Magnetic Persimmon Leaf Composite: Preparation and Application in Magnetic Solid-Phase Extraction of Pesticides in Water Samples DOI Creative Commons

Yuyue Zang,

Na Hang,

Jiale Sui

et al.

Molecules, Journal Year: 2023, Volume and Issue: 29(1), P. 45 - 45

Published: Dec. 20, 2023

In recent years, the utilization of biomass materials for removal and detection water pollutants has garnered considerable attention. This study introduces, first time, preparation Fe3O4/persimmon leaf magnetic composites. The composites were employed in a solid-phase extraction method, coupled with gas chromatography-electron capture (GC-ECD), analysis four pesticides (trifluralin, triadimefon, permethrin, fenvalerate) environmental samples. innovative persimmon synthesized by situ generation Fe3O4 nanoparticles through coprecipitation loaded onto leaves. These exhibit superparamagnetism saturation magnetization 12.8 emu g−1, facilitating rapid phase separation using field reducing time to 10 min. Desorption can be achieved within 30 s aspirating 20 times, eliminating need time-consuming labor-intensive experimental steps like filtration centrifugation. specific surface area composite adsorbent increased from 1.3279 m2 g−1 original 5.4688 g−1. abundant hydroxyl carboxyl groups on provide ample adsorption sites, resulting capacities ranging 55.056 mg 73.095 studied pesticides. exhibited recoveries 80% 90% Compared certain previously reported MSPE methods, this approach achieves equivalent or higher shorter operation demonstrating enhanced efficiency convenience. Good linearity target analytes was obtained range 0.75–1500 μg L−1, determination coefficient (R2) greater than 0.999. findings contribute use as effective environmentally friendly adsorbents pollutant

Language: Английский

The Impact of Permethrin and Cypermethrin on Plants, Soil Enzyme Activity, and Microbial Communities DOI Open Access
Agata Borowik, Jadwiga Wyszkowska, Magdalena Zaborowska

et al.

International Journal of Molecular Sciences, Journal Year: 2023, Volume and Issue: 24(3), P. 2892 - 2892

Published: Feb. 2, 2023

Pyrethroids are insecticides most commonly used for insect control to boost agricultural production. The aim of the present research was determine effect permethrin and cypermethrin on cultured non-cultivated bacteria fungi activity soil enzymes, as well usefulness Zea mays in mitigating adverse effects tested pyrethroids microbiome. analyses were carried out samples both not sown with any plant mays. Permethrin found stimulate multiplication organotrophic (on average by 38.3%) actinomycetes 80.2%), inhibit growth 31.7%) enzymatic soil, reducing biochemical fertility index (BA) 27.7%. They also modified number operational taxonomic units (OTUs) Actinobacteria Proteobacteria phyla Ascomycota Basidiomycota phyla. pressure tolerated Sphingomonas (clone 3214512, 1052559, 237613, 1048605) Bacillus New.ReferenceOTU111, 593219, 578257), Penicillium (SH1533734.08FU, SH1692798.08FU) Trichocladium (SH1615601.08FU). Both disturbed yielding mays, a result which its yield leaf greenness decreased. cultivation had positive enzymes microorganisms mitigated anomalies caused microbiome enzymes. decreased aerial parts 37.9% roots 33.9%, whereas respective decreases reached 16.8% 4.3%.

Language: Английский

Citations

24
Widespread phthalate esters and monoesters in the aquatic environment: Distribution, bioconcentration, and ecological risks DOI
Jiayao Li,

Jia-Liang Guo,

Jing-Feng Yi

et al.

Journal of Hazardous Materials, Journal Year: 2024, Volume and Issue: 477, P. 135201 - 135201

Published: July 14, 2024

Language: Английский

Citations

12
Occurrence, distribution, and health risk assessment of pyrethroid and neonicotinoid insecticides in aquatic products of China DOI

Manni Wu,

Jingjing Miao, Wenhao Zhang

et al.

The Science of The Total Environment, Journal Year: 2024, Volume and Issue: 919, P. 170880 - 170880

Published: Feb. 15, 2024

Language: Английский

Citations

9
Chronic exposure to deltamethrin disrupts intestinal health and intestinal microbiota in juvenile crucian carp DOI Creative Commons
Hao Wu, Jinwei Gao, Min Xie

et al.

Ecotoxicology and Environmental Safety, Journal Year: 2022, Volume and Issue: 241, P. 113732 - 113732

Published: June 6, 2022

The indiscriminate use of deltamethrin in agriculture and aquaculture can lead to residues increased many regions, which poses negative impacts on intestinal health aquatic organisms. Although the potential toxicity have recently attracted attention, comprehensive studies injuries after chronic exposure remain poorly understood. Herein, a 28-day test, crucian carp expose different concentrations (0, 0.3, 0.6 μg/L) were used as research object. We found that morphology changes goblet cells tissue, extent tissue injury along with increasing dose deltamethrin. Additionally, genes expression antioxidant activity (Cu/Zn superoxide dismutase (Cu-Zn SOD), glutathione peroxidase 1 (GPX1), catalase (CAT)), inflammatory response (tumor necrosis factor alpha (TNFα), interferon gamma (IFNγ), interleukin beta (IL-1β)), tight junctions (Claudin 12 (CLDN12), junction protein (ZO-1)) dramatically increased. Meanwhile, apoptosis autophagy process triggered through caspase-9 cascade related 5 (ATG5)- (ATG12) conjugate. Besides, amount Proteobacteria Verrucomicrobiota, while decreased Fusobacteriota abundance, resulting microbiota function disorders. In summary, our results highlight cause serious physiological flora disturbances.

Language: Английский

Citations

30
Effects of point and nonpoint source pollution on urban rivers: From the perspective of pollutant composition and toxicity DOI
Yuxuan Liu, Bei Su,

Hongxin Mu

et al.

Journal of Hazardous Materials, Journal Year: 2023, Volume and Issue: 460, P. 132441 - 132441

Published: Aug. 29, 2023

Language: Английский

Citations

17
Target and suspect screening approaches for the identification of emerging and other contaminants in fish feeds using high resolution mass spectrometry DOI
Vasiliki Boti,

Panagiota Martinaiou,

Dimitrios Gkountouras

et al.

Environmental Research, Journal Year: 2024, Volume and Issue: 251, P. 118739 - 118739

Published: March 19, 2024

Language: Английский

Citations

8
Obesity modifies the association of environmental pyrethroid exposure with glucose homeostasis in the US general adults DOI

Ruyi Liang,

Xiaobing Feng, Da Shi

et al.

Environmental Pollution, Journal Year: 2023, Volume and Issue: 328, P. 121671 - 121671

Published: April 18, 2023

Language: Английский

Citations

13
Bifenthrin disrupts cytochrome c oxidase activity and reduces mitochondrial DNA copy number through oxidative damage in pool barb (Puntius sophore) DOI
Anwesha Das, Sarbashri Bank, Srilagna Chatterjee

et al.

Chemosphere, Journal Year: 2023, Volume and Issue: 332, P. 138848 - 138848

Published: May 6, 2023

Language: Английский

Citations

12
Simultaneous Determination of Seven Pyrethroid Pesticide Residues in Aquatic Products by Gas Chromatography DOI Creative Commons

Changling Fang,

Xiaoyi Lou,

Xuan Zhang

et al.

Fishes, Journal Year: 2024, Volume and Issue: 9(3), P. 79 - 79

Published: Feb. 20, 2024

Aquatic products are good sources of essential nutrients, but the presence pyrethroids (PYRs) as contaminants may pose risks to consumer health intricate matrices PYRs usually obstruct chemical hazard detection. In this study, a gas chromatographic method was established and validated for simultaneously detecting residues seven (cyhalothrin, permethrin, cyfluthrin, cypermethrin, tau-fluvalinate, fenvalerate, deltamethrin) in aquatic products. The aim assess better potential pesticide were extracted with acetonitrile, purified n-hexane saturated cleaned up on Cleanert® Alumina N column. Statistical analysis orthogonal array experimental design used optimize key parameters. To validate proposed method, commonly consumed (such carp, crucian whiteleg shrimp, river crab, sea cucumber, scallop) obtained from local supermarkets Shanghai. Satisfied linearity calibration curves achieved matrix-matched standard solution, correlation coefficient (R2) larger than 0.995. average recoveries at five fortification levels varied 77.0% 117.2%, relative deviations (RSDs) below 11.1%. Concerning electron capture detection, limits detection (LOD) quantification (LOQ) 2.0–5.0 µg/kg 5.0–10.0 µg/kg, respectively. These results demonstrate high stability sensitivity products, having great practicability which can be popularized easily.

Language: Английский

Citations

4
Pesticide exposure among Czech adults and children from the CELSPAC-SPECIMEn cohort: Urinary biomarker levels and associated health risks DOI Creative Commons
Libor Šulc, Tomáš Janoš, Daniel Figueiredo

et al.

Environmental Research, Journal Year: 2022, Volume and Issue: 214, P. 114002 - 114002

Published: Aug. 5, 2022

Current-use pesticides (CUP) are extensively applied in both agricultural and urban settings. Exposure occurs mainly via the dietary pathway; however, other pathways such as inhalation or skin contact also important. In this study, urinary levels of 12 CUP metabolites were investigated among 110 parent-child pairs during two seasons 2020. Metabolites pyrethroids (3-PBA, t/c-DCCA), chlorpyrifos (TCPY), tebuconazole (TEB-OH) detected more than 60% samples. Chlorpyrifos metabolite was found at highest concentration almost all significantly higher children comparison to adults, except for tebuconazole, which similar groups. children, winter samples had concentrations pyrethroid summer samples, but only winter. No association between proximity/surface areas around residences observed. Based on our findings, we suspect that exposure is driven by diet effect environmental less significant. Daily Intakes estimated with three possible scenarios considering amount excreted urine compared Acceptable Intake values. Using a realistic scenario, exhibited health risk, still within safe level. The exceeded one child case cypermethrin. cumulative risk assessment pesticide mixtures having an nervous system, based total margin calculations, did not indicate any risk. overall associated observed population low. However, using worst-case scenario suggests need continuous evaluation human compounds, especially children.

Language: Английский

Citations

19