Polymers,
Journal Year:
2024,
Volume and Issue:
16(24), P. 3575 - 3575
Published: Dec. 21, 2024
Smart
fibers
with
tunable
luminescence
properties,
as
a
new
form
of
visual
output,
present
the
potential
to
revolutionize
personal
living
habits
in
future
and
are
receiving
more
attention.
However,
huge
challenge
smart
wearable
materials
is
their
stretching
capability
for
seamless
integration
human
body.
Herein,
stretchable
thermochromic
fluorescent
prepared
based
on
self-crystallinity
phase
change,
using
elastic
polyurethane
(PU)
fiber
matrix,
meet
dynamic
requirements
The
switching
fluorescence-emitting
characteristic
derived
from
reversible
conversion
dispersion/aggregation
state
fluorophore
coumarin
6
(C6)
quencher
methylene
blue
(MB)
phase-change
material
hexadecanoic
acid
(HcA)
during
heating/cooling
processes.
Considering
important
role
materials,
dye
encapsuled
solid
via
piercing–solidifying
method
avoid
dissolution
HcA
by
organic
solvent
PU
spinning
solution
maintain
excellent
behavior
fibers.
obtained
wet
exhibit
good
emission
contrast
reversibility,
well
high
elasticity
800%
elongation.
This
work
presents
strategy
constructing
human–machine
interaction
communications.
Advanced Materials,
Journal Year:
2024,
Volume and Issue:
36(31)
Published: May 17, 2024
Abstract
Electronic
skin
(e‐skin),
a
skin‐like
wearable
electronic
device,
holds
great
promise
in
the
fields
of
telemedicine
and
personalized
healthcare
because
its
good
flexibility,
biocompatibility,
conformability,
sensing
performance.
E‐skin
can
monitor
various
health
indicators
human
body
real
time
over
long
term,
including
physical
(exercise,
respiration,
blood
pressure,
etc.)
chemical
(saliva,
sweat,
urine,
etc.).
In
recent
years,
development
materials,
analysis,
manufacturing
technologies
has
promoted
significant
e‐skin,
laying
foundation
for
application
next‐generation
medical
devices.
Herein,
properties
required
e‐skin
monitoring
devices
to
achieve
long‐term
precise
summarize
several
detectable
field
are
discussed.
Subsequently,
applications
integrated
systems
reviewed.
Finally,
current
challenges
future
directions
this
This
review
is
expected
generate
interest
inspiration
improvement
systems.
Advanced Optical Materials,
Journal Year:
2025,
Volume and Issue:
unknown
Published: Jan. 24, 2025
Abstract
Electrochromic
fibers
adept
at
miniaturization
and
seamless
integration
with
the
soft
dynamically
deformed
human
body,
emerge
as
promising
frontrunners
in
smart
displays
a
new
form
of
wearable
visual
output
devices.
However,
it
remains
huge
challenge
to
simultaneously
achieve
conformal
various
colors,
desirable
color‐changing
performance,
reliable
mechanical
properties,
simple
preparation
procedure
for
intelligent
display
complex
information
during
human‐machine
interface.
Herein,
full‐color
electro‐thermochromic
fluorescent
fast
response
(<1
s),
off–on
switching
luminescence,
good
reversibility
(>50
cycles),
programmable
control,
are
developed
on
basis
self‐crystallinity
phase
changes
Förster
resonance
energy
transfer;
performed
self‐adaptive
(≈2
s)
multi‐targets
dynamic
environments
assistance
deep
learning,
by
using
textile
system
an
example
implementation.
The
work
unifies
learning
make
possible
bio‐inspired
ability,
which
targets
encompass
diverse
array
morphological
entities,
extending
even
stimuli
like
light,
scent,
temperature,
humidity.
This
fiber
presents
unprecedented
opportunities
next‐generation
electronics
systems,
fostering
communication
adaptability
within
environments.
Angewandte Chemie International Edition,
Journal Year:
2024,
Volume and Issue:
unknown
Published: Sept. 24, 2024
Thermochromic
fluorescent
materials
(TFMs)
have
attracted
significant
attention
due
to
their
unique
colorimetric
response
temperature.
However,
existing
TFMs
still
suffer
from
weak
stimulus
responsiveness,
broad
temperature
ranges,
uncontrollable
emission
color
changes,
and
low
quantum
yields.
In
this
study,
we
address
these
issues
by
designing
synthesizing
three
diketone-boron
complexes
with
distinct
wavelengths
(NWPU-(2-4)).
Utilizing
a
molecular
engineering
strategy
manipulate
intramolecular
charge
transfer
transitions
packing
modes,
our
synthesized
exhibit
efficient
fluorescence
in
both
solution
solid
states.
Moreover,
are
highly
sensitive
environmental
polarity.
By
incorporating
compounds
into
thermosensitive
matrices
of
long-chain
alkanes,
produced
varied
peak
variation
ranges.
Notably,
the
TFM
based
on
NWPU-4,
owing
its
strong
dense
J-aggregate
configuration,
not
only
exhibits
intense
spanning
deep
red
near-infrared
spectrum
but
also
displays
remarkable
90
nm
range
thermochromic
properties.
Ultimately,
it
was
successfully
applied
programmable,
thermally
controlled,
multi-level
information
encryption.
Angewandte Chemie,
Journal Year:
2024,
Volume and Issue:
unknown
Published: Sept. 24, 2024
Abstract
Thermochromic
fluorescent
materials
(TFMs)
have
attracted
significant
attention
due
to
their
unique
colorimetric
response
temperature.
However,
existing
TFMs
still
suffer
from
weak
stimulus
responsiveness,
broad
temperature
ranges,
uncontrollable
emission
color
changes,
and
low
quantum
yields.
In
this
study,
we
address
these
issues
by
designing
synthesizing
three
diketone‐boron
complexes
with
distinct
wavelengths
(
NWPU‐(2–4)
).
Utilizing
a
molecular
engineering
strategy
manipulate
intramolecular
charge
transfer
transitions
packing
modes,
our
synthesized
exhibit
efficient
fluorescence
in
both
solution
solid
states.
Moreover,
are
highly
sensitive
environmental
polarity.
By
incorporating
compounds
into
thermosensitive
matrices
of
long‐chain
alkanes,
produced
varied
peak
variation
ranges.
Notably,
the
TFM
based
on
NWPU‐4
,
owing
its
strong
dense
J‐aggregate
configuration,
not
only
exhibits
intense
spanning
deep
red
near‐infrared
spectrum
but
also
displays
remarkable
90
nm
range
thermochromic
properties.
Ultimately,
it
was
successfully
applied
programmable,
thermally
controlled,
multi‐level
information
encryption.
ACS Applied Nano Materials,
Journal Year:
2024,
Volume and Issue:
7(20), P. 23485 - 23493
Published: Oct. 16, 2024
Although
aerogel
thermal
management
materials
for
daily
routine
environments
are
widely
investigated,
the
development
of
functionally
integrated
aerogels
sustainable
regulation
in
diverse
hot
and
cold
remains
a
formidable
challenge.
Meanwhile,
inherent
brittleness
porous
skeletons
limits
their
normal
operation.
Here,
we
demonstrate
an
asymmetric
structure
aramid
nanofiber
(ANF)/MXene-NH2
(ASAMA)
while
maintaining
high
tensile
strength.
By
integrating
different
conductivities
brought
by
structure,
solar-thermal
energy
conversion
ability
derived
from
MXene-NH2,
solar
reflectivity,
mid-infrared
emissivity
ANF,
ASAMA
successfully
achieves
both
environments.
In
simulate
environments,
can
keep
suitable
temperature
20
°C
frigid
environment
−5
via
synergistic
effect
conductivity.
Moreover,
it
provides
efficient
buffering
through
its
emissivity,
insulation,
which
reduce
to
28
40
°C.
The
resulting
exhibits
strength
(2.98
MPa),
superinsulation
−10
280
°C,
durable
combustion
protection
6
min.
design
these
asymmetrically
structured
holds
promise
widespread
application
low-energy
amid
changing
climates.
Advanced Materials,
Journal Year:
2024,
Volume and Issue:
unknown
Published: Dec. 17, 2024
Smart
wearable
devices
with
dynamically
reversible
color
displays
are
crucial
for
the
next
generation
of
smart
textiles,
and
promising
bio-robots,
adaptive
camouflage,
visual
health
monitoring.
The
rapid
advancement
technology
brings
out
different
categories
that
feature
fundamentally
color-reversing
mechanisms,
including
thermochromic,
mechanochromic,
electrochromic,
photochromic
wearables.
Although
some
reviews
have
showcased
relevant
developments
from
unique
perspectives,
focusing
on
advanced
design
flexible
chromic
within
each
category
not
been
reported.
In
this
review,
development
history
recent
progress
in
wearables
across
systematically
examined.
strategies
device
outlined
a
focus
functional
materials,
synthesis
processes,
applications.
Furthermore,
integrated
based
dual-stimuli
multi-stimuli
responsive
chromics
customizable
functionalities
summarized.
Finally,
challenges
perspectives
future
proposed.
Such
systematic
summary
will
serve
as
valuable
insight
researchers
field.
