Deleted Journal,
Journal Year:
2024,
Volume and Issue:
1(1), P. 100002 - 100002
Published: Jan. 18, 2024
With
a
booming
population,
global
food
demand
is
increasing
rapidly.
Various
methods
have
been
proposed
to
alleviate
heat
stress
and
improve
yields
for
agriculture
in
hot
climates.
However,
the
damage
caused
by
high
root
temperatures
cannot
be
avoided
due
lack
of
efficient
regulation
strategies.
In
this
work,
we
investigate
new
soil
cooling
strategy
based
on
daytime
radiative
film.
This
film
has
emissivity
across
atmospheric
window
along
with
reflectivity
solar
spectrum.
temperature
drop
12.5°C,
germination
rate
Cherry
Radish
improved
from
39.6%
81.3%
after
using
mulch.
field
test
during
summer,
mulch
increases
fresh
weight
yield
Chinese
cabbage
127.4%
arrtibuting
reduced
stress..
Moreover,
applicability
diverse
geographical
climatic
conditions
was
dicussed
global-scale
simulation.
The
limitations
future
development
perspectives
were
discussed
here.
passive
paves
way
tackle
water-food
crisis
without
extra
energy
consumption.
Advanced Materials,
Journal Year:
2021,
Volume and Issue:
34(10)
Published: Oct. 28, 2021
Abstract
Near‐infrared
(NIR)‐absorbing
organic
semiconductors
have
opened
up
many
exciting
opportunities
for
photovoltaic
(OPV)
research.
For
example,
new
chemistries
and
synthetical
methodologies
been
developed;
especially,
the
breakthrough
Y‐series
acceptors,
originally
invented
by
our
group,
specifically
Y1,
Y3,
Y6,
contributed
immensely
to
boosting
single‐junction
solar
cell
efficiency
around
19%;
novel
device
architectures
such
as
tandem
transparent
photovoltaics
realized.
The
concept
of
NIR
donors/acceptors
thus
becomes
a
turning
point
in
OPV
field.
Here,
development
NIR‐absorbing
materials
OPVs
is
reviewed.
According
low‐energy
absorption
window,
here,
(p‐type
(polymers)
n‐type
(fullerene
nonfullerene))
are
classified
into
four
categories:
700–800
nm,
800–900
900–1000
greater
than
1000
nm.
Each
subsection
covers
design,
synthesis,
utilization
various
types
donor
(D)
acceptor
(A)
units.
structure–property
relationship
between
kinds
D,
A
units
window
constructed
satisfy
requirements
different
applications.
Subsequently,
variety
applications
realized
materials,
including
OPVs,
photodetectors,
presented.
Finally,
challenges
future
next‐generation
beyond
discussed.
Advanced Functional Materials,
Journal Year:
2022,
Volume and Issue:
32(35)
Published: July 5, 2022
Abstract
Symmetric
conjugated
molecules
can
be
broken
through
suitable
synthetic
strategies
to
construct
novel
asymmetric
molecules,
which
largely
broaden
the
material
library.
In
field
of
organic
solar
cells,
fused‐ring
electron
acceptors
(FREAs)
with
A‐DA'D‐A
type
backbone
structure
have
attracted
much
attention
and
enabled
power
conversion
efficiencies
(PCE)
exceeding
18%.
Among
them,
Y6
is
one
most
classic
FREAs
that
derive
many
symmetric
exhibit
unique
optoelectronic
properties.
Thus,
in
this
review,
focus
on
recent
progress
Y6‐derived
containing
a
dipyrrolobenzothiadiazole
segment,
classified
as
following
three
categories:
end
group,
central
core
side
chain.
The
relationship
molecular
structure,
properties,
device
performance
discussed
detail.
Finally,
future
design
directions
challenges
faced
by
kind
photovoltaic
materials
are
given.
Advanced Energy Materials,
Journal Year:
2021,
Volume and Issue:
11(47)
Published: Oct. 29, 2021
Abstract
Side‐chain
modifications
of
non‐fullerene
acceptors
(NFAs)
are
essential
for
harvesting
their
full
potential
in
organic
solar
cells
(OSC).
Here,
an
effective
alkyl‐chain‐branching
approach
the
Y‐series
NFAs
flanking
meta‐substituted
phenyl
side
groups
at
outer
positions
is
demonstrated.
Compared
to
BTP‐4F‐PC6
with
linear
m
‐hexylphenyl
chains,
two
new
named
BTP‐4F‐P2EH
and
BTP‐4F‐P3EH
developed
bulkier
alkyl
chains
branched
β
γ
positions,
respectively.
These
result
altered
molecular
packing
afford
higher
open‐circuit
voltage
devices.
Despite
blue‐shifted
absorption
branched‐chain
NFAs,
blends
PBDB‐T‐2F
enable
improved
short‐circuit
current
density
corresponding
devices
owing
more
suitable
phase
separation
better
exciton
dissociation.
Consequently,
OSCs
based
on
yield
enhanced
device
performance
18.22%
17.57%,
respectively,
outperforming
BTP‐4F‐PC6‐based
ones
(17.22%).
results
highlight
that
side‐chain
branching
design
has
great
optimizing
properties
promoting
photovoltaic
performance.
Angewandte Chemie International Edition,
Journal Year:
2021,
Volume and Issue:
61(19)
Published: Dec. 28, 2021
Semitransparent
organic
solar
cells
(ST-OSCs)
are
considered
as
one
of
the
most
valuable
applications
OSCs
and
a
strong
contender
in
market.
However,
optical
band
gap
current
high-performance
ST-OSCs
is
still
not
low
enough
to
achieve
optimal
balance
between
power
conversion
efficiency
(PCE)
average
visible
transmittance
(AVT).
An
N-substituted
asymmetric
nonfullerene
acceptor
SN
with
over
40
nm
bathochromically
shifted
absorption
compared
Y6
was
designed
synthesized,
based
on
which
device
PM6
donor
obtained
PCE
14.3
%,
accompanied
nonradiative
voltage
loss
0.15
eV.
Meanwhile,
ternary
devices
addition
into
:
can
17.5
%
an
unchanged
open-circuit
improved
short-circuit
current.
Benefiting
from
extended
NIR
lowered
loss,
were
fabricated
optimized
demonstrated
14.0
at
AVT
20.2
highest
20
%.
Advanced Functional Materials,
Journal Year:
2021,
Volume and Issue:
32(4)
Published: Oct. 12, 2021
Abstract
High‐performance
organic
solar
cells
(OSCs)
at
the
current
stage
are
majorly
accomplished
from
processing
of
halogenated
solvents,
such
as
chloroform,
which
will
be
constrained
for
upscale
fabrication
due
to
adverse
health
and
environmental
impacts.
Therefore,
exploring
high‐performance
OSCs
non‐halogenated
solvent
becomes
highly
necessary,
yet
largely
lagged
behind.
Herein,
it
is
demonstrated
can
obtained
hot
spin
different
achieve
highest
reported
efficiency
so
far.
It
revealed
that
phase
evolution
ternary
blends
during
solution‐to‐solid
transition
has
a
correlation
substrate
temperature.
With
elevated
temperature
coating,
optimal
blend
films
secured
in
kinds
solvents.
As
result,
with
excellent
power
conversion
efficiencies
18.25%
o
‐xylene,
18.20%
p
18.12%
toluene,
respectively.
To
author's
best
knowledge,
these
results
represent
best‐performed
made
solvents
Energy & Environmental Science,
Journal Year:
2023,
Volume and Issue:
16(5), P. 2316 - 2326
Published: Jan. 1, 2023
Here
the
aggregation
behavior
differences
induced
by
solvent–material
and
material–material
interactions
are
clearly
revealed
combined
ex
situ
in
morphology
characterization
studies
on
representative
high-efficiency
OPV
systems.