Experimental and Modeling Study on the Removal of Mn, Fe, and Zn from Fiberboard Industrial Wastewater Using Modified Activated Carbon DOI Open Access

Syafiqa Ayob,

Wahid Ali Hamood Altowayti, Norzila Othman

et al.

Sustainability, Journal Year: 2023, Volume and Issue: 15(8), P. 6734 - 6734

Published: April 17, 2023

In this work, the use of agricultural waste from oil palm petioles (OPP) as a raw material for production activated carbon (AC) and its characterization were examined. By soaking these chars in nitric acid (HNO3) potassium hydroxide (KOH) at 10% concentration, AC with favorable high-porosity carbons was generated. To maximize synthesis, pyrolyzed 460, 480, 500 °C temperatures 20 min. Based on micrographs formed pores surface functional groups, 480 carbonization temperature both chemical HNO3 KOH shown to be best. The FTIR measurements reveal that activation successfully transformed into AC. Moreover, FESEM show cavities prepared achieve high area. This is further supported by BET results OPP areas 883.3 372.4 m2/g, respectively, compared area 0.58 m2/g. Furthermore, tests revealed an optimization model, namely response methodology (RSM), using central composite design (CCD) technique. findings showed all three parameters (pH, time, dose) had substantial impact removal Zn, Fe, Mn. Analysis variance (ANOVA) analytical error indicated models accurate, low value R2 > 0.9. Remarkably, good correlation between actual predicted values modified promising adsorbent heavy metal wastewater.

Language: Английский

Modified Shrimp-Based Chitosan as an Emerging Adsorbent Removing Heavy Metals (Chromium, Nickel, Arsenic, and Cobalt) from Polluted Water DOI Open Access
Aminur Rahman, Md. Azizul Haque,

Sibdas Ghosh

et al.

Sustainability, Journal Year: 2023, Volume and Issue: 15(3), P. 2431 - 2431

Published: Jan. 30, 2023

Water quality is under constant threat worldwide due to the discharge of heavy metals into water from industrial waste. In this report, we introduce a potential candidate, chitosan, extracted and isolated shrimp shells, that can adsorb polluted water. The waste shell chitosan was characterized via Fourier transform infrared spectroscopy (FTIR) scanning electron microscopy with energy dispersive X-ray (SEM-EDS). adsorption capacity on modified measured using an inductively coupled plasma mass spectrometry before after adsorption. highest arsenic, nickel, cobalt 98.50, 74.50, 47.82%, respectively, at neutral pH, whereas chromium 97.40% pH 3. Correspondingly, maximum capacities MSS for As, Cr, Ni, Co were observed be 15.92, 20.37, 7.00, 6.27 mg/g, respectively. application Langmuir Freundlich isotherm models revealed processes statistically significant (r2 > 0.98). kinetic studies metal adsorption, shell, well explained by pseudo-second-order model linear coefficients (r2) >0.97. presence greater number functional groups adsorbent, such as N–H H–O, –COO−, C–H, N–N, C–O–C, confirmed FTIR analyses. Furthermore, SEM-EDX analysis detected elements surface chitosan. This noteworthy suggests could serve promising, eco-friendly, low-cost adsorbent removing toxic including used in many broad-scale applications clean wastewater.

Language: Английский

Citations

41
Synergism between polyethyleneimine, graphene oxide, and MgFeAl-layered triple hydroxide in removing acid red 1 dye and bisphenol A from contaminated water samples DOI
Salem A. Bahadi, Q.A. Drmosh, Sagheer A. Onaizi

et al.

Colloids and Surfaces A Physicochemical and Engineering Aspects, Journal Year: 2024, Volume and Issue: 688, P. 133579 - 133579

Published: Feb. 27, 2024

Language: Английский

Citations

14
Chemically versus thermally reduced graphene oxide: effects of reduction methods and reducing agents on the adsorption of phenolic compounds from wastewater DOI
Salem A. Bahadi, Mustapha Iddrisu, Mohammed K. Al-Sakkaf

et al.

Emergent Materials, Journal Year: 2023, Volume and Issue: 7(2), P. 533 - 545

Published: June 12, 2023

Language: Английский

Citations

22
Enhanced Biochar Production via Co-Pyrolysis of Biomass Residual with Plastic Waste after Recycling Process DOI Creative Commons
Sukanya Hongthong,

Worachate Sangsida,

Surachai Wongcharee

et al.

International Journal of Chemical Engineering, Journal Year: 2024, Volume and Issue: 2024, P. 1 - 17

Published: Feb. 17, 2024

Biomass pyrolysis for oil production results in biochar byproduct, whose characteristics can be improved by the reuse of waste plastics. While plastic recycling process leads to a large amount that cannot reused, this underutilized feedstock holds potential coprocessing with biomass, thereby increasing likelihood producing valuable products. This study sought evaluate how inclusion influences biomass residue. To end, sawdust and hardwood were chosen as materials investigate presence plastics might alter properties resulting chars. Synergies observed among components, particularly samples higher lignin content from which resulted increased yields. The showed 20% blend wood at 300°C produced solid char yield 40% weight. Co-pyrolysis derived blends 20 wt. % PP both significant enhancement various biochar, including surface area, carbon content, hydrophobicity, aromaticity. had favorable effect on calorific values biochar. These enhanced significantly contributed biochar’s capacity sorbing substances like heavy metals. It proved result importance energy its use renewable applications. beneficial combined seen credited interaction between polymer fewer volatile products temperatures. suggested biowaste not only reduces environmental impact but also converts it into eco-friendly product.

Language: Английский

Citations

8
Functionalization of recycled polymer and 3D printing into porous structures for selective recovery of copper from copper tailings DOI Creative Commons
Kosisochi Ibebunjo, Youssef El Ouardi, John Kwame Bediako

et al.

Chemical Engineering Science, Journal Year: 2023, Volume and Issue: 286, P. 119664 - 119664

Published: Dec. 23, 2023

Selective copper recovery from tailings reduces environmental pollution caused by mining activities and provides a valuable source of copper. Furthermore, polymer waste accumulation handling small functional materials like resins remains challenging. In this study, 3D-printed adsorbent for selective was designed functionalizing recycled with chelating resin 3D-printing using laser sintering technique. The characterized, its adsorption performance examined under varying conditions. kinetics isotherm fitted well to the pseudo-second-order Langmuir models, suggesting chemical monolayer processes. FTIR indicated coordination as possible mechanism. Thermodynamics revealed an endothermic process. demonstrated excellent Cu(II) adsorption, high selectivity towards Cu(II), reusability. This work offers promising recovery, while also addressing particle issues.

Language: Английский

Citations

15
Using Excel Solver’s Parameter Function in Predicting and Interpretation for Kinetic Adsorption Model via Batch Sorption: Selection and Statistical Analysis for Basic Dye Removal onto a Novel Magnetic Nanosorbent DOI Creative Commons

Akkharaphong Wongphat,

Surachai Wongcharee,

Nuttapon Chaiduangsri

et al.

ChemEngineering, Journal Year: 2024, Volume and Issue: 8(3), P. 58 - 58

Published: June 6, 2024

Magnetic nanosorbents efficiently capture substances, particularly basic dyes, and can be easily recovered using a magnetic field in water treatment. Adsorption is cost-effective highly efficient method for dye removal. This study compared eight nonlinear kinetic adsorption models Microsoft Excel 2023, which provided detailed analysis statistical results comparable to advanced programs like MATLAB OriginPro. The Fractal Like-Pseudo First Order (FL-PFO) model showed the best fit model, closely predicting experimental data at 33.09 mg g−1. suggests that diffusion rate of within nanosorbent pores crucial factor. parameters confirmed suitability these describing observed behavior. Overall, emerged as reliable tool behavior various removal, offering wide range functions diverse applications, including environmental monitoring modeling. Corrected Akaike’s information criterion was used determine optimal model. It found lowest AICcorrected value about −3.8479 FL-PFO while Elovich had highest 29.6605. indicates effectively correlated data. concluded Excel’s accessibility, familiarity, broad capabilities make it valuable resource many aspects engineering.

Language: Английский

Citations

6
Comprehensive Cost–Benefit and Statistical Analysis of Isotherm and Kinetic Models for Heavy Metal Removal in Acidic Solutions Using Weakly Base Polymeric Chelating Resin as Adsorbent DOI Open Access
Kowit Suwannahong, Surachai Wongcharee, Torpong Kreetachat

et al.

Water, Journal Year: 2024, Volume and Issue: 16(17), P. 2384 - 2384

Published: Aug. 25, 2024

This study investigates the removal of heavy metals, particularly copper and nickel, from acidic aqueous solutions using weakly base polymeric chelating resin Dowex M-4195. The research conducts comprehensive cost–benefit statistical analyses various kinetic isotherm adsorption models. results show that PSO general order models provide high accuracy for Cu2⁺ kinetics, while Avrami fractional model excels Ni2⁺. In terms models, Langmuir Jovanovic are highly accurate both with Toth being effective Ni2⁺ due to its ability account surface heterogeneity multi-layer adsorption. also reveals process is more economically beneficial than process, highlighting importance selection optimizing metal removal. Incorporating circular economy principles, this emphasizes sustainability regenerable reusable adsorbents like findings valuable insights designing efficient systems, promoting environmental sustainability, ensuring public health safety.

Language: Английский

Citations

6
Sustainable strategies for recovering metallic copper from waste printed circuit boards: Clean leaching and micro-nano copper powder preparation DOI

Xi-guang Li,

Shun-xiang Shi,

Shuai Yan

et al.

Journal of environmental chemical engineering, Journal Year: 2024, Volume and Issue: 12(4), P. 113220 - 113220

Published: May 31, 2024

Language: Английский

Citations

5
Innovative closed-loop copper recovery strategy from waste printed circuit boards through efficient ionic liquid leaching DOI

Xi-guang Li,

Xinlong Li,

Xiaodong Shi

et al.

Separation and Purification Technology, Journal Year: 2024, Volume and Issue: 338, P. 126530 - 126530

Published: Jan. 27, 2024

Language: Английский

Citations

4
Optimizing seawater purification: Ion exchange selective demineralization through single and multi-objective techniques DOI
Muhammad Irfan, Muhammad Ans, S. M. Zakir Hossain

et al.

Journal of Dispersion Science and Technology, Journal Year: 2025, Volume and Issue: unknown, P. 1 - 18

Published: Jan. 21, 2025

Language: Английский

Citations

0