Influence of Solid Alkaline Photocatalysts Irradiated with UV Light on Fuel Properties of Palm Oil Biodiesel DOI Creative Commons
Cherng‐Yuan Lin,

Shun-Lien Tseng

ACS Omega, Journal Year: 2024, Volume and Issue: unknown

Published: Sept. 8, 2024

TiO

Language: Английский

Coordination-driven innovations in low-energy catalytic processes: Advancing sustainability in chemical production DOI Creative Commons
Ahmed I. Osman, Ali Ayati, Pavel V. Krivoshapkin

et al.

Coordination Chemistry Reviews, Journal Year: 2024, Volume and Issue: 514, P. 215900 - 215900

Published: May 8, 2024

Catalysis stands as a cornerstone in chemical synthesis, pivotal advancing sustainable manufacturing pathways. The evolution from energy-intensive to catalytic processes has marked transformative shift, notably exemplified by low-energy methods. These processes, operating under milder conditions and emphasizing selectivity recyclability, represent the forefront of chemistry. This review navigates through an array reactions, highlighting their diverse applications culminating exploration recent strides within processes. For example, explores uses such enzyme mimicking, biodiesel production, carbon dioxide capture, organic synthesis. Additionally, it covers enzymatic catalysis photocatalysis for transformations, energy applications, water treatment. Notably, emphasizes capabilities single-atom (SAC) diatomic catalysts (DACs), recognizing exceptional performance catalyzing reactions at minimal activation energies while maintaining high efficiency mild conditions. By elucidating modulation electronic structure offering microelectronic perspective, aims elucidate mechanisms underlying activity SAC DACs. Emphasizing interplay between coordination chemistry principles efficacy, elucidates indispensable role complexes fortifying sustainability these spotlighting fusion with catalysis, this underscore collective influence shaping landscape production.

Language: Английский

Citations

83

Room-temperature and carbon-negative production of biodiesel via synergy of geminal-atom and photothermal catalysis DOI

Jinshu Huang,

Tengyu Liu, Keping Wang

et al.

Environmental Chemistry Letters, Journal Year: 2024, Volume and Issue: 22(4), P. 1607 - 1613

Published: March 19, 2024

Language: Английский

Citations

24

Boosting Photocatalytic Upcycling of Liquid Biomass into Biodiesel via Microenvironment Modulation DOI Creative Commons

Lijuan He,

Lilong Zhang, Heng Zhou

et al.

Advanced Energy Materials, Journal Year: 2024, Volume and Issue: unknown

Published: Aug. 13, 2024

Abstract The rational design of a photocatalyst and its microenvironmental modulation is crucial in the heterogeneous photocatalysis process, yet relevant research on photocatalytic biodiesel synthesis not explored. Herein, based prediction density functional theory (DFT) calculations, highly efficient ternary biocompatible montmorillonite (Mt) nanocomposites S‐scheme heterojunction photocatalysts (g‐C 3 N 4 ‐TiO 2 @Mt, CTM) are successfully rationally designed. By modulating microenvironment production, CTM‐2 demonstrates exceptional catalytic performance stability, achieving record‐breaking yield 98.5%. Through ex/in situ X‐ray photoelectron spectroscopy (XPS), absorption near‐edge (XANES), theoretical formation revealed, which can generate an interface electric field (IEF) that provides intrinsic driving force for carrier migration enhances surface positivity. This boosts enrichment effect electronegative oleic acid (OA) carboxyl molecules, thus greatly enriching substrate concentration improving reaction microenvironment. Moreover, fourier transform infrared spectrometer (FT‐IR)/Raman together with electron paramagnetic resonance (EPR) further confirm key intermediates CH O• ester carbonyl (C═O), DFT calculations provide reference pathway, determined to be capable significantly reducing energy barrier rate‐determining step.

Language: Английский

Citations

23

Advances in photocatalytic biodiesel production: Preparation methods, modifications and mechanisms DOI

Vishal Gadore,

Soumya Ranjan Mishra, Md. Ahmaruzzaman

et al.

Fuel, Journal Year: 2024, Volume and Issue: 362, P. 130749 - 130749

Published: Jan. 3, 2024

Language: Английский

Citations

19

Sustainable Production of Biofuels from Biomass Feedstocks Using Modified Montmorillonite Catalysts DOI

Lin Ban,

Deyu Wu,

Dalin Sun

et al.

ChemSusChem, Journal Year: 2024, Volume and Issue: unknown

Published: July 10, 2024

Abstract The rampant exploitation of fossil fuels has led to the significant energy scarcity and environmental disruption, affecting sound momentum development progress human civilization. To build a closed‐loop anthropogenic carbon cycle, biofuels employing sustainable biomass feedstocks stands at forefront advancing neutrality, yet its widespread adoption is mainly hampered by high production costs. Montmorillonite, however, garnered considerable attention serving as an efficient heterogeneous catalyst ideal economic feasibility for biofuel production, primarily due affordability, accessibility, stability, excellent plasticity. Up now, nevertheless, it merely received finite concerns interests in various using montmorillonite‐based catalysts. There no timely comprehensive review that addresses this latest relevant progress. This fills gap providing systematically summary controllable synthesis, performance enhancement, applications related different kinds including biodiesel, biohydrogenated diesel, levulinate, γ ‐valerolactone, 5‐ethoxymethylfurfural, gaseous (CO, H 2 ), cycloalkane, montmorillonite catalysts modified forms. Particularly, critically depicts design strategies montmorillonite, illustrates reaction mechanisms, assesses their viability, realizing via valorization. Overall, may offer valuable insights into cost‐effective proposes strategic recommendations advancement future development.

Language: Английский

Citations

15

An intelligent dual stimuli-responsive Pickering emulsion for highly efficiently producing waste frying oil-based biodiesel DOI
Jialiang Guo, Qingqing Sun, Zhong-Qiu Liu

et al.

Journal of Cleaner Production, Journal Year: 2024, Volume and Issue: 436, P. 140638 - 140638

Published: Jan. 1, 2024

Language: Английский

Citations

9

Manganese Metal Organic Frame Work Assisted Magnetic Ionic Liquid Single Crystal DOI Creative Commons
Nazmun Sharmin, Md. Jahidul Islam

Chemical Physics Impact, Journal Year: 2025, Volume and Issue: unknown, P. 100816 - 100816

Published: Jan. 1, 2025

Language: Английский

Citations

1

Application of S-type heterojunction CaTiO3/rGO-g-C3N4 photocatalyst in the conversion of waste cooking oil to biodiesel: Optimization via RSM and performance evaluation DOI
Guohui Zhang, Qingrong Zhang, Guanyi Chen

et al.

Separation and Purification Technology, Journal Year: 2025, Volume and Issue: unknown, P. 131922 - 131922

Published: Feb. 1, 2025

Language: Английский

Citations

1

Phosphotungstic-Acid-Based Ionic Liquid Catalyst for Efficient Photocatalytic Oxidative Desulfurization under Visible Light DOI
Desheng Liu, Suhang Xun,

Bohan Yang

et al.

Energy & Fuels, Journal Year: 2024, Volume and Issue: 38(7), P. 6553 - 6559

Published: March 24, 2024

The modification of ionic liquids to improve the catalytic activity in oxidative desulfurization fuel is a research hotspot. Herein, kind phosphotungstic-acid-based imidazole liquid [C1imCH2CH2COOH]3PW12O40 ([C1im]3PW) was prepared and acted as photocatalyst extractive coupled photocatalytic oxidation (EPODS) system, which consisted [Omim]PF6, H2O2, formic acid. structure composition characteristics [C1im]3PW were studied, it exhibited excellent performance under visible light. dibenzothiophene achieved 99.8% 30 min room temperature atmospheric pressure. reusability, anti-interference ability, reaction process, possible mechanism EPODS system studied.

Language: Английский

Citations

8

Novel ionic liquid-based nano-photocatalyst for microwave-ultrasound intensified biodiesel synthesis DOI

Aparna Gautam,

Nitesh S. Chawade,

Sushil Kumar

et al.

Energy Conversion and Management, Journal Year: 2024, Volume and Issue: 313, P. 118599 - 118599

Published: May 28, 2024

Language: Английский

Citations

6