Inorganic Chemistry,
Journal Year:
2024,
Volume and Issue:
63(27), P. 12564 - 12571
Published: June 26, 2024
The
design
and
intentional
construction
of
crystalline
materials
containing
two
clusters
with
redox
properties
in
one
framework
still
remains
challenging.
Linking
oxidative
polyoxometalate
(POM)
a
reductive
cyclic
trinuclear
copper
complex
(Cu-CTC)
to
prepare
stable
catalysts
is
rarely
reported.
Herein,
we
successfully
obtained
new
polyoxometalate-based
metal-organic
compounds
(POMOCs)
[Cu
Chemical Reviews,
Journal Year:
2025,
Volume and Issue:
unknown
Published: Feb. 18, 2025
The
electrocatalytic
technique,
as
an
efficient
energy
storage
and
conversion
technology,
has
attracted
significant
attention
to
address
exhaustion
environmental
pollution.
Usually,
the
activity
selectivity
of
reactions
are
largely
dominated
by
dynamic
process
occurring
on
electrocatalysts.
Therefore,
high-performance
electrocatalysts,
which
can
dominate
pathway
barrier
reactions,
great
significance
for
advancement
technique.
Metal-organic
frameworks
(MOFs),
emerging
crystalline
porous
materials,
present
structural
component
advantages
including
well-defined
structure,
high
surface
area,
large
porosity,
diverse
components,
easy
tailorability,
demonstrating
fantastic
potential
precise
fabrication
In
this
Review,
strategies
in
electrocatalysts
based
MOF-related
materials
specifically
introduced
from
aspects
catalytic
site
design
microenvironment
modulation
around
sites.
Furthermore,
representative
progress
achieved
various
applications
employing
MOF-based
is
systematically
summarized,
with
special
emphasis
MOFs
performance
optimization.
Finally,
remaining
challenges
future
perspectives
further
highlighted.
Chemical Society Reviews,
Journal Year:
2024,
Volume and Issue:
unknown
Published: Dec. 11, 2024
The
core
of
clean
energy
technologies
such
as
fuel
cells,
water
electrolyzers,
and
metal-air
batteries
depends
on
a
series
oxygen
hydrogen-based
electrocatalysis
reactions,
including
the
reduction
reaction
(ORR),
evolution
(OER)
hydrogen
(HER),
which
necessitate
cost-effective
electrocatalysts
to
improve
their
efficiency.
In
recent
decade,
complex
metal
oxides
(beyond
simple
transition
oxides,
spinel
ABO
Solar RRL,
Journal Year:
2024,
Volume and Issue:
8(12)
Published: April 29, 2024
Graphdiyne
(GDY)
has
been
widely
applied
in
the
field
of
photocatalytic
hydrogen
production
due
to
its
unique
chemical
structure
and
excellent
photoelectric
performance.
Herein,
CuBr
is
used
as
a
catalytic
substrate
prepare
CuBr/GDY
through
cross‐coupling
reaction,
novel
NENU‐5/CuBr/GDY
tandem
S‐scheme
heterojunction
photocatalyst
constructed
at
low
temperature.
The
exhibits
significantly
enhanced
activity
evolution,
with
evolution
reaching
226.62
μmol
5
h,
which
4.7
12.6
times
greater
than
that
pure
GDY
NENU‐5,
respectively.
Comprehensive
evaluation
electrochemical,
photoluminescence,
time‐resolved
photoluminescence
indicates
composite
catalyst
attributed
high
photocurrent
response
electrical
resistance,
increases
efficiency
photogenerated
charge
separation.
Additionally,
density
functional
theory
calculations
ultraviolet
photoelectron
spectroscopy
propose
possibility
constructing
structure.
In
summary,
this
work
provides
valuable
ideas
into
heterojunctions
for
production.
