Encyclopedia of Inorganic and Bioinorganic Chemistry,
Journal Year:
2023,
Volume and Issue:
unknown, P. 1 - 21
Published: Dec. 29, 2023
Abstract
This
article
highlights
the
epoxidation
of
alkenes
by
molecular
catalysts
in
biphasic
liquid–liquid
media.
We
showcase
strategies
for
a
precise
control
phase
behavior
both
catalyst
and
substrate,
which
is
dominated
phase‐transfer‐enabling
surfactants.
The
focus
set
on
rationale
transfer
efficiency
recycling.
Principally,
it
possible
to
either
aqueous
or
organic
phase,
depending
type
surfactant
requirements
reaction,
example,
activity
versus
present
these
two
basic
concepts
with
respect
interactions
between
surfactant,
activity,
possibility
efficient
green
Green Chemistry,
Journal Year:
2023,
Volume and Issue:
25(5), P. 1704 - 1728
Published: Jan. 1, 2023
Publication
of
the
E
Factor
drew
attention
to
problem
waste
in
chemicals
manufacture.
Thirty
yeas
later
it
is
abundantly
clear
that
underlying
cause
global
environmental
problems,
from
climate
change
plastic
pollution.
International Journal of Nanomedicine,
Journal Year:
2023,
Volume and Issue:
Volume 18, P. 4275 - 4311
Published: July 1, 2023
Abstract:
Breast
cancer
(BC)
is
the
most
prevalent
type
of
in
world
and
main
reason
women
die
from
cancer.
Due
to
significant
side
effects
conventional
treatments
such
as
chemotherapy
radiotherapy,
search
for
supplemental
alternative
natural
drugs
with
lower
toxicity
interest
researchers.
Curcumin
(CUR)
a
polyphenol
extracted
turmeric.
Numerous
studies
have
demonstrated
that
CUR
an
effective
anticancer
drug
works
by
modifying
different
intracellular
signaling
pathways.
CUR's
therapeutic
utility
severely
constrained
its
short
half-life
vivo,
low
water
solubility,
poor
stability,
quick
metabolism,
oral
bioavailability,
potential
gastrointestinal
discomfort
high
doses.
One
practical
solutions
aforementioned
issues
development
targeted
delivery
systems
(TDDSs)
based
on
nanomaterials.
To
improve
targeting
efficacy
serve
reference
use
TDDSs
clinical
setting,
this
review
describes
physicochemical
properties
bioavailability
mechanism
action
BC,
emphasis
recent
BC
combination
CUR,
including
passive
TDDSs,
active
TDDSs.
Keywords:
breast
cancer,
curcumin,
system,
targeting,
Chemical Reviews,
Journal Year:
2025,
Volume and Issue:
unknown
Published: Feb. 11, 2025
The
chemistry
and
physics
of
soft
matter
interfaces,
especially
aqueous–organic
are
centrally
important
to
many
areas
science
technology.
Often,
the
thermodynamics,
kinetics,
selectivity
reactions
modified
at
interfaces.
Here,
we
review
electrostatics
hydration
charged
monolayers
on
water
their
influence
interfacial
chemical
equilibria.
First,
provide
an
understanding
interfaces
as
a
conceptual
continuation
solvation
shell
small
molecules,
along
with
recent
relevant
experimental
work.
Then,
summary
models
for
describing
aqueous
While
will
discuss
range
new
developments,
our
focus
be
systems
where
surface
is
controllable
by
choice
relatively
simple
insoluble
surfactants.
New
insights
into
molecular
structure
double
layer,
particular
attention
knowledge
gained
from
spectroscopy
reviewed.
Our
approach
familiarize
reader
models,
followed
discussion
further
complexity
explaining
phenomena.
Experiments
that
test
limits
such
also
discussed.
Finally,
outlook
engineering
environment
tailored
reactivity,
anticipated
advancements
potentials
impacts.
Small,
Journal Year:
2024,
Volume and Issue:
20(23)
Published: Jan. 6, 2024
Abstract
The
applications
of
nanoreactors
in
biology
are
becoming
increasingly
significant
and
prominent.
Specifically,
with
spatially
confined,
due
to
their
exquisite
design
that
effectively
limits
the
spatial
range
biomolecules,
attracted
widespread
attention.
main
advantage
this
structure
is
designed
improve
reaction
selectivity
efficiency
by
accumulating
reactants
catalysts
within
chambers,
thus
increasing
frequency
collisions
between
reactants.
Herein,
recent
progress
synthesis
confined
biological
summarized,
covering
various
kinds
nanoreactors,
including
porous
inorganic
materials,
crystalline
materials
organic
components
self‐assembled
polymers
construct
nanoreactors.
These
principles
underscore
how
precise
control
could
be
achieved
adjusting
composition
create
confined.
Furthermore,
demonstrated
fields,
such
as
biocatalysis,
molecular
detection,
drug
delivery,
cancer
therapy.
showcase
potential
prospects
offering
robust
guidance
for
future
research
innovation.
ChemCatChem,
Journal Year:
2022,
Volume and Issue:
15(1)
Published: Nov. 11, 2022
Abstract
The
encapsulation
of
substrates
within
micellar
structures
gives
rise
to
a
multitude
effects
beyond
simple
solubilization
in
water.
When
incorporated
photochemical
reaction
design
media
may
offer
possibilities
control
both
reactivity
and
selectivity.
Herein,
we
describe
various
important
phenomena
such
as
encapsulation,
polarity
differences,
electrostatic
interactions
hydrogen
bonding,
discuss
the
resulting
mechanisms
by
which
outcomes
can
be
greatly
influenced.
In
this
concept
article,
showcase
selected
reactions
demonstrate
how
selectively
applied
design.
Langmuir,
Journal Year:
2025,
Volume and Issue:
unknown
Published: Feb. 19, 2025
The
reuse
of
hazardous
HCl
contaminants
containing
various
impurities
is
a
challenging
issue
in
academia
and
industry.
An
efficient
method
for
the
direct
utilization
industrial
has
been
developed
based
on
oxychlorination
phenol
using
hydrogen
peroxide
as
an
oxidant.
By
employing
from
hydrochloric
acid
chlorinating
agent,
87-94%
was
effectively
reused
synthesis
chlorophenols.
process
achieved
complete
conversion
highly
selective
C-H
bonds
at
both
ortho-
para-positions,
particularly
forming
2,4-dichlorophenol,
presence
reaction-promoting
additives.
Various
characterizations
indicated
that
surfactants
promoted
formation
stable
aggregates.
reaction
primarily
occurred
aggregates
interface,
with
diameters
less
than
100
nm.
These
exert
nanoscale
limiting
effect
spatial
structure
phenol,
resulting
2,4-dichlorophenol
during
oxidative
chlorination
HCl.
This
demonstrates
treatment
rate
pollutants
impurities.
Chemistry - A European Journal,
Journal Year:
2023,
Volume and Issue:
29(26)
Published: March 2, 2023
Abstract
Micellar
photocatalysis
has
been
used
to
overcome
oxygen
quenching
and
enable
a
[2+2]
photocycloaddition
through
triplet‐energy
transfer
in
water
under
aerobic
conditions.
The
cheap
commercially
available
self‐assembling
sodium
dodecyl
sulfate
(SDS)
micelles
were
found
increase
the
tolerance
of
typically
oxygen‐sensitive
reaction.
Furthermore,
use
micellar
solution
was
activate
α,β‐unsaturated
carbonyl
compounds
energy
allow
photocycloadditions
take
place.
Our
preliminary
studies
effects
on
energy‐transfer‐based
reactions
demonstrate
reaction
between
activated
alkenes
mixture
SDS,
[Ru(bpy)
3
](PF
6
)
2
.
