Polyhedron, Journal Year: 2024, Volume and Issue: 264, P. 117212 - 117212
Published: Aug. 31, 2024
Language: Английский
Polyhedron, Journal Year: 2024, Volume and Issue: 264, P. 117212 - 117212
Published: Aug. 31, 2024
Language: Английский
Inorganica Chimica Acta, Journal Year: 2024, Volume and Issue: 568, P. 122115 - 122115
Published: May 3, 2024
Language: Английский
Citations
89Coordination Chemistry Reviews, Journal Year: 2024, Volume and Issue: 519, P. 216120 - 216120
Published: Aug. 9, 2024
Language: Английский
Citations
10Inorganica Chimica Acta, Journal Year: 2023, Volume and Issue: 562, P. 121892 - 121892
Published: Dec. 18, 2023
Language: Английский
Citations
15Applied Organometallic Chemistry, Journal Year: 2024, Volume and Issue: 38(11)
Published: July 25, 2024
A novel zinc‐based metal–organic framework (Zn‐MOF), designated as [Zn 3 (L)(bpyp) 2 (HCOO) ·2DMF·H O] ( 1 ), was synthesized using 2,5‐bis(pyrid‐4‐yl)pyridine (bpyp), 1,3,5‐benzenetricarboxylic acid (H L), and Zn(CH COO) ·2H O in a DMF solution. Single‐crystal X‐ray diffraction analysis revealed that MOF crystallizes the monoclinic system with C2/c space group, featuring (3,5)‐connected binodal network. The structural integrity characteristics of were confirmed by Fourier transform infrared (FT‐IR), thermal gravimetric (TGA), powder (PXRD), Brunauer–Emmett–Teller (BET) analyses, showing type IV isotherms indicative microporous structures. photocatalytic efficiency evaluated for degradation various antibiotics under UV light, nitrofurantoin (NFT) demonstrating highest rate 83.9% at an optimal concentration 40 ppm catalyst loading 5 mg. process followed pseudo‐first‐order kinetic model constant 0.02492 min −1 . Radical trapping experiments identified superoxide radicals (O ˙ − ) holes (h + predominant reactive species, while hydroxyl (˙OH) played negligible role. Reusability tests over four cycles stability durability , consistent performance unchanged morphology evidenced PXRD SEM analyses. proposed mechanism involves photoinduced electron–hole pair generation, subsequent formation oxygen species (ROS) facilitating NFT degradation. This study highlights promising photocatalyst environmental remediation, specifically efficient pharmaceutical contaminants aquatic systems, providing insights into its properties, activity, underlying mechanisms.
Language: Английский
Citations
3Inorganica Chimica Acta, Journal Year: 2024, Volume and Issue: 573, P. 122326 - 122326
Published: Aug. 22, 2024
Language: Английский
Citations
3Langmuir, Journal Year: 2023, Volume and Issue: 39(30), P. 10445 - 10452
Published: July 17, 2023
Three new hybrid metal-polymer-coordinated complexes (MPCs) of copper(II), cobalt(II), and nickel(II) ions with an organic polymer derived from gallic acid ethylenediamine (GAEtH) were synthesized. The structures GAEtH MPCs characterized FT-IR, ultraviolet (UV)-Vis,
Language: Английский
Citations
4Polyhedron, Journal Year: 2023, Volume and Issue: 243, P. 116575 - 116575
Published: July 28, 2023
Language: Английский
Citations
4Polyhedron, Journal Year: 2023, Volume and Issue: 246, P. 116693 - 116693
Published: Oct. 14, 2023
Language: Английский
Citations
4Polyhedron, Journal Year: 2024, Volume and Issue: 264, P. 117212 - 117212
Published: Aug. 31, 2024
Language: Английский
Citations
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