The trade-off anionic modulation in metal–organic glasses showing color-tunable persistent luminescence DOI
Tianhong Chen, Yu‐Juan Ma, Guowei Xiao

et al.

Materials Horizons, Journal Year: 2024, Volume and Issue: 11(20), P. 4951 - 4960

Published: Jan. 1, 2024

Ultralong room-temperature phosphorescence (RTP) and thermally activated delayed fluorescence (TADF) materials provide exciting opportunities for the rational design of persistent luminescence owing to their long-lived excitons.

Language: Английский

Lattice oxygen activation and local electric field enhancement by co-doping Fe and F in CoO nanoneedle arrays for industrial electrocatalytic water oxidation DOI Creative Commons
Pengcheng Ye,

K. Fang,

Haiyan Wang

et al.

Nature Communications, Journal Year: 2024, Volume and Issue: 15(1)

Published: Feb. 3, 2024

Abstract Oxygen evolution reaction (OER) is critical to renewable energy conversion technologies, but the structure-activity relationships and underlying catalytic mechanisms in catalysts are not fully understood. We herein demonstrate a strategy promote OER with simultaneously achieved lattice oxygen activation enhanced local electric field by dual doping of cations anions. Rough arrays Fe F co-doped CoO nanoneedles constructed, low overpotential 277 mV at 500 mA cm −2 achieved. The dually doped could cooperatively tailor electronic properties CoO, leading improved metal-oxygen covalency stimulated activation. Particularly, induces synergetic effect tip enhancement proximity effect, which effectively concentrates OH − ions, optimizes barrier promotes O 2 desorption. This work demonstrates conceptual couple for effective electrocatalytic water oxidation.

Language: Английский

Citations

104

Photoswitchable diarylethenes: From molecular structures to biological applications DOI
Ziyong Li,

Xiaoyan Zeng,

Caimin Gao

et al.

Coordination Chemistry Reviews, Journal Year: 2023, Volume and Issue: 497, P. 215451 - 215451

Published: Sept. 18, 2023

Language: Английский

Citations

73

Synergistic Interaction between Metal Single‐Atoms and Defective WO3−x Nanosheets for Enhanced Sonodynamic Cancer Therapy DOI Creative Commons
Zhan Zhou, Tao Wang, Tingting Hu

et al.

Advanced Materials, Journal Year: 2024, Volume and Issue: 36(23)

Published: Feb. 27, 2024

Abstract Although metal single‐atom (SA)‐based nanomaterials are explored as sonosensitizers for sonodynamic therapy (SDT), they normally exhibit poor activities and need to combine with other therapeutic strategies. Herein, the deposition of SAs on oxygen vacancy (OV)‐rich WO 3− x nanosheets generate a synergistic effect efficient SDT is reported. Crystalline 3 OV‐rich first prepared by simple calcination ·H 2 O under an air N atmosphere, respectively. Pt, Cu, Fe, Co, Ni then deposited obtain SA‐decorated nanocomposites (M‐WO ). Importantly, Cu‐WO sonosensitizer exhibits much higher activity ultrasound (US)‐induced production reactive species than that Cu , which also M‐WO nanosheets. Both experimental theoretical results suggest excellent performance should be attributed between OVs. Therefore, after polyethylene glycol modification, can quickly kill cancer cells in vitro effectively eradicate tumors vivo US irradiation. Transcriptome sequencing analysis further molecular validation ‐mediated SDT‐activated apoptosis TNF signaling pathways potential drivers tumor induction.

Language: Английский

Citations

44

Preventing Dissolution of Cathode Active Materials by Ion‐anchoring Zeolite‐based Separators for Durable Aqueous Zinc Batteries** DOI
Yao Qin, Xin Wang

Angewandte Chemie International Edition, Journal Year: 2023, Volume and Issue: 63(2)

Published: Nov. 30, 2023

Aqueous zinc batteries have emerged as promising energy storage devices due to their safety and low cost. However, they face challenges such anodic dendrite formation cathodic compound dissolution. Here, we present the development of a polymer-matrixed zeolite separator (SZ) by synthesizing materials on flexible polymeric membrane. This acts an effective ionic barrier, preventing leaching shuttling vanadium from cathode, while significantly inhibiting by-products dendrites. The SZ cells demonstrate stable operation for more than 400 cycles at 0.5 A g

Language: Английский

Citations

42

CuS/Co-Ferrocene-MOF Nanocomposites for Photothermally Enhanced Chemodynamic Antibacterial Therapy DOI

Aidi Hou,

Yuhang Du,

Yumeng Su

et al.

ACS Applied Nano Materials, Journal Year: 2024, Volume and Issue: 7(9), P. 10998 - 11007

Published: April 29, 2024

Infections caused by bacteria pose a serious threat to public health, and there is need for numerous innovative, antibiotic-free antimicrobial medicines. Herein, we describe the synthesis of CuS/Co-ferrocene-MOF (CuS/Co-Fc-MOF) nanocomposites, formed coupling CuS nanoparticles (NPs) two-dimensional (2D) Co-Fc-MOF nanosheets, that constitutes an platform capable near-infrared (NIR) photothermal promotion chemodynamic antibacterial. 2D CuS/Co-Fc-MOF nanocomposites consist nanosheets with dimensions approximately 100–200 nm thicknesses 13.1–15.6 nm, where NPs, size about 8 are excellently dispersed on surface nanosheets. The diverse valence states cobalt iron in enable them undergo Fenton-like reactions H2O2, thus generating highly oxidizing ·OH therapy (CDT). utilization local plasmonic resonance effect NPs enables enhancement CDT activity under laser irradiation. More importantly, can achieve rapid (15 min) NIR laser-assisted killing both S. aureus E. coli bacterial infection microenvironment compared Therefore, be employed as promising nanoagent promote photothermally augmented antibacterial therapy.

Language: Английский

Citations

39

U(VI) removal on polymer adsorbents: Recent development and future challenges DOI
Yong‐Gang Zhao, Lihui Chen, Mingli Ye

et al.

Critical Reviews in Environmental Science and Technology, Journal Year: 2024, Volume and Issue: unknown, P. 1 - 23

Published: Sept. 10, 2024

Language: Английский

Citations

37

A Zn-MOF-GOx-based cascade nanoreactor promotes diabetic infected wound healing by NO release and microenvironment regulation DOI
Guangli Xiang, Bingjie Wang,

Wenshang Zhang

et al.

Acta Biomaterialia, Journal Year: 2024, Volume and Issue: 182, P. 245 - 259

Published: May 9, 2024

Language: Английский

Citations

20

Ru-regulated electronic structure CoNi-MOF nanosheets advance water electrolysis kinetics in alkaline and seawater media DOI
Wenqiang Li,

Bowen Guo,

Zhang Ka

et al.

Journal of Colloid and Interface Science, Journal Year: 2024, Volume and Issue: 668, P. 181 - 189

Published: April 21, 2024

Language: Английский

Citations

16

Recent advances in metal-organic frameworks for oxygen evolution reaction electrocatalysts DOI Open Access
Ming Liu, Yinqiang Zhang, Xuemin Wang

et al.

Science China Chemistry, Journal Year: 2023, Volume and Issue: 66(10), P. 2754 - 2779

Published: Sept. 11, 2023

Language: Английский

Citations

33

Lipase from Yarrowia lipolytica: Prospects as an Industrial Biocatalyst for Biotechnological Applications DOI Creative Commons
Jessica Lopes da Silva, Misael Bessa Sales, Viviane de Castro Bizerra

et al.

Fermentation, Journal Year: 2023, Volume and Issue: 9(7), P. 581 - 581

Published: June 21, 2023

This paper aims to present the advances related biotechnological application of lipases Y. lipolytica, presenting their properties and more efficient ways use them in different industrial applications. Waste treatment bioremediation highlight recent studies interest large-scale applications food sector biofuel production. The USA China, two major world powers industy, are utmost importance search for improvement development a controlled system production significant number lipase from lipolytica.

Language: Английский

Citations

28