Journal of Catalysis, Journal Year: 2024, Volume and Issue: unknown, P. 115933 - 115933
Published: Dec. 1, 2024
Language: Английский
Journal of Catalysis, Journal Year: 2024, Volume and Issue: unknown, P. 115933 - 115933
Published: Dec. 1, 2024
Language: Английский
Organic Letters, Journal Year: 2024, Volume and Issue: 26(15), P. 3014 - 3019
Published: March 28, 2024
The radical relay provides an effective paradigm for intermolecular assembly to achieve functionalization across remote chemical bonds. Herein, we report the first 1,3-carbocarbonylation of α-carbonyl alkyl bromides two separate C═C reaction is highly chemo- and regioselective, with C(sp3)–C(sp3) bonds one C═O bond formed in a single orchestrated operation. In addition, synthesis method under mild conditions using inexpensive copper as catalyst allows facile access structurally diverse products. plausible mechanism investigated through series control experiments, including trapping, clock critical intermediate 18O labeling experiment.
Language: Английский
Citations
12Chinese Chemical Letters, Journal Year: 2025, Volume and Issue: unknown, P. 110843 - 110843
Published: Jan. 1, 2025
Language: Английский
Citations
2Journal of Catalysis, Journal Year: 2025, Volume and Issue: unknown, P. 115935 - 115935
Published: Jan. 1, 2025
Language: Английский
Citations
0Chinese Chemical Letters, Journal Year: 2025, Volume and Issue: unknown, P. 111150 - 111150
Published: March 1, 2025
Language: Английский
Citations
0Green Synthesis and Catalysis, Journal Year: 2024, Volume and Issue: unknown
Published: May 1, 2024
The development of heterogeneous catalysis difunctionalization olefins is great significance because it can save costs in the industry. Here, we report perfluoroalkyl carbonylation reaction inactive catalyzed by titanium dioxide under light, obtaining β-perfluoroalkylamide compounds. catalyst has high activity and wide functional group tolerance maintain after multiple cycles. This reduces use precious metals, avoids ligands, easily be separated from mixtures.
Language: Английский
Citations
2EES Catalysis, Journal Year: 2024, Volume and Issue: 2(6), P. 1247 - 1252
Published: Jan. 1, 2024
We developed an intermolecular oxygen-centered radical addition carbonylation reaction of unactivated alkenes under visible light irradiation which provides a new strategy to alkenes.
Language: Английский
Citations
2Organic Chemistry Frontiers, Journal Year: 2024, Volume and Issue: 11(12), P. 3451 - 3458
Published: Jan. 1, 2024
A general and unprecedented Pd-catalysed four-component inter-molecular Heck alkynylcarbonylation involving haloalkynes, alkenes, carbon monoxide alcohols based on a molecular queuing strategy is presented.
Language: Английский
Citations
1Journal of Catalysis, Journal Year: 2024, Volume and Issue: unknown, P. 115933 - 115933
Published: Dec. 1, 2024
Language: Английский
Citations
0