Nanomaterial-based AOPs for the removal of organic pollutants in aqueous matrices: A systematic review of response surface methodology (RSM) models DOI Creative Commons
Ramin Nabizadeh,

Samira Sheikhi

Environmental Technology & Innovation, Journal Year: 2024, Volume and Issue: 35, P. 103718 - 103718

Published: June 14, 2024

Organic pollutants in water mainly originate from human activities and can cause numerous problems for health the environment. In order to avoid these problems, organic must be removed using appropriate effective methods. Advanced oxidation processes (AOPs), which comprise different technologies, have attracted attention recent years due their high efficiency wastewater treatment. This systematic review evaluates effectiveness of nanomaterial-based AOPs removing aqueous solutions. The uniqueness this study is investigation response surface methodology (RSM) models. Specifically, present reviewed six subgroups AOPs, including Fe-based, TiO2-based, Zn-based, Cu-based, Mg-based, a set disparate categorized as others. effects process variables (including pH, contact time, initial pollutant concentration, catalyst dosage) were investigated by considering classification groups. total, 71 studies included review. data primarily analyzed with R software, graphs figures drawn if necessary. average pooled percentages Mg-based removal, regardless type, 87.53 %, 82.61 80.16 82.93 87.93 respectively. Based on review, nano-based efficiently remove matrices. Notably, however, changed depending conditions applied system.

Language: Английский

Sequestration of Paracetamol from Aqueous Solution Using Zinc Oxide/Polypyrrole Nanocomposite: Cost Analysis, Scale-Up Design, and Optimization of Process Parameters DOI

Bibek Saha,

Saptarshi Gayen,

Animesh Debnath

et al.

Journal of Hazardous Toxic and Radioactive Waste, Journal Year: 2023, Volume and Issue: 27(4)

Published: Aug. 3, 2023

The production of pharmaceuticals in recent years has been racing to its peak due the advancement society that led a rise variety diseases. Thus, disposal these untreated pharmaceutical products coming from hospital wastewater and medicine manufacturing plants water system is causing serious environmental threat. Therefore, this work mainly focuses on removal one widely used (e.g., paracetamol) with help adsorption technology using metal oxide-based polymer, is, zinc oxide/polypyrrole (ZnO/PPy). fabricated adsorbent was characterized X-ray diffraction, field emission gun–scanning electron microscopy, energy-dispersive spectroscopy, Fourier transform infrared Brunauer–Emmett–Teller analysis identify crystal formation, morphology, effective functional groups, surface area, respectively. A pseudo-second-order kinetic model better suits study compared pseudo-first-order intraparticle diffusion model. Langmuir isotherm fits provided paracetamol capacity 25.51 mg/g for ZnO/PPy. Monovalent anions Cl−, NO3−, HCO3−) have less impact efficiency (3.0% ∼10.0%) as divalent anion S2−) process. lab scale synthesis cost ZnO/PPy observed ∼111 USD/kg whereas associated process found be ∼4,347 paracetamol. Batch mode scale-up design indicated addition ∼426 g required 50 L contaminated treatment 95% efficiency.

Language: Английский

Citations

24

Controlled assembly of novel Fe2O3/MgFe2O4 nanotubular array structures for rapid detection of dibutylamine DOI
Baosheng Li, Junchao Yang, Guanyi Zhang

et al.

Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: 485, P. 149940 - 149940

Published: Feb. 24, 2024

Language: Английский

Citations

13

Ultrasound‐assisted sol–gel synthesis of N‐TiO2, Fe‐TiO2, and TiO2 with application in treatment of a commercial effluent DOI Open Access
Ananya Dey, Lakshay Vashishtha, Parag R. Gogate

et al.

Journal of Chemical Technology & Biotechnology, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 8, 2025

Abstract BACKGROUND Nitrogen doped titanium dioxide (N‐TiO 2 ), iron (Fe‐TiO and undoped (TiO ) nanocatalysts were synthesized using sol–gel method aided with ultrasound (US). The effects of duty cycle, US‐power, US irradiation time on catalyst characteristics investigated so as to establish the best synthesis conditions. RESULTS optimum parameters for minimum mean size particles 60% 100 W power, 20 min time. X‐Ray diffraction (XRD) analysis revealed that primary phase all was anatase crystallite 46.29 nm, 54.32 56.17 nm N‐TiO , Fe‐TiO TiO respectively. Field electron scanning microscopy (FE‐SEM) images confirmed is a mixture microspheres rice‐like structures whereas spherical. X‐ray photoelectron spectroscopy (XPS) study showed both exhibited minor shifts lower binding energies when compared spectra . application studies obtained catalysts simple ultrasonic horn disc coupled oxidants results (51.67% reduction in COD) at pH 12 addition mL per L −1 dose H O CONCLUSION Doping metal non‐metal ions improved catalytic activity maximum COD commercial effluent disk + based approach. © 2025 Society Chemical Industry (SCI).

Language: Английский

Citations

1

Nickel-decorated ZIF-67 (Co) MOF derived bi-metallic catalyst for efficient degradation of tetracycline under microwave irradiation through persulfate activation route: Performance assessment and predictive intermediate toxicity profile DOI
Saptarshi Bose, Mathava Kumar

Separation and Purification Technology, Journal Year: 2025, Volume and Issue: unknown, P. 132371 - 132371

Published: March 1, 2025

Language: Английский

Citations

1

Experimental and DFT theoretical study for understanding the adsorption mechanism of toxic dye onto innovative material Fb-HAp based on fishbone powder DOI
Youssef Miyah, Mohammed Benjellοun, Rajae Salim

et al.

Journal of Molecular Liquids, Journal Year: 2022, Volume and Issue: 362, P. 119739 - 119739

Published: June 28, 2022

Language: Английский

Citations

33

Peroxydisulfate-assisted sonocatalytic degradation of metribuzin by La-doped ZnFe layered double hydroxide DOI Creative Commons

Sultan Akdağ,

Tannaz Sadeghi Rad, Ramazan Keyikoğlu

et al.

Ultrasonics Sonochemistry, Journal Year: 2022, Volume and Issue: 91, P. 106236 - 106236

Published: Nov. 23, 2022

Metribuzin is an herbicide that easily contaminates ground and surface water. Herein, La-doped ZnFe layered double hydroxide (LDH) was synthesized for the first time used degradation of metribuzin via ultrasonic (US) assisted peroxydisulfate (PDS) activation. The LDH had a lamellar structure, average thickness 26 nm, showed mesoporous characteristics, including specific area 110.93 m

Language: Английский

Citations

30

Chemically synthesized manganese oxide nanorods for effectual organic dye removal and energy storage application DOI
Pinky Yadav, Ayana Bhaduri

Materials Chemistry and Physics, Journal Year: 2023, Volume and Issue: 299, P. 127495 - 127495

Published: Feb. 13, 2023

Language: Английский

Citations

21

Interface regulation of ZnIn2S4/g-C3N4 S-scheme heterojunction for revealing exciton transfer mechanism and enhancing photocatalytic performance DOI
Xiaojie Liu,

Shirong Kang,

Guang Yang

et al.

International Journal of Hydrogen Energy, Journal Year: 2023, Volume and Issue: 51, P. 410 - 424

Published: July 10, 2023

Language: Английский

Citations

21

Preparation of CdS–Ag2S nanocomposites by ultrasound-assisted UV photolysis treatment and its visible light photocatalysis activity DOI Creative Commons
Chao Han, Chu Cheng,

Fengling Liu

et al.

Nanotechnology Reviews, Journal Year: 2023, Volume and Issue: 12(1)

Published: Jan. 1, 2023

Abstract Thiosulfate is a green leaching agent used in the hydrometallurgical process because it both environmentally benign and can form required soluble ion complexes. In this article, novel method for synthesis of CdS–Ag 2 S nanocomposites from solution relevant complexes via ultrasound-assisted ultraviolet (UV) photolysis was proposed. An analysis mechanism revealed that undergo series photochemical reactions. The were synthesized by co-precipitation under UV-C irradiation. microstructure, chemical composition, optical electrochemical properties prepared analyzed to verify investigate product. photodegradation methyl orange (MO) xenon lamp performed determine photocatalytic activity. Under visible light irradiation, electrons transition (from valence band conduction band) photogenerated electron–hole pairs realizing effective separation carriers finally promote degradation MO water carbon dioxide. subsequent efficiency found be 87% after 90 min, larger than 78% pure CdS UV photolysis, indicating as-developed effectively fabricate photocatalyst with superior performance.

Language: Английский

Citations

20

A synergistic consequence of catalyst dosage, pH solution and reactive species of Fe-doped CdAl2O4 nanoparticles on the degradation of toxic environmental pollutants DOI

G. Rajesh,

P. Senthil Kumar, S. Akilandeswari

et al.

Chemosphere, Journal Year: 2023, Volume and Issue: 318, P. 137919 - 137919

Published: Jan. 23, 2023

Language: Английский

Citations

18