Environmental science and engineering, Journal Year: 2024, Volume and Issue: unknown, P. 63 - 86
Published: Dec. 31, 2024
Language: Английский
Environmental science and engineering, Journal Year: 2024, Volume and Issue: unknown, P. 63 - 86
Published: Dec. 31, 2024
Language: Английский
The Science of The Total Environment, Journal Year: 2025, Volume and Issue: 959, P. 178331 - 178331
Published: Jan. 1, 2025
Language: Английский
Citations
1Environmental Research, Journal Year: 2025, Volume and Issue: unknown, P. 121181 - 121181
Published: Feb. 1, 2025
Language: Английский
Citations
1Chemical Engineering Journal, Journal Year: 2025, Volume and Issue: unknown, P. 159710 - 159710
Published: Jan. 1, 2025
Language: Английский
Citations
0Microchemical Journal, Journal Year: 2025, Volume and Issue: unknown, P. 113789 - 113789
Published: April 1, 2025
Language: Английский
Citations
0Journal of Water Process Engineering, Journal Year: 2025, Volume and Issue: 74, P. 107793 - 107793
Published: April 27, 2025
Language: Английский
Citations
0Journal of Environmental Management, Journal Year: 2024, Volume and Issue: 370, P. 122929 - 122929
Published: Oct. 19, 2024
Pure Magnéli-phase Ti
Citations
1Journal of environmental chemical engineering, Journal Year: 2024, Volume and Issue: unknown, P. 114863 - 114863
Published: Nov. 1, 2024
Language: Английский
Citations
1Ecotoxicology and Environmental Safety, Journal Year: 2024, Volume and Issue: 289, P. 117436 - 117436
Published: Dec. 4, 2024
Language: Английский
Citations
1Analytical and Bioanalytical Chemistry, Journal Year: 2024, Volume and Issue: unknown
Published: Sept. 13, 2024
Abstract Fluorinated organic compounds (FOCs) represent a class of synthetic chemicals distinguished by their resilient carbon–fluorine bonds, which demonstrate an ability to withstand environmental degradation over extended period. The integration FOCs into cutting-edge applications, including lithium-ion batteries (LiBs), presents considerable potential for harm that has not yet been sufficiently addressed. This study focuses on the fate two fluorinated aromatics, tris(pentafluorophenyl)borane (TPFP B ) and tris(pentafluorophenyl)phosphine P ), given important role in improving performance LiBs. To achieve this, laboratory simulation methods total oxidizable precursor assay, electrochemistry (EC), Fenton reaction, UV-C irradiation, hydrolysis were employed. Liquid chromatography gas coupled with high-resolution mass spectrometry used identification transformation products (TPs) prediction molecular formulae. Despite structural similarity between TPFP , distinct differences electrochemical behavior pathways observed. readily underwent hydroxylation hydrolysis, resulting wide range 49 TPs. A 28 TPs newly identified, oligomers highly toxic dioxins. In contrast, degraded exclusively under harsh conditions, requiring development innovative conditioning protocols EC. total, experiments yielded nine structurally different compounds, seven previously undescribed, partially defluorinated highlights risks associated use LiBs provides insight complex FOCs. Graphical
Language: Английский
Citations
0Ömer Halisdemir Üniversitesi Mühendislik Bilimleri Dergisi, Journal Year: 2024, Volume and Issue: unknown
Published: Oct. 19, 2024
Per- ve polifloroalkil maddeler (PFAS) yaygın kullanılan, yüksek kararlılıkları nedeniyle çevrede kalıcı halde biriken sentetik kimyasallardır. Florlanmış hidrofobik bir kuyruk hidrofilik fonksiyonel grup içeren kısa uzun zincirli bileşikleri sayesinde yapısal olarak çok çeşitli olan bu maddeler, yağ su itici özellikleri birçok endüstriyel tüketici ürününde yer almakta; ancak biyobirikim toksisite riskleri taşımaktadır. Küresel ölçekte 4700’den fazla türü üretilmiş PFAS'ların türleri zincirlilere göre daha kalıcıdır, iki grubunda oluşturabileceği toksik riskler benzer olabilmektedir. 1940’lardaki ilk üretiminden yana çevresel ortamlarda (hava-su-toprak-biyota) birikmeye başlayan, bitkilerde hayvanlarda biyokümüle olabilen PFAS’ların, insan sağlığı üzerinde kanser, hormonal bozukluklar bağışıklık sistemi olumsuz etkiler sergilediği anlaşılmıştır. Bu nedenle kontrolü izleme stratejilerinin geliştirilmesi önem kazanmıştır. çalışma, çevredeki kalıcılığını, hareketliliğini, taşınım birikimini ele alarak üzerindeki potansiyel doğrultuda alınması gereken kontrol önlemlerinin önemini vurgulamaktadır.
Citations
0