mimetics provide perspective on solutions to current challenges (4) Ultimately, review provides general overview most recent advances catalyst platforms, including biocatalysts nanozymes, applications.

Language: Английский

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Biocatalytic nanofibrous membranes with enhanced self-cleaning properties through an in-situ ZIF-8 anchoring and trypsin incorporation strategy

Separation and Purification Technology, Journal Year: 2025, Volume and Issue: unknown, P. 132808 - 132808

Published: April 1, 2025

Language: Английский

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Applications of ordered porous materials in chromatography separation and analysis

Chinese Journal of Chromatography, Journal Year: 2025, Volume and Issue: 43(6), P. 594 - 605

Published: June 1, 2025

Chromatography， a highly efficient and selective separation technology， is broadly applicable exhibits range of developmental prospects. The stationary phase chromatography column the most important component chromatography； hence， development advanced stationary-phase materials that exhibit resolved performance continuing research hotspot in this field. In regard， ordered porous （OPMs） are advantageous owing to their precisely controllable pore sizes， morphologies， regularly arranged structures， which capable accurately sieving molecules different sizes shapes， reducing disordered molecular diffusion flow path. Such overcome limitation accuracy traditional chromatographic materials， effectively solve problems faced by scientific industry purification raw products. Over past few decades， variety new OPMs have been developed used as matrices columns. These efficiently rapidly separated homologues， isomers， isotopes， other substances with similar properties， delivered excellent analysis results. review， we first discuss influence structures on efficiency resolution during from theoretical perspective， provides basis for use phases chromatography. This review then summarizes progress several OPM types applications， including metal organic frameworks （MOFs）， covalent （COFs）， cages （POCs）， mesoporous silica block copolymer （BCP） assemblies， high internal-phase emulsion polymers （PolyHIPEs）. concludes discussing current challenges well directions future development.

Language: Английский

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Cascade synthesis of D-phenyllactic acid using amorphous metal-organic framework-modified Escherichia coli

Molecular Catalysis, Journal Year: 2024, Volume and Issue: 560, P. 114131 - 114131

Published: April 12, 2024

Language: Английский

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Cu-MOFs@AuPtNPs nanozyme-based immunosorbent assay for colorimetric detection of alpha-fetoprotein

Analytical Methods, Journal Year: 2024, Volume and Issue: 16(37), P. 6443 - 6450

Published: Jan. 1, 2024

A novel MeLISA based on Cu-MOFs@AuPtNPs for ultrasensitive detection of AFP provides a distinct colorimetric result, which was differentiated by the naked eye.

Language: Английский

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Nanotechnological advances in microbial enzymes for biosensor development

Elsevier eBooks, Journal Year: 2024, Volume and Issue: unknown, P. 313 - 338

Published: Jan. 1, 2024

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Closing the Loop in the Carbon Cycle: Enzymatic Reactions Housed in Metal–Organic Frameworks for CO2 Conversion to Methanol

Applied Biochemistry and Biotechnology, Journal Year: 2024, Volume and Issue: unknown

Published: Nov. 26, 2024

Language: Английский

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