Visible-light-promoted phosphorylation carbonylation of unactivated alkenes DOI

Ren‐Guan Miao,

Yuanrui Wang, Xiao‐Feng Wu

et al.

Journal of Catalysis, Journal Year: 2024, Volume and Issue: unknown, P. 115933 - 115933

Published: Dec. 1, 2024

Language: Английский

Copper-Catalyzed Radical Relay 1,3-Carbocarbonylation across Two Distinct C═C Bonds DOI

Nan‐Nan Dai,

Yue-Jiao Lu,

Zhong-Qi Wu

et al.

Organic Letters, Journal Year: 2024, Volume and Issue: 26(15), P. 3014 - 3019

Published: March 28, 2024

The radical relay provides an effective paradigm for intermolecular assembly to achieve functionalization across remote chemical bonds. Herein, we report the first 1,3-carbocarbonylation of α-carbonyl alkyl bromides two separate C═C reaction is highly chemo- and regioselective, with C(sp3)–C(sp3) bonds one C═O bond formed in a single orchestrated operation. In addition, synthesis method under mild conditions using inexpensive copper as catalyst allows facile access structurally diverse products. plausible mechanism investigated through series control experiments, including trapping, clock critical intermediate 18O labeling experiment.

Language: Английский

Citations

12

Sustainable carbonylative transformation of alkyl iodides to amides via crosslinking of EDA and XAT DOI

Hefei Yang,

Le‐Cheng Wang,

Xiao‐Feng Wu

et al.

Chinese Chemical Letters, Journal Year: 2025, Volume and Issue: unknown, P. 110843 - 110843

Published: Jan. 1, 2025

Language: Английский

Citations

2

Photo-Promoted carbonylative Difunctionalization of alkenes toward β-Aminoketones DOI

Qiangwei Li,

Le‐Cheng Wang,

Xiao‐Feng Wu

et al.

Journal of Catalysis, Journal Year: 2025, Volume and Issue: unknown, P. 115935 - 115935

Published: Jan. 1, 2025

Language: Английский

Citations

0

Carbonylative five-component synthesis of amides and esters with α-quaternary carbon center DOI
Zhipeng Bao,

Hefei Yang,

A. Ruhan

et al.

Chinese Chemical Letters, Journal Year: 2025, Volume and Issue: unknown, P. 111150 - 111150

Published: March 1, 2025

Language: Английский

Citations

0

Light-induced perfluoroalkylative carbonylation of unactivated alkenes with a recyclable photocatalyst DOI Creative Commons
Heng Yang, Shuyu Yang, Xiao‐Feng Wu

et al.

Green Synthesis and Catalysis, Journal Year: 2024, Volume and Issue: unknown

Published: May 1, 2024

The development of heterogeneous catalysis difunctionalization olefins is great significance because it can save costs in the industry. Here, we report perfluoroalkyl carbonylation reaction inactive catalyzed by titanium dioxide under light, obtaining β-perfluoroalkylamide compounds. catalyst has high activity and wide functional group tolerance maintain after multiple cycles. This reduces use precious metals, avoids ligands, easily be separated from mixtures.

Language: Английский

Citations

2

Visible light-promoted oxycarbonylation of unactivated alkenes DOI Creative Commons

Hefei Yang,

Yuanrui Wang,

Le‐Cheng Wang

et al.

EES Catalysis, Journal Year: 2024, Volume and Issue: 2(6), P. 1247 - 1252

Published: Jan. 1, 2024

We developed an intermolecular oxygen-centered radical addition carbonylation reaction of unactivated alkenes under visible light irradiation which provides a new strategy to alkenes.

Language: Английский

Citations

2

Palladium-catalyzed multi-component Heck alkynylcarbonylation of unactivated alkenes for synthesis of β,γ-alkynoates DOI

Xin Peng,

Huanliang Hong, Li Wang

et al.

Organic Chemistry Frontiers, Journal Year: 2024, Volume and Issue: 11(12), P. 3451 - 3458

Published: Jan. 1, 2024

A general and unprecedented Pd-catalysed four-component inter-molecular Heck alkynylcarbonylation involving haloalkynes, alkenes, carbon monoxide alcohols based on a molecular queuing strategy is presented.

Language: Английский

Citations

1

Visible-light-promoted phosphorylation carbonylation of unactivated alkenes DOI

Ren‐Guan Miao,

Yuanrui Wang, Xiao‐Feng Wu

et al.

Journal of Catalysis, Journal Year: 2024, Volume and Issue: unknown, P. 115933 - 115933

Published: Dec. 1, 2024

Language: Английский

Citations

0