Materials Horizons,
Journal Year:
2024,
Volume and Issue:
11(20), P. 4951 - 4960
Published: Jan. 1, 2024
Ultralong
room-temperature
phosphorescence
(RTP)
and
thermally
activated
delayed
fluorescence
(TADF)
materials
provide
exciting
opportunities
for
the
rational
design
of
persistent
luminescence
owing
to
their
long-lived
excitons.
Nature Communications,
Journal Year:
2024,
Volume and Issue:
15(1)
Published: Feb. 3, 2024
Abstract
Oxygen
evolution
reaction
(OER)
is
critical
to
renewable
energy
conversion
technologies,
but
the
structure-activity
relationships
and
underlying
catalytic
mechanisms
in
catalysts
are
not
fully
understood.
We
herein
demonstrate
a
strategy
promote
OER
with
simultaneously
achieved
lattice
oxygen
activation
enhanced
local
electric
field
by
dual
doping
of
cations
anions.
Rough
arrays
Fe
F
co-doped
CoO
nanoneedles
constructed,
low
overpotential
277
mV
at
500
mA
cm
−2
achieved.
The
dually
doped
could
cooperatively
tailor
electronic
properties
CoO,
leading
improved
metal-oxygen
covalency
stimulated
activation.
Particularly,
induces
synergetic
effect
tip
enhancement
proximity
effect,
which
effectively
concentrates
OH
−
ions,
optimizes
barrier
promotes
O
2
desorption.
This
work
demonstrates
conceptual
couple
for
effective
electrocatalytic
water
oxidation.
Advanced Materials,
Journal Year:
2024,
Volume and Issue:
36(23)
Published: Feb. 27, 2024
Abstract
Although
metal
single‐atom
(SA)‐based
nanomaterials
are
explored
as
sonosensitizers
for
sonodynamic
therapy
(SDT),
they
normally
exhibit
poor
activities
and
need
to
combine
with
other
therapeutic
strategies.
Herein,
the
deposition
of
SAs
on
oxygen
vacancy
(OV)‐rich
WO
3−
x
nanosheets
generate
a
synergistic
effect
efficient
SDT
is
reported.
Crystalline
3
OV‐rich
first
prepared
by
simple
calcination
·H
2
O
under
an
air
N
atmosphere,
respectively.
Pt,
Cu,
Fe,
Co,
Ni
then
deposited
obtain
SA‐decorated
nanocomposites
(M‐WO
).
Importantly,
Cu‐WO
sonosensitizer
exhibits
much
higher
activity
ultrasound
(US)‐induced
production
reactive
species
than
that
Cu
,
which
also
M‐WO
nanosheets.
Both
experimental
theoretical
results
suggest
excellent
performance
should
be
attributed
between
OVs.
Therefore,
after
polyethylene
glycol
modification,
can
quickly
kill
cancer
cells
in
vitro
effectively
eradicate
tumors
vivo
US
irradiation.
Transcriptome
sequencing
analysis
further
molecular
validation
‐mediated
SDT‐activated
apoptosis
TNF
signaling
pathways
potential
drivers
tumor
induction.
Angewandte Chemie International Edition,
Journal Year:
2023,
Volume and Issue:
63(2)
Published: Nov. 30, 2023
Aqueous
zinc
batteries
have
emerged
as
promising
energy
storage
devices
due
to
their
safety
and
low
cost.
However,
they
face
challenges
such
anodic
dendrite
formation
cathodic
compound
dissolution.
Here,
we
present
the
development
of
a
polymer-matrixed
zeolite
separator
(SZ)
by
synthesizing
materials
on
flexible
polymeric
membrane.
This
acts
an
effective
ionic
barrier,
preventing
leaching
shuttling
vanadium
from
cathode,
while
significantly
inhibiting
by-products
dendrites.
The
SZ
cells
demonstrate
stable
operation
for
more
than
400
cycles
at
0.5
A
g
ACS Applied Nano Materials,
Journal Year:
2024,
Volume and Issue:
7(9), P. 10998 - 11007
Published: April 29, 2024
Infections
caused
by
bacteria
pose
a
serious
threat
to
public
health,
and
there
is
need
for
numerous
innovative,
antibiotic-free
antimicrobial
medicines.
Herein,
we
describe
the
synthesis
of
CuS/Co-ferrocene-MOF
(CuS/Co-Fc-MOF)
nanocomposites,
formed
coupling
CuS
nanoparticles
(NPs)
two-dimensional
(2D)
Co-Fc-MOF
nanosheets,
that
constitutes
an
platform
capable
near-infrared
(NIR)
photothermal
promotion
chemodynamic
antibacterial.
2D
CuS/Co-Fc-MOF
nanocomposites
consist
nanosheets
with
dimensions
approximately
100–200
nm
thicknesses
13.1–15.6
nm,
where
NPs,
size
about
8
are
excellently
dispersed
on
surface
nanosheets.
The
diverse
valence
states
cobalt
iron
in
enable
them
undergo
Fenton-like
reactions
H2O2,
thus
generating
highly
oxidizing
·OH
therapy
(CDT).
utilization
local
plasmonic
resonance
effect
NPs
enables
enhancement
CDT
activity
under
laser
irradiation.
More
importantly,
can
achieve
rapid
(15
min)
NIR
laser-assisted
killing
both
S.
aureus
E.
coli
bacterial
infection
microenvironment
compared
Therefore,
be
employed
as
promising
nanoagent
promote
photothermally
augmented
antibacterial
therapy.
Fermentation,
Journal Year:
2023,
Volume and Issue:
9(7), P. 581 - 581
Published: June 21, 2023
This
paper
aims
to
present
the
advances
related
biotechnological
application
of
lipases
Y.
lipolytica,
presenting
their
properties
and
more
efficient
ways
use
them
in
different
industrial
applications.
Waste
treatment
bioremediation
highlight
recent
studies
interest
large-scale
applications
food
sector
biofuel
production.
The
USA
China,
two
major
world
powers
industy,
are
utmost
importance
search
for
improvement
development
a
controlled
system
production
significant
number
lipase
from
lipolytica.