Nanoscale,
Journal Year:
2023,
Volume and Issue:
15(24), P. 10189 - 10205
Published: Jan. 1, 2023
Water-stable
metal–organic
frameworks
(MOFs):
adsorbents
to
remove
heavy
metal
ions
with
excellent
stability.
MOFs
from
different
functionalization
strategies
enhance
the
removal
performance
of
MOF
adsorbents.
Materials Advances,
Journal Year:
2024,
Volume and Issue:
5(14), P. 5870 - 5884
Published: Jan. 1, 2024
The
synthesis
of
a
zinc-based
organic
framework
utilized
rapid,
cost-effective,
and
environmentally
friendly
sonochemical
method,
for
the
electrochemical
detection
paracetamol.
Small,
Journal Year:
2024,
Volume and Issue:
20(47)
Published: Aug. 16, 2024
Abstract
Metal‐organic
frameworks
(MOFs)
are
a
new
variety
of
solid
crystalline
porous
functional
materials.
As
an
extension
inorganic
materials,
it
has
made
important
progress
in
preparation
and
application.
MOFs
widely
used
various
fields
such
as
gas
adsorption
storage,
drug
delivery,
sensing,
biological
imaging
due
to
their
high
specific
surface
area,
porosity,
adjustable
pore
size,
abundant
active
sites,
modification
by
introducing
groups.
In
this
paper,
the
types
classified,
synthesis
methods
mechanisms
materials
summarized.
Finally,
application
prospects
challenges
metal‐organic
framework
biomedical
field
discussed,
hoping
promote
multidisciplinary
fields.
The Innovation,
Journal Year:
2025,
Volume and Issue:
6(2), P. 100778 - 100778
Published: Jan. 18, 2025
Traditional
fossil
fuels
significantly
contribute
to
energy
supply,
economic
development,
and
advancements
in
science
technology.
However,
prolonged
extensive
use
of
has
resulted
increasingly
severe
environmental
pollution.
Consequently,
it
is
imperative
develop
new,
clean,
pollution-free
sources
with
high
density
versatility
as
substitutes
for
conventional
fuels,
although
this
remains
a
considerable
challenge.
Simultaneously,
addressing
water
pollution
critical
concern.
The
design,
optimization
functional
nanomaterials
are
pivotal
advancing
new
solutions
pollutant
remediation.
Emerging
porous
framework
materials
such
metal-organic
frameworks
(MOFs)
covalent
organic
(COFs),
recognized
exemplary
crystalline
materials,
exhibit
potential
applications
due
their
specific
surface
area,
adjustable
pore
sizes
structures,
permanent
porosity,
customizable
functionalities.
This
work
provides
comprehensive
systematic
review
the
MOFs,
COFs,
derivatives
emerging
technologies,
including
oxygen
reduction
reaction,
evolution
hydrogen
lithium-ion
batteries,
remediation
carbon
dioxide
reaction
management.
In
addition,
strategies
performance
adjustment
structure-effect
relationships
these
explored.
Interaction
mechanisms
summarized
based
on
experimental
discussions,
theoretical
calculations,
advanced
spectroscopy
analyses.
challenges,
future
prospects,
opportunities
tailoring
presented.
Molecules,
Journal Year:
2025,
Volume and Issue:
30(2), P. 251 - 251
Published: Jan. 10, 2025
Climate
change
and
the
energy
crisis,
driven
by
excessive
CO2
emissions,
have
emerged
as
pressing
global
challenges.
The
conversion
of
into
high-value
chemicals
not
only
mitigates
atmospheric
levels
but
also
optimizes
carbon
resource
utilization.
Enzyme-catalyzed
technology
offers
a
green
efficient
approach
to
conversion.
However,
free
enzymes
are
prone
inactivation
denaturation
under
reaction
conditions,
which
limit
their
practical
applications.
Metal-organic
frameworks
(MOFs)
serve
effective
carriers
for
enzyme
immobilization,
offering
porous
crystalline
structures
that
enhance
stability.
Moreover,
high
specific
surface
area
facilitates
strong
gas
adsorption,
making
enzyme@MOF
composites
particularly
advantageous
catalytic
In
this
paper,
we
review
synthesis
technologies
application
enzyme@MOFs
in
Furthermore,
strategies,
including
enhancement
utilization,
coenzyme
regeneration
efficiency,
substrate
mass
transfer
discussed
further
improve
efficiency
aim
is
present
innovative
ideas
future
research
highlight
potential
applications
achieving
Scientific Reports,
Journal Year:
2023,
Volume and Issue:
13(1)
Published: Nov. 14, 2023
The
excessive
release
of
greenhouse
gases,
especially
carbon
dioxide
(CO2)
pollution,
has
resulted
in
significant
environmental
problems
all
over
the
world.
CO2
capture
technologies
offer
a
very
effective
means
combating
global
warming,
climate
change,
and
promoting
sustainable
economic
growth.
In
this
work,
UiO-66-NH2
was
synthesized
by
novel
sonochemical
method
only
one
hour.
This
material
characterized
through
PXRD,
FT-IR,
FE-SEM,
EDX,
BET,
TGA
methods.
potential
presented
investigated
analysis
gas
isotherms
under
varying
pressure
conditions,
encompassing
both
low
high-pressure
regions.
Remarkably,
adsorbent
manifested
notable
augmentation
adsorption
capacity
(3.2
mmol/g),
achieving
an
approximate
enhancement
0.9
mmol/g,
when
compared
to
conventional
solvothermal
techniques
(2.3
mmol/g)
at
25
°C
1
bar.
To
accurately
represent
experimental
findings,
three
isotherm,
kinetic
models
were
used
fit
data
which
Langmuir
model
Elovich
exhibited
best
with
R2
values
0.999
0.981,
respectively.
Isosteric
heat
evaluation
showed
higher
than
80
kJ/mol
indicates
chemisorption
between
surface
adsorbate.
Furthermore,
selectivity
examined
using
Ideal
Adsorbed
Solution
Theory
(IAST),
high
value
202
towards
simulated
flue
conditions.
evaluate
durability
performance
consecutive
adsorption-desorption
processes,
cyclic
tests
conducted.
Interestingly,
these
demonstrated
0.6
mmol/g
decrease
for
throughout
8
cycles.