Advanced Materials,
Journal Year:
2024,
Volume and Issue:
unknown
Published: Feb. 20, 2024
Abstract
Responsive
materials
possess
the
inherent
capacity
to
autonomously
sense
and
respond
various
external
stimuli,
demonstrating
physical
intelligence.
Among
diverse
array
of
responsive
materials,
liquid
crystalline
polymers
(LCPs)
stand
out
for
their
remarkable
reversible
stimuli‐responsive
shape‐morphing
properties
potential
creating
soft
robots.
While
numerous
reviews
have
extensively
detailed
progress
in
developing
LCP‐based
actuators
robots,
there
exists
a
need
comprehensive
summaries
that
elucidate
underlying
principles
governing
actuation
how
intelligence
is
embedded
within
these
systems.
This
review
provides
overview
recent
advancements
robots
endowed
with
using
LCPs.
structured
around
stimulus
conditions
categorizes
studies
involving
LCPs
based
on
fundamental
control
stimulation
logic
approach.
Specifically,
three
main
categories
are
examined:
systems
changing
those
operating
under
constant
equip
learning
capabilities.
Furthermore,
persisting
challenges
be
addressed
outlined
discuss
future
avenues
research
this
dynamic
field.
Advanced Materials,
Journal Year:
2022,
Volume and Issue:
34(21)
Published: March 31, 2022
Realization
of
muscle-like
actuation
for
a
liquid
crystal
elastomer
(LCE)
requires
mesogen
alignment,
which
is
typically
achieved/fixed
chemically
during
the
synthesis.
Post-synthesis
regulation
alignment
in
convenient
and
repeatable
manner
highly
desirable
yet
challenging.
Here,
dual-phase
LCE
network
designed
synthesized
with
crystalline
melting
transition
above
transition.
The
phase
can
serve
as
an
"alignment
frame"
to
fix
any
mechanical
deformation
via
shape
memory
mechanism,
leading
corresponding
phase.
be
erased
by
melting,
starting
point
reprogramming.
This
strategy
that
relies
on
physical
permits
repeated
reprogramming
timescale
seconds,
stark
contrast
typical
methods.
It
further
leads
unusual
versatility
designing
3D
printed
unlimited
programmable
modes.
Polymer Composites,
Journal Year:
2022,
Volume and Issue:
43(9), P. 6355 - 6380
Published: Aug. 12, 2022
Abstract
The
latest
developments
in
smart
systems
for
improved
human
lives
with
advanced
biomedical
devices
have
evolved
out
of
multi‐disciplinary
scientific
studies,
including
medicine,
biology,
material
sciences,
design,
manufacturing,
artificial
intelligence,
microelectronics,
and
so
forth.
growth
such
intelligent
is
primarily
possible
innovative
materials,
which
demonstrate
the
response
to
various
external
stimuli
like
temperature,
heat,
moisture,
light,
electromagnetic
field,
chemical
alteration.
Such
materials
been
recently
fabricated
using
different
additive
manufacturing
techniques
devise
personalized
unique,
complex,
novel
structures
that
can
adjust
conditions
over
time
are
specifically
attributed
4D
printing.
Novel
further
improve
continued
be
explored
employed.
This
review
paper
investigates
functional
polymer
nanocomposites,
offer
compliant
flexible
processes
high
strength,
low
cost,
long‐term
stability.
study
aims
deliver
a
comprehensive
deep
understanding
fundamental
mechanisms
involved,
future
possibilities
this
area
research.
European Polymer Journal,
Journal Year:
2024,
Volume and Issue:
205, P. 112718 - 112718
Published: Jan. 2, 2024
In
the
contemporary
era,
novel
manufacturing
technologies
like
additive
(AM)
have
revolutionized
different
engineering
sectors
including
biomedical,
aerospace,
electronics,
etc.
Four-dimensional
(4D)
printing
aka
AM
of
smart
materials
is
gaining
popularity
among
scientific
community,
which
has
excellent
ability
to
make
soft
structures
such
as
robots,
actuators,
and
grippers.
These
are
developed
by
applying
various
stimuli
pH,
temperature,
magnetic
field,
many
combinations
onto
materials.
Stimuli
in
3D
permit
shape-morphing
behaviors
bending,
twisting,
folding,
swelling,
rolling,
shrinking,
origami,
or
locomotion.
A
wide
variety
can
be
fabricated
through
incorporation
hard
particles
into
resulting
magneto-active
(MASMs).
With
this
integration,
magneto-thermal
coupling
actuation
allows
diverse
magneto-deformations,
facilitating
development
personalized
devices
that
capable
enhanced
deformation.
review,
guidelines
provided
on
for
MASMs
polymers
(MAPs),
composites,
hydrogels
(MAHs)
booming
flexible
wearable
biomimetic
devices.
Moreover,
3D-printed
robotics
an
outstanding
capacity
adapt
complicated
situations
advanced
actuating
applications.
Finally,
some
current
challenges
emerging
areas
exciting
technology
been
proposed.
Lastly,
it
anticipated
technological
advancements
developing
intelligent
will
a
significant
impact
design
real-world
Materials Horizons,
Journal Year:
2023,
Volume and Issue:
10(7), P. 2587 - 2598
Published: Jan. 1, 2023
Liquid
crystal
elastomer
(LCE)
fibers
exhibit
large
deformation
and
reversibility,
making
them
an
ideal
candidate
for
soft
actuators.
It
is
still
challenging
to
develop
a
scalable
strategy
endow
fiber
actuators
with
photoelectric
functions
achieve
tailorable
photo-electro-thermal
responsiveness
rapid
actuation
deformation.
Herein,
we
fabricated
multiresponsive
actuator
that
consists
of
LCE
long
obtained
by
continuous
dry
spinning
further
coated
it
polydopamine
(PDA)-modified
MXene
ink.
The
designed
PDA@MXene-integrated
used
shape-deformable
multi-trigger
can
be
photo-
electro-thermally
actuated.
proposed
combines
excellent
photothermal
long-term
electrically
conductive
PDA@MXene
shape-morphing
fiber,
enabling
their
robust
mechanical
flexibility,
multiple
fast
responses
(∼0.4
s),
stable
(∼60%).
As
proof-of-concept,
present
near-infrared
light-driven
artificial
muscle
lift
1000
times
the
weight
intelligent
circuit
switch
controllability
(∼0.1
s).
Importantly,
adaptive
smart
window
system
integrates
energy
harvesting/conversion
ingeniously
constructed
integration
propellable
curtain
woven
solar
cells.
This
work
provide
insights
into
development
advanced
materials
toward
robotics,
sustainable
savings
beyond.
Nature Communications,
Journal Year:
2023,
Volume and Issue:
14(1)
Published: June 20, 2023
Abstract
Untethered
magnetic
miniature
soft
robots
capable
of
accessing
hard-to-reach
regions
can
enable
safe,
disruptive,
and
minimally
invasive
medical
procedures.
However,
the
body
limits
integration
non-magnetic
external
stimuli
sources
on
robot,
thereby
restricting
functionalities
such
robots.
One
functionality
is
localised
heat
generation,
which
requires
solid
metallic
materials
for
increased
efficiency.
Yet,
using
these
compromises
compliance
safety
To
overcome
competing
requirements,
we
propose
a
pangolin-inspired
bi-layered
robot
design.
We
show
that
reported
design
achieves
heating
>
70
°C
at
large
distances
5
cm
within
short
period
time
<30
s,
allowing
users
to
realise
on-demand
in
tandem
with
shape-morphing
capabilities.
demonstrate
advanced
robotic
functionalities,
as
selective
cargo
release,
situ
demagnetisation,
hyperthermia
mitigation
bleeding,
tissue
phantoms
ex
vivo
tissues.
Science Advances,
Journal Year:
2023,
Volume and Issue:
9(23)
Published: June 7, 2023
Implanted
electronic
sensors,
compared
with
conventional
medical
imaging,
allow
monitoring
of
advanced
physiological
properties
soft
biological
tissues
continuously,
such
as
adhesion,
pH,
viscoelasticity,
and
biomarkers
for
disease
diagnosis.
However,
they
are
typically
invasive,
requiring
being
deployed
by
surgery,
frequently
cause
inflammation.
Here
we
propose
a
minimally
invasive
method
using
wireless
miniature
robots
to
in
situ
sense
the
tissues.
By
controlling
robot-tissue
interaction
external
magnetic
fields,
visualized
can
recover
tissue
precisely
from
robot
shape
fields.
We
demonstrate
that
traverse
multimodal
locomotion
viscoelasticity
on
porcine
mice
gastrointestinal
ex
vivo,
tracked
x-ray
or
ultrasound
imaging.
With
unprecedented
capability
sensing
minimal
invasion
high
resolution
deep
inside
our
body,
this
technology
potentially
enable
critical
applications
both
basic
research
clinical
practice.
Advanced Materials,
Journal Year:
2023,
Volume and Issue:
35(45)
Published: July 12, 2023
Liquid
crystal
elastomers
(LCE)
and
magnetic
soft
materials
are
promising
active
in
many
emerging
fields,
such
as
robotics.
Despite
the
high
demand
for
developing
that
combine
advantages
of
LCE
actuation,
lack
independent
programming
nematic
order
magnetization
a
single
material
still
hinders
desired
multi-responsiveness.
In
this
study,
ferromagnetic
(magLCE)
ink
with
is
developed
can
be
independently
programmed
to
anisotropic,
referred
"dual
anisotropy",
via
customized
3D-printing
platform.
The
magLCE
fabricated
by
dispersing
microparticles
matrix,
platform
created
integrating
magnet
3-DoF
motion
into
an
extrusion-based
3D
printer.
addition
magLCEs
also
actuated
heating
sources
(either
environmental
or
photo-heating
embedded
microparticles)
energy
density
tunable
actuation
temperature.
A
strip
robot
demonstrated
enhanced
adaptability
complex
environments
(different
terrains,
temperatures)
using
multi-actuation
strategy.
has
potential
applications
mechanical
memory,
multistable
metastructure
array
remote
writability
stable
memory.
Advanced Functional Materials,
Journal Year:
2023,
Volume and Issue:
33(14)
Published: Jan. 15, 2023
Abstract
Stimuli‐responsive
micro‐pillared
structures
can
perform
complex
and
precise
tasks
at
the
microscale
through
dynamic
reversible
deformation
of
pillars
in
response
to
external
triggers.
Magnetic
field
is
one
most
common
actuation
strategies
due
its
incomparable
advantages
such
as
instantaneous
response,
remote
nondestructive
control,
superior
biocompatibility.
Over
past
decade,
many
researches
are
attempted
design
optimize
magnetically‐responsive
micropillars
for
a
wide
range
applications
great
progresses
accomplished.
In
this
review,
important
aspects
recent
progress
covered
give
comprehensive
systematical
introduction
new
field,
from
mechanisms,
fabrication
methods,
patterns
practical
applications.
The
increasingly
maturing
techniques
provide
low‐cost
large‐scale
magnetic
with
homogeneous
responses.
Some
advanced
developed
fabricate
programmable
reprogrammable
responses
site‐specific
reconfigurable
actuations.
On
other
hand,
particle/droplet/light
manipulation,
flow
generation,
miniature
swimming/climbing/carrying
microrobots,
tunable
adhesion,
cellular
probe,
fog
collector,
anti‐ice
surfaces
also
summarized.
Finally,
current
challenges
that
limit
industrial
implementation
discussed
authors’
perspectives
on
future
directions
stated.
Advanced Materials,
Journal Year:
2024,
Volume and Issue:
36(19)
Published: Feb. 2, 2024
Diverse
and
adaptable
modes
of
complex
motion
observed
at
different
scales
in
living
creatures
are
challenging
to
reproduce
robotic
systems.
Achieving
dexterous
movement
conventional
robots
can
be
difficult
due
the
many
limitations
applying
rigid
materials.
Robots
based
on
soft
materials
inherently
deformable,
compliant,
adaptable,
adjustable,
making
robotics
conducive
creating
machines
with
complicated
actuation
gaits.
This
review
examines
mechanisms
modalities
deformation
that
respond
various
stimuli.
Then,
strategies
composite
considered
build
toward
actuators
combine
multiple
for
sophisticated
movements.
Examples
across
literature
illustrate
development
as
free-moving,
entirely
soft-bodied
locomotion
gaits
via
careful
manipulation
external
The
further
highlights
how
application
functional
into
components
enhances
their
locomotive
abilities.
Finally,
taking
advantage
shape-morphing
properties
materials,
reconfigurable
have
shown
capacity
adaptive
enable
transition
environments
optimal
efficiency.
Overall,
varied
multimodal
robots,
positioning
make
real-world
applications
intricate
tasks.
Advanced Science,
Journal Year:
2024,
Volume and Issue:
11(23)
Published: March 23, 2024
Abstract
Self‐oscillation
phenomena
observed
in
nature
serve
as
extraordinary
inspiration
for
designing
synthetic
autonomous
moving
systems.
Converting
self‐oscillation
into
designable
self‐sustained
locomotion
can
lead
to
a
new
generation
of
soft
robots
that
require
minimal/no
external
control.
However,
such
is
typically
constrained
single
mode
dictated
by
the
constant
surrounding
environment.
In
this
study,
liquid
crystal
elastomer
(LCE)
robot
capable
achieving
multimodal
locomotion,
with
specific
motion
being
controlled
via
substrate
adhesion
or
remote
light
stimulation
presented.
Specifically,
LCE
mechanically
trained
undergo
repeated
snapping
actions
ensure
its
rolling
gradient
thermal
field
atop
hotplate.
By
further
fine‐tuning
adhesion,
exhibits
reversible
transitions
between
and
jumping
modes.
addition,
be
manipulated
real
time
through
perform
other
diverse
motions
including
turning,
decelerating,
stopping,
backing
up,
steering
around
complex
obstacles.
The
principle
introducing
an
on‐demand
gate
control
offers
venue
future
robots.