Rational Design of Flexible Zn-Based Batteries for Wearable Electronic Devices

ACS Nano, Journal Year: 2023, Volume and Issue: 17(3), P. 1764 - 1802

Published: Jan. 30, 2023

The advent of 5G and the Internet Things has spawned a demand for wearable electronic devices. However, lack suitable flexible energy storage system become "Achilles' Heel" Additional problems during transformation battery structure from conventional to also present severe challenge design. Flexible Zn-based batteries, including Zn-ion batteries Zn–air have long been considered promising candidates due their high safety, eco-efficiency, substantial reserve, low cost. In past decade, researchers come up with elaborate designs each portion improve ionic conductivities, mechanical properties, environment adaptabilities, scalable productions. It would be helpful summarize reported strategies compare pros cons facilitate further research toward commercialization batteries. this review, current progress in developing is comprehensively reviewed, electrolytes, cathodes, anodes, discussed terms synthesis, characterization, performance validation. By clarifying challenges design, we methodology previous investigations propose future development. end, paradigm summarized fit burgeoning requirement devices an iterative process, which will benefit development

Language: Английский

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Understanding the bifunctional catalytic ability of electrocatalysts for oxygen evolution reaction and urea oxidation Reaction: Recent advances and perspectives

Chemical Engineering Journal, Journal Year: 2023, Volume and Issue: 471, P. 144660 - 144660

Published: July 11, 2023

Language: Английский

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Carbon-based electrocatalysts for rechargeable Zn–air batteries: design concepts, recent progress and future perspectives

Energy & Environmental Science, Journal Year: 2023, Volume and Issue: 17(2), P. 386 - 424

Published: Nov. 22, 2023

This review provides an in-depth discussion of the carbon-based electrocatalysts for rechargeable Zn–air batteries from design strategies, research progress, and future perspectives.

Language: Английский

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Accelerated deprotonation with a hydroxy-silicon alkali solid for rechargeable zinc-air batteries

Nature Communications, Journal Year: 2023, Volume and Issue: 14(1)

Published: Nov. 1, 2023

Transition metal oxides are promising electrocatalysts for zinc-air batteries, yet surface reconstruction caused by the adsorbate evolution mechanism, which induces zinc-ion battery behavior in oxygen reaction, leads to poor cycling performance. In this study, we propose a lattice mechanism involving proton acceptors overcome performance of OER process. We introduce stable solid base, hydroxy BaCaSiO4, onto surfaces PrBa0.5Ca0.5Co2O5+δ perovskite nanofibers with one-step exsolution strategy. The HO-Si sites on BaCaSiO4 significantly accelerate transfer from OH* adsorbed during As proof concept, rechargeable assembled composite electrocatalyst is an alkaline environment over 150 hours at 5 mA cm-2 galvanostatic charge/discharge tests. Our findings open new avenues designing efficient batteries.

Language: Английский

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Interface and doping engineering of Co-based electrocatalysts for enhanced oxygen reduction and evolution reactions

Chemical Engineering Journal, Journal Year: 2023, Volume and Issue: 470, P. 144380 - 144380

Published: June 25, 2023

Language: Английский

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Heterostructured Catalytic Materials as Advanced Electrocatalysts: Classification, Synthesis, Characterization, and Application

Advanced Functional Materials, Journal Year: 2024, Volume and Issue: unknown

Published: May 6, 2024

Abstract The proactive exploration of electrocatalytic conversion for renewable energy valorization is tremendous significance in addressing the issues fossil exhaustion, among which critical challenge electrocatalysis lies rational design efficient electrocatalysts that are rich earth. Among electrocatalysts, heterostructured materials exhibits immense potential optimization noble metals and elaboration non‐precious metal with durability. In this review, a systematic overview modern advances range reactions described, special interfacial brings additional functional effects. Subsequently, various synthesis methods characterization techniques also summarized. innovative classification heterostructures junction, crystal structure, structural morphology, properties components presented review. Finally, possible challenges outlooks future further discussed, including how to develop more sophisticated synthesis, characterization, theoretical calculation methods, will serve as guiding direction interface design. This review aims set trajectory providing meaningful inspiration references by advancing process carbon neutrality.

Language: Английский

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Screening Spinel Oxide Supports for RuO₂ to Boost Bifunctional Electrocatalysts for Advanced Zn–Air Batteries

Advanced Functional Materials, Journal Year: 2024, Volume and Issue: 34(36)

Published: March 10, 2024

Abstract The compositing strategy offers great potential in designing bifunctional oxygen electrocatalysts for Zn–air batteries. Recent reports reveal that the couple of RuO 2 , serving as a benchmark evolution reaction (OER) catalyst, with other reduction (ORR) catalysts is wise choice to build highly efficient electrocatalysts. However, design criteria ORR and OER activities ‐based composite are still unclear. Herein, series transition metal (Fe, Co, Mn, Ni)‐doped spinel oxides designed support nanorods exploring mechanism. Through advanced technology, it considered increasing content binding energy Co 3+ enhancing oxidation state Ru 4+ an promote /Co‐based oxide catalysts. It found coupling Mn‐doping 3 O 4 (CMO) supports can induce highest catalytic ORR/OER excellent performance rechargeable Operando electrochemical impedance spectroscopy theoretical calculation further prove synergistic effect between CMO originated from overflow overcome large barrier desorption on during adsorption ORR.

Language: Английский

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MOF-mediated synthesis of novel PtFeCoNiMn high-entropy nano-alloy as bifunctional oxygen electrocatalysts for zinc-air battery

Nano Research, Journal Year: 2024, Volume and Issue: 17(6), P. 5288 - 5297

Published: March 21, 2024

Language: Английский

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Single-phase ruthenium-based oxide with dual-atoms induced bifunctional catalytic centers enables highly efficient rechargeable Zn-air batteries

Energy storage materials, Journal Year: 2024, Volume and Issue: 68, P. 103341 - 103341

Published: March 11, 2024

Composite strategies for constructing dual-atom sites at the hetero-interface provide considerable prospects designing efficient bifunctional oxygen catalysts. Given insufficient interface site and instability of phase interface, we need to develop more efficiently utilizing site. Here, report a doping strategy construct abundant in single-phase oxide Ru/Mn bond formation enables electronic interaction between Ru Mn, which reduces oxidation state meanwhile constructs electron-rich states Mn sites. DFT calculation was further applied explore reaction mechanism. We found that atoms serve as reduction evolution catalytic respectively facilitate adsorption OH* desorption. More importantly, co-adsorption OOH* on Mn/Ru dual can greatly enhance activity. The resulting Mn-RuO2 catalyst exhibits an ultra-low ORR/OER overpotential just 0.65 V, substantially lower than RuO2 MnOx. Remarkably, also demonstrates excellent stability, with minimal ORR decay after repeated OER cycling. Rechargeable zinc-air batteries using Mn-doped achieve super-durability 2000 cycles final energy efficiency retention 87.5%.

Language: Английский

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Promoting Electrocatalytic Oxygen Reactions Using Advanced Heterostructures for Rechargeable Zinc–Air Battery Applications

ACS Nano, Journal Year: 2024, Volume and Issue: 18(33), P. 21651 - 21684

Published: Aug. 12, 2024

In order to facilitate electrochemical oxygen reactions in electrically rechargeable zinc-air batteries (ZABs), there is a need develop innovative approaches for efficient electrocatalysts. Due their reliability, high energy density, material abundance, and ecofriendliness, ZABs hold promise as next-generation storage conversion devices. However, the large-scale application of currently hindered by slow kinetics reduction reaction (ORR) evolution (OER). development heterostructure-based electrocatalysts has potential surpass limitations imposed intrinsic properties single material. This Account begins with an explanation configurations fundamentals electrochemistry air electrode. Then, we summarize recent progress respect variety heterostructures that exploit bifunctional electrocatalytic overview impact on ZAB performance. The range heterointerfacial engineering strategies improving ORR/OER performance includes tailoring surface chemistry, dimensionality catalysts, interfacial charge transfer, mass transport, morphology. We highlight multicomponent design take these features into account create advanced highly active catalysts. Finally, discuss challenges future perspectives this important topic aim enhance activity batteries.

Language: Английский

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