Mitigating metal-organic framework (MOF) toxicity for biomedical applications

Chemical Engineering Journal, Journal Year: 2023, Volume and Issue: 471, P. 144400 - 144400

Published: June 25, 2023

Metal-organic frameworks (MOFs) are a novel class of crystalline porous materials, consisting metal ions and organic linkers. These hybrid materials possess exceptional porosity specific surface area, which have recently garnered significant interest due to their potential applications in gas separation storage, energy biomedical imaging, drug delivery. As MOFs being explored for applications, it is essential comprehensively assess toxicity. Although nearly ninety thousand been investigated, evaluating optimizing physico-chemical properties relevant biological systems remain critical clinical translation. In this review article, we first provide brief classification based on chemical structures. We then conduct comprehensive evaluation

Language: Английский

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Design and Advanced Manufacturing of NU‐1000 Metal–Organic Frameworks with Future Perspectives for Environmental and Renewable Energy Applications

Small, Journal Year: 2023, Volume and Issue: 20(15)

Published: Nov. 23, 2023

Abstract Metal–organic frameworks (MOFs) represent a relatively new family of materials that attract lots attention thanks to their unique features such as hierarchical porosity, active metal centers, versatility linkers/metal nodes, and large surface area. Among the extended list MOFs, Zr‐based‐MOFs demonstrate comparably superior chemical thermal stabilities, making them ideal candidates for energy environmental applications. As Zr‐MOF, NU‐1000 is first synthesized at Northwestern University. A comprehensive review various approaches synthesis MOFs obtaining properties (e.g., diverse morphologies, area, particular pore size distribution) applications in catalysis (electro‐, photo‐catalysis), CO 2 reduction, batteries, hydrogen storage, gas storage/separation, other fields are presented. The further outlines current challenges development derivatives practical applications, revealing areas future investigation.

Language: Английский

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Porous materials as effective chemiresistive gas sensors

Chemical Society Reviews, Journal Year: 2024, Volume and Issue: 53(5), P. 2530 - 2577

Published: Jan. 1, 2024

This review emphasizes the crucial role of chemiresistive gas sensors (CGS) in detection. It underscores porous materials as alternatives, showcasing their exceptional attributes. The explores CGS-based real-life applications.

Language: Английский

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Sustainable metal-organic frameworks (MOFs) for drug delivery systems

Materials Today Communications, Journal Year: 2023, Volume and Issue: 35, P. 106244 - 106244

Published: May 18, 2023

Language: Английский

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Road Map for In Situ Grown Binder‐Free MOFs and Their Derivatives as Freestanding Electrodes for Supercapacitors

Small, Journal Year: 2023, Volume and Issue: 19(20)

Published: Feb. 17, 2023

Among several electrocatalysts for energy storage purposes including supercapacitors, metal-organic frameworks (MOFs), and their derivatives have spurred wide spread interest owing to structural merits, multifariousness with tailor-made functionalities tunable pore sizes. The electrochemical performance of supercapacitors can be further enhanced using in situ grown MOFs derivatives, eliminating the role insulating binders whose "dead mass" contribution hampers device capability otherwise. expulsion not only ensures better adhesion catalyst material current collector but also facilitates transport electron electrolyte ions remedy cycle deterioration chemical stability. This review systematically summarizes different kinds metal-ligand combinations preparation techniques, modification strategies, properties, charge mechanisms as freestanding electrode materials determining supercapacitors. In end, highlights potential promises, challenges, state-of-the-art advancement rational design electrodes overcome bottlenecks improve applications.

Language: Английский

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Bio-inspired sustainable synthesis of silver nanoparticles as next generation of nanoproduct in antimicrobial and catalytic applications

Materials Science and Engineering B, Journal Year: 2024, Volume and Issue: 301, P. 117165 - 117165

Published: Jan. 5, 2024

Language: Английский

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Superior photocatalytic and self-cleaning performance of PVDF-TiO₂@NH₂-MIL-125(Ti)/PVA membranes for efficient produced water treatment

Journal of Water Process Engineering, Journal Year: 2025, Volume and Issue: 72, P. 107415 - 107415

Published: March 10, 2025

Language: Английский

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A review of recent developments of metal–organic frameworks as combined biomedical platforms over the past decade

Advances in Colloid and Interface Science, Journal Year: 2023, Volume and Issue: 316, P. 102908 - 102908

Published: April 25, 2023

Language: Английский

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BioMOF-Based Anti-Cancer Drug Delivery Systems

Nanomaterials, Journal Year: 2023, Volume and Issue: 13(5), P. 953 - 953

Published: March 6, 2023

A variety of nanomaterials have been developed specifically for biomedical applications, such as drug delivery in cancer treatment. These materials involve both synthetic and natural nanoparticles nanofibers varying dimensions. The efficacy a system (DDS) depends on its biocompatibility, intrinsic high surface area, interconnected porosity, chemical functionality. Recent advances metal-organic framework (MOF) nanostructures led to the achievement these desirable features. MOFs consist metal ions organic linkers that are assembled different geometries can be produced 0, 1, 2, or 3 defining features their outstanding variable functionality, which enable an endless range modalities loading drugs into hierarchical structures. MOFs, coupled with biocompatibility requisites, now regarded highly successful DDSs treatment diverse diseases. This review aims present development applications based chemically-functionalized MOF context concise overview structure, synthesis, mode action MOF-DDS is provided.

Language: Английский

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Metal-organic frameworks (MOFs) as efficient catalysts for electro-Fenton (EF) reactions: Current progress and prospects

Chemical Engineering Journal, Journal Year: 2023, Volume and Issue: 463, P. 142287 - 142287

Published: March 7, 2023

Language: Английский

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