
ACS Omega, Journal Year: 2024, Volume and Issue: unknown
Published: Sept. 8, 2024
TiO
Language: Английский
ACS Omega, Journal Year: 2024, Volume and Issue: unknown
Published: Sept. 8, 2024
TiO
Language: Английский
Coordination Chemistry Reviews, Journal Year: 2024, Volume and Issue: 514, P. 215900 - 215900
Published: May 8, 2024
Catalysis stands as a cornerstone in chemical synthesis, pivotal advancing sustainable manufacturing pathways. The evolution from energy-intensive to catalytic processes has marked transformative shift, notably exemplified by low-energy methods. These processes, operating under milder conditions and emphasizing selectivity recyclability, represent the forefront of chemistry. This review navigates through an array reactions, highlighting their diverse applications culminating exploration recent strides within processes. For example, explores uses such enzyme mimicking, biodiesel production, carbon dioxide capture, organic synthesis. Additionally, it covers enzymatic catalysis photocatalysis for transformations, energy applications, water treatment. Notably, emphasizes capabilities single-atom (SAC) diatomic catalysts (DACs), recognizing exceptional performance catalyzing reactions at minimal activation energies while maintaining high efficiency mild conditions. By elucidating modulation electronic structure offering microelectronic perspective, aims elucidate mechanisms underlying activity SAC DACs. Emphasizing interplay between coordination chemistry principles efficacy, elucidates indispensable role complexes fortifying sustainability these spotlighting fusion with catalysis, this underscore collective influence shaping landscape production.
Language: Английский
Citations
83Environmental Chemistry Letters, Journal Year: 2024, Volume and Issue: 22(4), P. 1607 - 1613
Published: March 19, 2024
Language: Английский
Citations
24Advanced Energy Materials, Journal Year: 2024, Volume and Issue: unknown
Published: Aug. 13, 2024
Abstract The rational design of a photocatalyst and its microenvironmental modulation is crucial in the heterogeneous photocatalysis process, yet relevant research on photocatalytic biodiesel synthesis not explored. Herein, based prediction density functional theory (DFT) calculations, highly efficient ternary biocompatible montmorillonite (Mt) nanocomposites S‐scheme heterojunction photocatalysts (g‐C 3 N 4 ‐TiO 2 @Mt, CTM) are successfully rationally designed. By modulating microenvironment production, CTM‐2 demonstrates exceptional catalytic performance stability, achieving record‐breaking yield 98.5%. Through ex/in situ X‐ray photoelectron spectroscopy (XPS), absorption near‐edge (XANES), theoretical formation revealed, which can generate an interface electric field (IEF) that provides intrinsic driving force for carrier migration enhances surface positivity. This boosts enrichment effect electronegative oleic acid (OA) carboxyl molecules, thus greatly enriching substrate concentration improving reaction microenvironment. Moreover, fourier transform infrared spectrometer (FT‐IR)/Raman together with electron paramagnetic resonance (EPR) further confirm key intermediates CH O• ester carbonyl (C═O), DFT calculations provide reference pathway, determined to be capable significantly reducing energy barrier rate‐determining step.
Language: Английский
Citations
23Fuel, Journal Year: 2024, Volume and Issue: 362, P. 130749 - 130749
Published: Jan. 3, 2024
Language: Английский
Citations
19ChemSusChem, Journal Year: 2024, Volume and Issue: unknown
Published: July 10, 2024
Abstract The rampant exploitation of fossil fuels has led to the significant energy scarcity and environmental disruption, affecting sound momentum development progress human civilization. To build a closed‐loop anthropogenic carbon cycle, biofuels employing sustainable biomass feedstocks stands at forefront advancing neutrality, yet its widespread adoption is mainly hampered by high production costs. Montmorillonite, however, garnered considerable attention serving as an efficient heterogeneous catalyst ideal economic feasibility for biofuel production, primarily due affordability, accessibility, stability, excellent plasticity. Up now, nevertheless, it merely received finite concerns interests in various using montmorillonite‐based catalysts. There no timely comprehensive review that addresses this latest relevant progress. This fills gap providing systematically summary controllable synthesis, performance enhancement, applications related different kinds including biodiesel, biohydrogenated diesel, levulinate, γ ‐valerolactone, 5‐ethoxymethylfurfural, gaseous (CO, H 2 ), cycloalkane, montmorillonite catalysts modified forms. Particularly, critically depicts design strategies montmorillonite, illustrates reaction mechanisms, assesses their viability, realizing via valorization. Overall, may offer valuable insights into cost‐effective proposes strategic recommendations advancement future development.
Language: Английский
Citations
15Journal of Cleaner Production, Journal Year: 2024, Volume and Issue: 436, P. 140638 - 140638
Published: Jan. 1, 2024
Language: Английский
Citations
9Chemical Physics Impact, Journal Year: 2025, Volume and Issue: unknown, P. 100816 - 100816
Published: Jan. 1, 2025
Language: Английский
Citations
1Separation and Purification Technology, Journal Year: 2025, Volume and Issue: unknown, P. 131922 - 131922
Published: Feb. 1, 2025
Language: Английский
Citations
1Energy & Fuels, Journal Year: 2024, Volume and Issue: 38(7), P. 6553 - 6559
Published: March 24, 2024
The modification of ionic liquids to improve the catalytic activity in oxidative desulfurization fuel is a research hotspot. Herein, kind phosphotungstic-acid-based imidazole liquid [C1imCH2CH2COOH]3PW12O40 ([C1im]3PW) was prepared and acted as photocatalyst extractive coupled photocatalytic oxidation (EPODS) system, which consisted [Omim]PF6, H2O2, formic acid. structure composition characteristics [C1im]3PW were studied, it exhibited excellent performance under visible light. dibenzothiophene achieved 99.8% 30 min room temperature atmospheric pressure. reusability, anti-interference ability, reaction process, possible mechanism EPODS system studied.
Language: Английский
Citations
8Energy Conversion and Management, Journal Year: 2024, Volume and Issue: 313, P. 118599 - 118599
Published: May 28, 2024
Language: Английский
Citations
6