Highly Efficient Bifunctional NiFe-MOF Array Electrode for Nitrate Reduction to Ammonia and Oxygen Evolution Reactions DOI

Yuanhui Yao,

Kai Wei, Shuang Zhao

et al.

ACS Sustainable Chemistry & Engineering, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 16, 2025

Electrocatalytically converting nitrates in sewage to ammonia, which can not only achieve the purpose of eliminating but also obtaining valuable is an effective supplement traditional Haber–Bosch process. Although significant progress has been made cathodic catalyst design, overall ammonia electrolysis from nitrate reduction still restricted by anodic oxygen evolution heavily relying on noble-based catalysts. Herein, a bimetallic NiFe-MOF nanosheet array electrode fabricated and serves as efficient bifunctional for reactions. The introduction Fe Ni-MOF facilitates formation structure with higher electrochemical active surface area, well provides synergetic NiFe sites. reaches greatly enhanced yield rate 0.94 mmol cm–2 h–1 Faradaic efficiency 90.8% at cathode −0.6 V versus reversible hydrogen electrode, reaction declined overpotential 424 mV 50 mA cm–2. As electrocatalysis, performance comparable that using Pt mesh counter electrode.

Language: Английский

Antibacterial gas therapy: Strategies, advances, and prospects DOI Creative Commons
Tianyu Wang, X. L. Zhu, Fu‐Gen Wu

et al.

Bioactive Materials, Journal Year: 2022, Volume and Issue: 23, P. 129 - 155

Published: Nov. 11, 2022

One of the challenges posed by current antibacterial therapy is that expanded and massive use antibiotics endows bacteria with ability to resist almost all kinds antibiotics. Therefore, developing alternative strategies for efficient treatment urgently needed. Antibacterial gas has attracted much attention in past decade. Nitric oxide (NO), carbon monoxide (CO), sulfur dioxide (SO2), hydrogen sulfide (H2S), (H2) are not only known as endogenous signaling molecules, but also play critical roles many pathological processes. These gases considered attractive bactericidal agents because they able kill bacteria, disperse biofilms, promote bacteria-infected wound healing while avoiding resistance. In this review, we discuss properties these gases, well recent advances gas-involving systems antibacterial, antibiofilm, applications. Moreover, summarize various donors utilized treatment. We hope review will shed new light on future design applications advanced therapy.

Language: Английский

Citations

84

Tailoring the Surface and Composition of Nanozymes for Enhanced Bacterial Binding and Antibacterial Activity DOI

Jinjie Hou,

Yunlei Xianyu

Small, Journal Year: 2023, Volume and Issue: 19(42)

Published: June 15, 2023

With the advantages of diverse structures, tunable enzymatic activity, and high stability, nanozymes are widely used in medicine, chemistry, food, environment, other fields. As an alternative to traditional antibiotics, attract more attention from scientific researchers recent years. Developing nanozymes-based antibacterial materials opens up a new avenue for bacterial disinfection sterilization. In this review, classification their mechanisms discussed. The surface composition critical efficacy, which can be tailored enhance both binding activity. On one hand, modification enables targeting bacteria that improves performance including biochemical recognition, charge, topography. modulated achieve enhanced single nanozyme-mediated synergistic multiple nanozymes-mediated cascade catalytic applications. addition, current challenges future prospects tailoring applications This review provide insights into design treatments.

Language: Английский

Citations

69

Covalent organic frameworks in supercapacitors: Unraveling the pros and cons for energy storage DOI
H.H. Hegazy, Siva Sankar Sana, Tholkappiyan Ramachandran

et al.

Journal of Energy Storage, Journal Year: 2023, Volume and Issue: 74, P. 109405 - 109405

Published: Oct. 27, 2023

Language: Английский

Citations

45

Recent Developments in the Design and Fabrication of Electrochemical Biosensors Using Functional Materials and Molecules DOI Creative Commons

K. Theyagarajan,

Young‐Joon Kim

Biosensors, Journal Year: 2023, Volume and Issue: 13(4), P. 424 - 424

Published: March 27, 2023

Electrochemical biosensors are superior technologies that used to detect or sense biologically and environmentally significant analytes in a laboratory environment, even the form of portable handheld wearable electronics. Recently, imprinted implantable emerging as point-of-care devices, which monitor target continuous environment alert intended users anomalies. The stability performance developed biosensor depend on nature properties electrode material platform is constructed. Therefore, plays an integral role effectiveness biosensor. Enormous effort has been dedicated rational design fabrication strategies for improving biosensors. Every year, search multifarious materials, thousands new platforms reported. Moreover, order construct effectual biosensor, researcher should familiarize themself with sensible behind fabrication. Thus, we intend shed light various methodologies utilized electrochemical facilitate sensitive selective detection analytes. Furthermore, this review highlights advantages materials correlation between immobilized biomolecules modified surfaces.

Language: Английский

Citations

43

Antibiotics-free nanomaterials against bacterial keratitis: Eliminating infections with reactive oxygen species (ROS) DOI
Liangyu Zhou, Yi Deng, Yujie Ren

et al.

Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 482, P. 148978 - 148978

Published: Jan. 22, 2024

Language: Английский

Citations

22

A Novel L-Cys@Cu MOF Embedding onto Cotton Fiber Surfaces to Exert Excellent Antiviral and Antibacterial Effects DOI

Yuanxiang Xiao,

Jingjing Jiang, Rui Cai

et al.

Advanced Fiber Materials, Journal Year: 2024, Volume and Issue: 6(2), P. 444 - 457

Published: Feb. 6, 2024

Language: Английский

Citations

21

Enhanced antibacterial activity of a novel silver-based metal organic framework towards multidrug-resistant Klebsiella pneumonia DOI Creative Commons
Payam B. Hassan, Sameera Sh. Mohammed Ameen,

Lana Mohammed

et al.

Nanoscale Advances, Journal Year: 2024, Volume and Issue: 6(15), P. 3801 - 3808

Published: Jan. 1, 2024

The growth and spread of multidrug-resistant bacterial species, such as

Language: Английский

Citations

21

Recent Progress and Prospect of Metal–Organic Framework-Based Nanozymes in Biomedical Application DOI Creative Commons
Anupriya Baranwal, Shakil Ahmed Polash, Vijay Kumar Aralappanavar

et al.

Nanomaterials, Journal Year: 2024, Volume and Issue: 14(3), P. 244 - 244

Published: Jan. 23, 2024

A nanozyme is a nanoscale material having enzyme-like properties. It exhibits several superior properties, including low preparation cost, robust catalytic activity, and long-term storage at ambient temperatures. Moreover, high stability enables repetitive use in multiple reactions. Hence, it considered potential replacement for natural enzymes. Enormous research interest nanozymes the past two decades has made imperative to look better enzyme-mimicking materials biomedical applications. Given this, on metal–organic frameworks (MOFs) as gained momentum. MOFs are advanced hybrid of inorganic metal ions organic ligands. Their distinct composition, adaptable pore size, structural diversity, ease tunability physicochemical properties enable mimic activities act promising candidates. This review aims discuss recent advances development MOF-based (MOF-NZs) highlight their applications field biomedicine. Firstly, different enzyme-mimetic exhibited by discussed, insights given into various strategies achieve them. Modification functionalization deliberated obtain MOF-NZs with enhanced activity. Subsequently, biosensing therapeutics domain discussed. Finally, concluded giving challenges encountered possible directions overcome them future. With this review, we aim encourage consolidated efforts across enzyme engineering, nanotechnology, science, biomedicine disciplines inspire exciting innovations emerging yet field.

Language: Английский

Citations

18

Research progress on antibacterial applications of metal-organic frameworks and their biomacromolecule composites DOI

Lei Guo,

Wei Kong,

Yilin Che

et al.

International Journal of Biological Macromolecules, Journal Year: 2024, Volume and Issue: 261, P. 129799 - 129799

Published: Feb. 1, 2024

Language: Английский

Citations

18

2D MOFs nanosheets derived from 2D LDHs as a multifunctional sensitizer for sono-photodynamic therapy-mediated tumor treatment DOI
Tingting Hu, Tao Wang, Yu-Sheng Yang

et al.

Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: unknown, P. 159771 - 159771

Published: Jan. 1, 2025

Language: Английский

Citations

2