Inorganic Chemistry,
Journal Year:
2025,
Volume and Issue:
unknown
Published: Feb. 20, 2025
In
the
work,
a
3D
Zn-based
MOF,
[CH3(NH2)2][Zn2(obdb)(OH)]·DMF
(compound
1)
has
been
formed
successfully
through
self-assembly
of
Zn(II)
ion
and
organic
linker
H4obdb
(4',4‴-oxybis[1,1'-biphenyl]-3,5-dicarboxylic
acid,
high-symmetrical
tetra-carboxylate
ligand)
under
solvothermal
conditions.
structure
compound
1,
Zn
symmetry-generated
ones
constitute
tetra-nuclear
cluster
[Zn4(μ2-COO)8(μ3-OH)2],
then
by
coordination
clusters
linkers,
stair-like
framework
containing
1D
rectangular
channel
with
porosity
47.3%
is
generated.
Interestingly,
1
confirmed
to
possess
striking
air
pH
stability.
Noteworthily,
results
detecting
studies
certify
that
can
serve
as
prospective
ratiometric
fluorescence
sensor
for
selectively
recognizing
1-hydroxypyrene
(1-HP)
among
diverse
urine
components
promising
probe
Asp
from
other
11
kinds
amino
acids
depended
on
"turn-off"
effects
decorated
high
quenching
efficiencies
(97.5%
1-HP
94.3%
Asp)
outstanding
sensitivity
Ksv
values
1.84
×
105
M-1
1.41
104
in
DMF-H2O
binary
system.
Amazingly,
sensing
capacities
maintain
similar
levels
fresh
human
compared
those
system,
giving
5.79
1.72
Asp.
RSC Advances,
Journal Year:
2024,
Volume and Issue:
14(41), P. 30201 - 30229
Published: Jan. 1, 2024
Recently,
metal-organic
frameworks
(MOFs)
have
attracted
much
attention
as
versatile
materials
for
drug
delivery
and
personalized
medicine.
MOFs
are
porous
structures
made
up
of
metal
ions
coupled
with
organic
ligands.
This
review
highlights
the
synthesis
techniques
used
to
design
specific
features
such
surface
area
pore
size,
encapsulation
within
not
only
improves
their
stability
solubility
but
also
allows
controlled
release
kinetics,
which
therapeutic
efficacy
minimizes
adverse
effects.
Furthermore,
it
discusses
challenges
potential
advantages
MOF-based
delivery,
MOF
stability,
biocompatibility,
scale-up
production.
With
further
advancements
in
synthesis,
functionalization
techniques,
understanding
interactions
using
biological
systems,
can
significant
promise
expanding
medicine
improving
patient
outcomes.
Journal of Materials Chemistry B,
Journal Year:
2025,
Volume and Issue:
unknown
Published: Jan. 1, 2025
This
review
discusses
the
recent
developments
in
copper-based
nanomaterials
that
utilize
copper-induced
cell
death,
categorized
by
materials
systems,
while
highlighting
limitations
of
current
cuproptosis
related
nanomaterials.
Journal of Materials Chemistry A,
Journal Year:
2024,
Volume and Issue:
12(32), P. 21230 - 21242
Published: Jan. 1, 2024
In
this
study,
a
novel
method
is
investigated
for
enhancing
the
electrochemical
performance
of
MOFs,
particularly
Ni-MOFs,
which
have
encountered
challenges
in
energy
storage
applications
owing
to
their
limited
electrical
conductivity
and
stability.
