Angewandte Chemie International Edition,
Journal Year:
2022,
Volume and Issue:
61(37)
Published: July 5, 2022
Ionic
liquids
(ILs)
and
deep
eutectic
solvents
(DESs)
debuted
with
a
promise
of
superior
sustainability
footprint
due
to
their
low
vapor
pressure.
However,
toxicity
high
cost
compromise
this
footprint,
impeding
real-world
applications.
Fortunately,
property
tunability
through
rational
selection
precursors,
including
bioderived
ones,
provides
strategy
ameliorate
toxicity,
lower
cost,
endow
new
functions.
This
Review
discusses
whether
ILs
DESs
are
sustainable
how
they
contribute
chemical
processes.
Angewandte Chemie International Edition,
Journal Year:
2020,
Volume and Issue:
59(36), P. 15402 - 15423
Published: March 11, 2020
Abstract
Increasing
the
stream
of
recycled
plastic
necessitates
an
approach
beyond
traditional
recycling
via
melting
and
re‐extrusion.
Various
chemical
processes
have
great
potential
to
enhance
rates.
In
this
Review,
a
summary
various
routes
assessment
life‐cycle
analysis
is
complemented
by
extensive
list
developed
companies
active
in
recycling.
We
show
that
each
currently
available
applicable
for
specific
waste
streams.
Thus,
only
combination
different
technologies
can
address
problem.
Research
should
focus
on
more
realistic,
contaminated
mixed
streams,
while
collection
sorting
infrastructure
will
need
be
improved,
is,
stricter
regulation.
This
Review
aims
inspire
both
science
innovation
production
higher
value
quality
products
from
suitable
reuse
or
valorization
create
necessary
economic
environmental
push
circular
economy.
Chemical Reviews,
Journal Year:
2021,
Volume and Issue:
122(2), P. 2752 - 2906
Published: Aug. 10, 2021
Photoinduced
chemical
transformations
have
received
in
recent
years
a
tremendous
amount
of
attention,
providing
plethora
opportunities
to
synthetic
organic
chemists.
However,
performing
photochemical
transformation
can
be
quite
challenge
because
various
issues
related
the
delivery
photons.
These
challenges
barred
widespread
adoption
steps
industry.
past
decade,
several
technological
innovations
led
more
reproducible,
selective,
and
scalable
photoinduced
reactions.
Herein,
we
provide
comprehensive
overview
these
exciting
advances,
including
flow
chemistry,
high-throughput
experimentation,
reactor
design
scale-up,
combination
photo-
electro-chemistry.
ChemSusChem,
Journal Year:
2021,
Volume and Issue:
14(10), P. 2145 - 2162
Published: April 9, 2021
In
recent
years,
mechanochemistry
has
been
growing
into
a
widely
accepted
alternative
for
chemical
synthesis.
addition
to
their
efficiency
and
practicality,
mechanochemical
reactions
are
also
recognized
sustainability.
The
association
between
Green
Chemistry
often
originates
from
the
solvent-free
nature
of
most
protocols,
which
can
reduce
waste
production.
However,
satisfies
more
than
one
Principles
Chemistry.
this
Review
we
will
present
series
examples
that
clearly
illustrate
how
significantly
contribute
fulfillment
in
holistic
manner.
Advanced Synthesis & Catalysis,
Journal Year:
2021,
Volume and Issue:
363(5), P. 1246 - 1271
Published: Jan. 21, 2021
Abstract
Mechanochemical
reactions
by
milling,
grinding
or
other
types
of
mechanical
action
have
emerged
as
a
salient
green
approach
because
its
wide
applications
towards
academic
and
industrial
chemical
communities
in
sustainable
solvent‐free/solvent‐less
processes.
Liquid‐assisted
(LAG)
an
extension
traditional
solvent‐free
mechanochemical
techniques
which
small
amount
liquid
is
used
additive
to
enhance
and/or
control
reactivity,
has
been
fruitfully
applied
the
screening
inclusion
compounds,
cocrystals,
salts,
solvates,
polymorphs.
However,
utilization
this
important
technique
synthesis
pharmaceutically
biologically
relevant
targets
was
not
adequately
investigated.
This
review
article
summarizes
overview
latest
development
LAG
approaches
active
pharmaceutical
ingredients
(API)
drug‐like
fragments,
highlights
superiority
versus
conventional
syntheses.
magnified
image
Chemical Society Reviews,
Journal Year:
2022,
Volume and Issue:
51(3), P. 1045 - 1097
Published: Jan. 1, 2022
This
review
illustrates
molecular-scale
confinement,
containment,
isolation,
and
related
concepts
to
present
MOF-centric
catalysts
realize
desired
chemical
transformations.
Chemical Reviews,
Journal Year:
2020,
Volume and Issue:
121(1), P. 110 - 139
Published: Aug. 6, 2020
In
this
review,
transition
metal-catalyzed
methodologies
and
applications
that
exploit
C–C
bond
cleavage
of
vinylcyclopropanes
(VCPs)
are
summarized
with
a
focus
on
cycloaddition
related
addition
reactions.
Transition
metals,
including
palladium,
nickel,
iron,
ruthenium,
rhodium,
cobalt,
iridium,
can
catalyze
the
bonds
in
activated
or
nonactivated
VCPs.
Additionally,
these
bond-breaking
reactions
occur
as
intra-
intermolecular
processes.
The
properties
VCPs
discussed
Introduction.
Various
involving
then
next
chapter.
cycloadditions
following
Finally,
challenges
potential
opportunities
outlined
last
Chemical Society Reviews,
Journal Year:
2021,
Volume and Issue:
50(8), P. 5126 - 5164
Published: Jan. 1, 2021
While
Nature
harnesses
RNA
and
DNA
to
store,
read
write
genetic
information,
the
inherent
programmability,
synthetic
accessibility
wide
functionality
of
these
nucleic
acids
make
them
attractive
tools
for
use
in
a
vast
array
applications.
