Bicyclic (alkyl)(amino)carbene (BICAAC)-supported phosphinidenes DOI
Ritu Yadav, Bindusagar Das, Ashi Singh

et al.

Dalton Transactions, Journal Year: 2023, Volume and Issue: 52(45), P. 16680 - 16687

Published: Jan. 1, 2023

Herein, the synthesis and characterization of bicyclic (alkyl)(amino)carbene (BICAAC)-stabilized phosphinidenes (1-4) are reported. Compounds 1-3 were obtained by reacting trihalophosphine [PX3, X = Cl (1), Br (2), I (3)] with BICAAC in THF. A BICAAC-stabilized bis-phosphinidene (4) was from reduction compound 2. All four compounds characterized X-ray crystallography heteronuclear NMR spectroscopy. Theoretical calculations indicated predominant C(carbene)P double bond characteristic 1-4.

Language: Английский

Air and Water Stable Bicyclic (alkyl)(amino)Carbene Stabilized Phosphenium Cation: Reactivity and Selective Fluoride Ion Affinity DOI Open Access
Ritu Yadav, Ankita Sharma, Bindusagar Das

et al.

Chemistry - A European Journal, Journal Year: 2024, Volume and Issue: 30(62)

Published: Aug. 15, 2024

Abstract The synthesis and reactivity of an air water stable Bicyclic (alkyl)(amino)carbene (BICAAC) stabilized phosphenium cation (1) is reported. Air are rare in the literature. Compound 1 obtained by reaction BICAAC with Ph 2 PCl THF followed anion exchange LiOTf. reduction oxidation yielded corresponding α‐radical phosphine species (2) oxide (3) respectively. All compounds well characterized single crystal X‐ray diffraction studies. Lewis acidity 3 determined conducting fluoride ion affinity experiments using UV‐Vis spectrophotometry multinuclei NMR spectroscopy. Compounds exhibited selective binding to but did not interact other halides (Cl − Br ). Quantum chemical calculations were performed understand structure nature bonding interactions these compounds, as comprehend specific over halide ions.

Language: Английский

Citations

3
Diborane, Diborene and M(I)‐η2‐Diborene Complexes Stabilized by Bicyclic (Alkyl)(Amino)Carbene (M = Cu and Ag) DOI
Manu Adhikari, Sriman De, Krishna K. Manar

et al.

European Journal of Inorganic Chemistry, Journal Year: 2024, Volume and Issue: 27(32)

Published: March 23, 2024

Abstract BICAAC (bicyclic (alkyl)(amino)carbene) as ambiphilic carbene has been utilized to prepare stable neutral tetrahydrodiborane [BICAAC (H 2 )B−B(H ) BICAAC] and dihydrodiborene [BICAAC→(H)B=B(H) compounds. The Lewis base stabilized is isoelectronic isolobal conventional olefins therefore offers the possibility explore formation of π ‐complexes with transition metals. Reaction diborene coinage metal salts (CuCl, AgBr CuI) leads ‐diborene complexes via η side‐on coordination. These are first examples complexes. Interestingly, coordination two CuCl units observed for time a considerable lengthening >B=B< B C bonds manifesting key role combined small steric requirements hydride substituents in stabilizing these energy decomposition analysis (EDA) calculations reveal interaction between Cu(I)/Ag(I) mainly electrostatic nature.

Language: Английский

Citations

1
Bicyclic (Alkyl)(Amino)Carbenes (BICAACs): Synthesis, Characteristics, and Applications DOI
Ankita Sharma,

Unnikrishnan Nair K,

Subrata Kundu

et al.

Dalton Transactions, Journal Year: 2024, Volume and Issue: unknown

Published: Jan. 1, 2024

This review covers the synthesis, characterization, and reactivity of bicyclic(alkyl)(amino)carbenes (BICAACs) outlines diverse applications BICAACs in organometallic chemistry, metal-free catalysis, main-group chemistry.

Language: Английский

Citations

1
Bicyclic (alkyl)(amino)carbene (BICAAC)-supported phosphinidenes DOI
Ritu Yadav, Bindusagar Das, Ashi Singh

et al.

Dalton Transactions, Journal Year: 2023, Volume and Issue: 52(45), P. 16680 - 16687

Published: Jan. 1, 2023

Herein, the synthesis and characterization of bicyclic (alkyl)(amino)carbene (BICAAC)-stabilized phosphinidenes (1-4) are reported. Compounds 1-3 were obtained by reacting trihalophosphine [PX3, X = Cl (1), Br (2), I (3)] with BICAAC in THF. A BICAAC-stabilized bis-phosphinidene (4) was from reduction compound 2. All four compounds characterized X-ray crystallography heteronuclear NMR spectroscopy. Theoretical calculations indicated predominant C(carbene)P double bond characteristic 1-4.

Language: Английский

Citations

2