Advanced Materials,
Journal Year:
2024,
Volume and Issue:
unknown
Published: Feb. 20, 2024
Abstract
Responsive
materials
possess
the
inherent
capacity
to
autonomously
sense
and
respond
various
external
stimuli,
demonstrating
physical
intelligence.
Among
diverse
array
of
responsive
materials,
liquid
crystalline
polymers
(LCPs)
stand
out
for
their
remarkable
reversible
stimuli‐responsive
shape‐morphing
properties
potential
creating
soft
robots.
While
numerous
reviews
have
extensively
detailed
progress
in
developing
LCP‐based
actuators
robots,
there
exists
a
need
comprehensive
summaries
that
elucidate
underlying
principles
governing
actuation
how
intelligence
is
embedded
within
these
systems.
This
review
provides
overview
recent
advancements
robots
endowed
with
using
LCPs.
structured
around
stimulus
conditions
categorizes
studies
involving
LCPs
based
on
fundamental
control
stimulation
logic
approach.
Specifically,
three
main
categories
are
examined:
systems
changing
those
operating
under
constant
equip
learning
capabilities.
Furthermore,
persisting
challenges
be
addressed
outlined
discuss
future
avenues
research
this
dynamic
field.
Chemical Reviews,
Journal Year:
2022,
Volume and Issue:
122(5), P. 5317 - 5364
Published: Feb. 1, 2022
In
conventional
classification,
soft
robots
feature
mechanical
compliance
as
the
main
distinguishing
factor
from
traditional
made
of
rigid
materials.
Recent
advances
in
functional
materials
have
facilitated
emergence
a
new
class
capable
tether-free
actuation
response
to
external
stimuli
such
heat,
light,
solvent,
or
electric
magnetic
field.
Among
various
types
stimuli-responsive
materials,
shown
remarkable
progress
their
design
and
fabrication,
leading
development
with
unique
advantages
potential
for
many
important
applications.
However,
field
is
still
its
infancy
requires
further
advancements
terms
principles,
fabrication
methods,
control
mechanisms,
sensing
modalities.
Successful
future
would
require
comprehensive
understanding
fundamental
principle
actuation,
well
physical
properties
behavior
this
review,
we
discuss
recent
modeling
simulation,
robots.
We
then
give
set
guidelines
optimal
performance
Lastly,
summarize
biomedical
applications
provide
our
perspectives
on
next-generation
Advanced Materials,
Journal Year:
2021,
Volume and Issue:
33(8)
Published: Jan. 14, 2021
Stimuli-responsive
and
active
materials
promise
radical
advances
for
many
applications.
In
particular,
soft
magnetic
offer
precise,
fast,
wireless
actuation
together
with
versatile
functionality,
while
liquid
crystal
elastomers
(LCEs)
are
capable
of
large
reversible
programmable
shape-morphing
high
work
densities
in
response
to
various
environmental
stimuli,
e.g.,
temperature,
light,
chemical
solutions.
Integrating
the
orthogonal
stimuli-responsiveness
these
two
kinds
could
potentially
enable
new
functionalities
future
Here,
microparticles
(MMPs)
embedded
into
an
LCE
film
take
respective
advantages
both
without
compromising
their
independent
stimuli-responsiveness.
This
composite
material
enables
reconfigurable
miniature
machines
that
can
self-adapt
a
changing
environment.
robot
autonomously
alter
its
locomotion
mode
when
it
moves
from
air
hot
liquid,
vine-like
filament
sense
twine
around
support,
light-switchable
spring
demonstrated.
The
integration
LCEs
MMPs
monolithic
structures
introduces
dimension
design
thus
greatly
enhances
use
applications
complex
environments,
especially
robots,
which
self-adaptable
changes
being
remotely
controllable.
Applied Physics Reviews,
Journal Year:
2022,
Volume and Issue:
9(1)
Published: Jan. 3, 2022
Liquid
crystal
elastomers
(LCEs),
owing
to
their
intrinsic
anisotropic
property
and
capability
of
generating
programmable
complex
morphologies
under
heat,
have
been
widely
used
for
applications
ranging
from
soft
robotics,
photonic
devices,
cell
culture,
tissue
engineering.
To
fulfill
the
various
circumstances,
high
actuation
efficiency,
mechanical
strength,
large
heat
electrical
conductivity,
or
responses
multiple
stimuli
are
required.
Therefore,
design
fabrication
LCE
composites
a
promising
strategy
enhanced
physical
properties
offer
additional
LCEs
such
as
light,
electric,
magnetic
fields.
In
this
review,
we
focus
on
recent
advances
in
composites,
where
defined
elastomeric
materials
broader
context.
Classic
with
metallic
nanoparticles,
particles,
liquid
metal,
carbon
nanotubes,
graphene
its
derivative,
black,
cellulose
nanocrystals
within
polymer
network
can
provide
unique
anisotropy
will
be
discussed.
We
conclude
challenges
future
research
opportunities.
Composite Structures,
Journal Year:
2021,
Volume and Issue:
279, P. 114800 - 114800
Published: Oct. 19, 2021
Hard-magnetic
soft
composites
consist
of
magneto-active
polymers
(MAPs)
where
the
fillers
are
composed
hard-magnetic
(magnetically
polarised)
particles.
These
novel
multifunctional
materials
experiencing
a
great
advance
from
last
few
years.
This
rise
has
been
motivated
by
possibility
controlling
ferromagnetic
patterns
during
manufacturing
process.
Thus,
structures
with
programmable
functionalities
can
be
conceptualised
and
implemented,
opening
new
routes
into
design
smart
components
opportunities
in
biomedical
engineering
robotics
fields.
In
this
work,
we
provide
an
overview
state
art
such
MAPs,
providing
key
fundamentals
reference
works.
To
end,
present
current
synthesis
experimental
characterisation
methods,
different
computational
modelling
approaches
across
scales,
detailed
presentation
their
potential
applications.
Finally,
overall
discussion
on
future
perspectives.
Advanced Functional Materials,
Journal Year:
2022,
Volume and Issue:
33(4)
Published: Nov. 11, 2022
Abstract
Direct
ink
writing
of
liquid
crystal
elastomers
(LCEs)
offers
a
new
opportunity
to
program
geometries
for
wide
variety
shape
transformation
modes
toward
applications
such
as
soft
robotics.
So
far,
most
3D‐printed
LCEs
are
thermally
actuated.
Herein,
3D‐printable
photoresponsive
gold
nanorod
(AuNR)/LCE
composite
is
developed,
allowing
photothermal
actuation
the
structures
with
AuNR
low
0.1
wt.%.
It
shown
that
printed
filament
has
superior
response
27%
strain
upon
irradiation
near‐infrared
(NIR)
light
(808
nm)
at
1.4
W
cm
−2
(corresponding
160
°C)
under
optimal
printing
conditions.
The
can
be
globally
or
locally
actuated
into
different
shapes
by
controlling
area
exposed
NIR
laser.
Taking
advantage
customized
enabled
3D
and
ability
control
light,
light‐responsive
robot
demonstrated
climb
on
ratchet
surface
maximum
speed
0.284
mm
s
−1
(on
flat
surface)
0.216
30°
titled
surface),
respectively,
corresponding
0.428
0.324
body
length
per
min,
large
mass
(0.23
g)
thickness
(1
mm).
Science Advances,
Journal Year:
2022,
Volume and Issue:
8(25)
Published: June 24, 2022
Reprogrammable
magneto-responsive
soft
actuators
capable
of
working
in
enclosed
and
confined
spaces
adapting
functions
under
changing
situations
are
highly
demanded
for
new-generation
smart
devices.
Despite
the
promising
prospect,
realization
versatile
morphing
modes
(more
than
bending)
local
magnetic
control
remains
challenging
but
is
crucial
further
on-demand
applications.
Here,
we
address
challenges
by
maximizing
unexplored
potential
magnetothermal
responsiveness
covalent
adaptable
networks
(CANs)
liquid
crystalline
elastomers
(LCEs).
Various
magneto-actuated
contraction-derived
motions
that
were
hard
to
achieve
previously
(e.g.,
bidirectional
shrinkage
dynamic
3D
patterns)
can
be
attained,
reprogrammed,
assembled
seamlessly
endow
functional
diversity
complexity.
By
integration
LCEs
with
different
threshold
values,
sequential
readily
realized.
Many
actuation
portfolios
performed
rationally
imputing
“logic
switch”
sequences.
Meanwhile,
our
systems
exhibit
additional
favorable
performances
including
stepwise
controllability,
multiresponsiveness,
self-healing,
remolding
ability.
Materials Horizons,
Journal Year:
2022,
Volume and Issue:
9(7), P. 1825 - 1849
Published: Jan. 1, 2022
We
review
recent
advances
in
4D
printing
of
LCEs,
with
emphasis
on
synthesis
and
processing
methods
that
enable
microscopic
changes
the
molecular
orientation
hence
macroscopic
properties
printed
objects.
Advanced Materials,
Journal Year:
2022,
Volume and Issue:
35(23)
Published: Dec. 3, 2022
Liquid
crystal
elastomers
(LCEs)
are
renowned
for
their
large,
reversible,
and
anisotropic
shape
change
in
response
to
various
external
stimuli
due
lightly
cross-linked
polymer
networks
with
an
oriented
mesogen
direction,
thus
showing
great
potential
applications
robotics,
bio-medics,
electronics,
optics,
energy.
To
fully
take
advantage
of
the
stimuli-responsive
behaviors
LCEs,
it
is
preferable
achieve
a
locally
controlled
alignment
into
monodomain
orientations.
In
recent
years,
application
4D
printing
LCEs
opens
new
doors
simultaneously
programming
3D
geometry,
offering
more
opportunities
higher
feasibility
fabrication
4D-printed
LCE
objects
desirable
properties.
Here,
state-of-the-art
advances
reviewed,
emphasis
on
both
mechanisms
applications.
First,
fundamental
properties
working
principles
representative
techniques
briefly
introduced.
Then,
by
advantages
over
conventional
manufacturing
methods
demonstrated.
Finally,
perspectives
current
challenges
development
trends
toward
discussed,
which
may
shed
light
future
research
directions
this
field.