Journal of Molecular Liquids, Journal Year: 2024, Volume and Issue: 409, P. 125547 - 125547
Published: July 16, 2024
Language: Английский
Journal of Molecular Liquids, Journal Year: 2024, Volume and Issue: 409, P. 125547 - 125547
Published: July 16, 2024
Language: Английский
Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 496, P. 154019 - 154019
Published: July 19, 2024
Language: Английский
Citations
11ChemSusChem, Journal Year: 2025, Volume and Issue: unknown
Published: Jan. 24, 2025
Abstract Valorization of carbohydrate‐rich biomass by conversion into industrially relevant products is at the forefront research in sustainable chemistry. In this work, we studied inulin 5‐hydroxymethylfurfural, deep eutectic solvents, presence acidic task‐specific ionic liquids as catalysts. We employed aliphatic and aromatic catalysts, choline chloride‐based solvents bearing glycols or carboxylic acids, solvents. The reactions were performed a biphasic system, with acetone benign extracting solvent, enabling continuous extraction 5‐HMF. aimed to find best experimental conditions for transformation, terms catalyst loading, reaction time temperature achieve an economical energy efficient process. also analyzed results solvent viscosity structural organization well catalysts acidity, elucidate which features mostly favour reaction. Under optimized conditions, obtained yield 5‐HMF 71 %, 80 °C 3 h. Our system can be scaled up recycled three times no loss yield. Finally, comparison literature shows that our achieves higher under milder than most protocols so far reported same transformation.
Language: Английский
Citations
1International Journal of Biological Macromolecules, Journal Year: 2025, Volume and Issue: 306, P. 141469 - 141469
Published: Feb. 25, 2025
Language: Английский
Citations
0Separation and Purification Technology, Journal Year: 2025, Volume and Issue: unknown, P. 132740 - 132740
Published: March 1, 2025
Language: Английский
Citations
0Journal of Molecular Liquids, Journal Year: 2024, Volume and Issue: 409, P. 125547 - 125547
Published: July 16, 2024
Language: Английский
Citations
0