Catalysis Science & Technology,
Год журнала:
2024,
Номер
14(9), С. 2638 - 2645
Опубликована: Янв. 1, 2024
Developing
low-cost,
high-activity
transition
metal-based
oxygen
reduction
electrocatalysts
to
replace
noble
metals
in
reactions
continues
pose
a
notable
difficulty
the
field
of
research.
Chemical Communications,
Год журнала:
2023,
Номер
59(20), С. 2869 - 2887
Опубликована: Янв. 1, 2023
Metal-organic
frameworks
(MOFs)
are
extremely
versatile
materials,
which
serve
to
create
platforms
with
exceptional
porosity
and
specific
reactivities.
The
production
of
MOFs
at
the
nanoscale
(NMOFs)
offers
possibility
creating
innovative
materials
for
bioapplications
as
long
they
maintain
properties
their
larger
counterparts.
Due
inherent
chemical
versatility,
synthetic
methods
produce
them
can
be
combined
inorganic
nanoparticles
(NPs)
nanocomposites
(NCs)
one-of-a-kind
features.
These
systems
remotely
controlled
catalyze
abiotic
reactions
in
living
cells,
have
potential
stimulate
further
research
on
these
tools
advanced
therapies.
Abstract
The
oxygen
reduction
reaction
(ORR)
represents
a
cornerstone
for
many
clean
energy
conversion
technologies
such
as
fuel
cells
and
metal‐air
batteries.
Nevertheless,
the
commercialization
of
these
is
largely
impeded
by
slow
kinetics
ORR,
which
active,
durable
cost‐effective
ORR
catalysts
are
needed.
In
recent
years,
zeolitic
imidazolate
framework
(ZIF)
derived
carbon
materials
emerge
new
class
non‐precious
metal
(NPMCs)
toward
benefiting
from
their
high
surface
area,
abundant
porosity,
tunable
chemical/electronic
structure,
superior
activity
comparable
or
even
surpasses
those
state‐of‐the‐art
Pt‐based
catalysts.
This
review
offers
comprehensive
overview
advances
in
ZIF‐derived
carbons
ORR.
synthesis
strategies
key
factors
affecting
performance
discussed.
Future
research
directions
perspectives
on
exploring
ZIF
efficient
highlighted,
with
focus
principles
rationally
engineering
coordination
structures
active
sites.