Separation and Purification Technology, Journal Year: 2025, Volume and Issue: unknown, P. 132363 - 132363
Published: March 1, 2025
Language: Английский
Separation and Purification Technology, Journal Year: 2025, Volume and Issue: unknown, P. 132363 - 132363
Published: March 1, 2025
Language: Английский
ACS Catalysis, Journal Year: 2022, Volume and Issue: 12(14), P. 8623 - 8631
Published: July 5, 2022
Oxidative desulfurization (ODS) plays critical roles in the production of high-quality sulfur impurity-free fuels, especially procedures using molecular oxygen as sole oxidant. However, state-of-the-art systems still rely on noble metal nanocatalysts, with deactivation issues caused by coking and sintering present. Herein, leveraging merits single-atom catalysts (SACs) earth-abundant cores robust nanoporous supports, a series composed homogeneously distributed single chromium atoms anchored multiwalled carbon nanotubes were fabricated deployed to catalyze aerobic ODS transformation. Adopting aromatic compound (ASC)-containing alkanes model system oxidant, efficient oxygen-to-active O2•– transformation subsequent ASCs-to-sulfone conversion have been achieved, former benefiting from chromium-active sites latter arising robust, nanoporous, π-conjugated architecture supports. The attractive catalytic performance cycling stability chromium-based SACs make them promising candidates practical species removal liquid supplying an alternative guidance catalyst design toward cost-effective energy-efficient procedures.
Language: Английский
Citations
119Journal of Industrial and Engineering Chemistry, Journal Year: 2022, Volume and Issue: 112, P. 20 - 36
Published: May 19, 2022
Language: Английский
Citations
81Energy storage materials, Journal Year: 2022, Volume and Issue: 55, P. 166 - 192
Published: Nov. 25, 2022
Language: Английский
Citations
77The Science of The Total Environment, Journal Year: 2023, Volume and Issue: 906, P. 167681 - 167681
Published: Oct. 14, 2023
Language: Английский
Citations
53Nano Energy, Journal Year: 2023, Volume and Issue: 111, P. 108415 - 108415
Published: April 5, 2023
Language: Английский
Citations
49Advanced Materials, Journal Year: 2024, Volume and Issue: 36(29)
Published: April 29, 2024
Organic acid-based deep eutectic solvents (DESs) as catalysts always suffer from weak stability and low recyclability due to the accumulation of organic oxidative products in DES phase. Herein, a completely inorganic solvent (IDES) ZnCl
Language: Английский
Citations
30Nano Letters, Journal Year: 2024, Volume and Issue: 24(21), P. 6302 - 6311
Published: May 15, 2024
Photocatalytic synthesis based on the oxygen reduction reaction (ORR) has shown great promise for H2O2 production. However, low activity and selectivity of 2e– ORR result in a fairly efficiency Herein, we propose strategy to enhance proton-coupled electron transfer (PCET) process covalent organic frameworks (COFs), thereby significantly boosting photosynthesis. We demonstrated that construction hydrogen-bonding network, achieved by anchoring H3PO4 molecular network COF nanochannels, can greatly improve both proton conductivity photogenerated charge separation COFs. Thus, COF@H3PO4 exhibited superior photocatalytic performance generating without sacrificial agents, with solar-to-chemical conversion as high 0.69%. Results indicated much more localized spatial distribution energy band density led efficient separation, small barrier rate-limiting step from *OOH endowed higher selectivity.
Language: Английский
Citations
26Applied Catalysis B Environment and Energy, Journal Year: 2024, Volume and Issue: 354, P. 124138 - 124138
Published: April 29, 2024
Language: Английский
Citations
25Applied Catalysis B Environment and Energy, Journal Year: 2024, Volume and Issue: 355, P. 124155 - 124155
Published: May 8, 2024
Language: Английский
Citations
24Environmental Research, Journal Year: 2025, Volume and Issue: unknown, P. 121152 - 121152
Published: Feb. 1, 2025
Language: Английский
Citations
2