Materials Chemistry and Physics, Journal Year: 2025, Volume and Issue: 344, P. 131025 - 131025
Published: May 30, 2025
Language: Английский
Materials Chemistry and Physics, Journal Year: 2025, Volume and Issue: 344, P. 131025 - 131025
Published: May 30, 2025
Language: Английский
ACS Catalysis, Journal Year: 2024, Volume and Issue: 14(9), P. 7277 - 7288
Published: April 25, 2024
The application of selective catalytic reduction with ammonia (NH3-SCR) technology urgently requires catalysts good performance to control nitrogen oxide (NOx, x = 1, 2) emissions, and structural analysis such is necessary crucial elucidate the catalytically active sites. Thus, we prepared molybdenum (Mo)-doped CeO2 achieve a substantial leap in performance. results revealed that emergence Ce3+–O–Ce3+ units induced by Mo doping achieved low-energy barrier activation NH3 molecule, which transformed dominant reaction mechanism thus led much better SCR Furthermore, designed tungsten (W)-doped same amount as found exhibited almost activity trend Mo-doped catalysts, further confirmed pivotal role units. This study provides basic theoretical foundation for design ceria-based efficient NOx removal.
Language: Английский
Citations
23Environmental Science & Technology, Journal Year: 2024, Volume and Issue: 58(17), P. 7672 - 7682
Published: April 19, 2024
The development of efficient technologies for the synergistic catalytic elimination NOx and chlorinated volatile organic compounds (CVOCs) remains challenging. Chlorine species from CVOCs are prone to catalyst poisoning, which increases degradation temperature fails balance selective reduction with NH3 (NH3–SCR) performance. Herein, chlorobenzene has been originally demonstrated by using phosphotungstic acid (HPW) as a dechlorination agent collaborate CeO2. conversion was over 80% at 270 °C, N2 selectivity reached 95% 270–420 °C. HPW not only allowed chlorine leave inorganic but also enhanced Bro̷nsted acidity NH4+ produced in NH3–SCR process can effectively promote low temperatures. remained structurally stable reaction, resulting good water resistance long-term stability. This work provides cheaper more environmentally friendly strategy address poisoning reaction offers new guidance multipollutant control.
Language: Английский
Citations
20International Journal of Biological Macromolecules, Journal Year: 2023, Volume and Issue: 256, P. 128458 - 128458
Published: Nov. 26, 2023
Language: Английский
Citations
27Journal of Catalysis, Journal Year: 2023, Volume and Issue: 429, P. 115260 - 115260
Published: Dec. 16, 2023
Language: Английский
Citations
27Electrochimica Acta, Journal Year: 2024, Volume and Issue: 499, P. 144685 - 144685
Published: Sept. 1, 2024
Language: Английский
Citations
13Applied Catalysis B Environment and Energy, Journal Year: 2025, Volume and Issue: unknown, P. 125065 - 125065
Published: Jan. 1, 2025
Language: Английский
Citations
2Fuel, Journal Year: 2025, Volume and Issue: 394, P. 135137 - 135137
Published: March 20, 2025
Language: Английский
Citations
1Journal of Alloys and Compounds, Journal Year: 2025, Volume and Issue: unknown, P. 180752 - 180752
Published: May 1, 2025
Language: Английский
Citations
1Ceramics International, Journal Year: 2023, Volume and Issue: 50(3), P. 4307 - 4314
Published: Nov. 4, 2023
Language: Английский
Citations
17Separation and Purification Technology, Journal Year: 2024, Volume and Issue: 348, P. 127770 - 127770
Published: May 2, 2024
Language: Английский
Citations
6