Nano Letters,
Journal Year:
2025,
Volume and Issue:
unknown
Published: March 6, 2025
Achieving
precise
control
over
the
construction
of
efficient
charge
transport
channels
through
self-assembly
engineering
represents
a
highly
effective
strategy
for
synthesis
organic
supramolecular
photocatalysts.
Herein,
tetragonal
zinc
meso-5,10,15,20-tetra(4-pyridyl)
porphyrin
(ZnTPyP)
nanorods
(T-ZnTPyPs)
and
hexagonal
ZnTPyP
nanowires
(H-ZnTPyPs)
were
synthesized
by
varying
assembly
temperature.
H-ZnTPyPs
demonstrated
photocatalytic
hydrogen
production
rate
(183
mmol/g/h)
that
was
14.62
times
greater
than
T-ZnTPyP
(13
mmol/g/h).
This
significantly
enhanced
activity
is
primarily
attributed
to
distinct
well-defined
molecular
arrangements
H-ZnTPyPs,
which
support
continuous
linear
long-range
electron
transfer
pathways
π-π
stacking.
Conversely,
heat
manipulation
used
in
T-ZnTPyPs
limits
participation
water
molecules
crystalline
stacking
arrangements,
leading
lattice
distortions
disrupt
interactions
impede
pathways.
research
presents
novel
modulating
optimize
Angewandte Chemie International Edition,
Journal Year:
2024,
Volume and Issue:
63(18)
Published: Feb. 7, 2024
Sonodynamic
therapy
(SDT)
has
garnered
growing
interest
owing
to
its
high
tissue
penetration
depth
and
minimal
side
effects.
However,
the
lack
of
efficient
sonosensitizers
remains
primary
limiting
factor
for
clinical
application
this
treatment
method.
Here,
defect-repaired
graphene
phase
carbon
nitride
(g-C
Materials Horizons,
Journal Year:
2023,
Volume and Issue:
11(2), P. 408 - 418
Published: Sept. 21, 2023
Photocatalytic
technology
has
been
well
studied
as
a
means
to
achieve
sustainable
energy
generation
through
water
splitting
or
chemical
synthesis.
Recently,
low
C/N
atomic
ratio
carbon
nitride
allotrope,
C
