Chemical Engineering Journal, Journal Year: 2024, Volume and Issue: unknown, P. 158624 - 158624
Published: Dec. 1, 2024
Language: Английский
Green Chemistry, Journal Year: 2024, Volume and Issue: 26(7), P. 3627 - 3669
Published: Jan. 1, 2024
Deep eutectic solvents (DESs) enable many processes to be environmentally friendly. This Tutorial Review aims showcase the roles of DESs in synthesis functional materials from a green chemistry perspective.
Language: Английский
Citations
56
Advanced Materials, Journal Year: 2024, Volume and Issue: 36(23)
Published: Feb. 27, 2024
Ionic liquids and their various analogues are without doubt the scientific sensation of last few decades, paving way to a more sustainable society. Their versatile suite properties, originating from an almost inconceivably large number possible cation anion combinations, allows tuning structure serve desired purpose. hence offer myriad useful applications solvents catalysts, through lubricants, gas absorbers, azeotrope breakers. The purpose this review is explore unexpected these applications, particularly in energy space. It guides reader application ionic as i) phase change materials for thermal storage, ii) organic plastic crystals, which have been studied battery electrolytes separation, iii) key components nitrogen reduction reaction ammonia generation, iv) aluminum-ion batteries, v) other emerging technologies. concluded that there tremendous scope further optimizing liquid its task, subject sustainability imperatives line with current global priorities, assisted by artificial intelligence.
Language: Английский
Citations
45
Advanced Functional Materials, Journal Year: 2025, Volume and Issue: unknown
Published: Jan. 2, 2025
Abstract The rapid expansion of the global economy has led to a surge in energy demand, resulting significant environmental pollution and scarcity due concomitant increase greenhouse gas emissions. advancement deep eutectic solvents (DESs) introduced viable substitute for traditional processing methods, boasting numerous intrinsic benefits, such as superior eco‐compatibility, outstanding thermal stability, desirable electrochemical properties. Consequently, DESs have garnered attention from research community, demonstrating broad spectrum prospective applications variety fields instance energy, biomass degradation, materials synthesis, biomedicine. This review aims offer comprehensive methodical overview DESs, encompassing their historical development, classification, preparation methodologies, fundamental physicochemical Furthermore, this explores synthesis various functional examines multifunctional roles. Crucially, economic viability is thoroughly examined, including an assessment cost‐effectiveness market potential. Finally, concludes by outlining future directions development challenges that remain.
Language: Английский
Citations
5
International Journal of Biological Macromolecules, Journal Year: 2024, Volume and Issue: 265, P. 130858 - 130858
Published: March 13, 2024
Language: Английский
Citations
12
Hydrometallurgy, Journal Year: 2025, Volume and Issue: unknown, P. 106465 - 106465
Published: March 1, 2025
Language: Английский
Citations
1
RSC Applied Interfaces, Journal Year: 2024, Volume and Issue: 1(3), P. 600 - 611
Published: Jan. 1, 2024
This study investigates the role of polyvinylpyrrolidone (PVP) as a capping and stabilizing agent for synthesis gold nanoparticles (AuNPs) in nonaqueous choline chloride–urea deep eutectic solvent (DES).
Language: Английский
Citations
7
ChemistrySelect, Journal Year: 2024, Volume and Issue: 9(22)
Published: June 6, 2024
Abstract To replace the hazardous organic solvents currently in use, one of key objectives green chemistry has been development obtained from natural sources. Natural deep eutectic (NADES) are bio‐based compounds, namely primary metabolites like acids, sugar, alcohols, amines, and amino which acceptable to environment may eventually conventionally used harsh solvents. This study focuses on recent developments realm these innovative materials as well conventional (DES)‐based techniques. A more in‐depth examination DES's applications various chemical processes is covered after a description its definition, manufacture, unique characteristics. Their significance designer reactions their impact production methods addressed.
Language: Английский
Citations
7
Journal of Applied Polymer Science, Journal Year: 2024, Volume and Issue: 141(34)
Published: June 16, 2024
Abstract Electrospinning is currently one of the most used techniques for obtaining various types nanofibers. In era sustainable development, it essential to utilize environmentally friendly raw materials and solvents. This review summarizes current state art in biopolymer electrospinning using deep eutectic To date, there have not been too many studies on simultaneous application these mixtures biopolymers process. Nevertheless, use natural origin replacement conventional organic solvents with appear promising this technique due attractive properties both biopolymers. article aims inspire scientists further research direction, related development aimed at reducing negative environmental impact.
Language: Английский
Citations
7
Molecules, Journal Year: 2024, Volume and Issue: 29(15), P. 3543 - 3543
Published: July 27, 2024
Mesoporous silica SBA-15 has emerged as a promising adsorbent and separation material due to its unique structural physicochemical properties. To further enhance performance, various surface modification strategies, including metal oxide noble incorporation for improved catalytic activity stability, organic functionalization with amino thiol groups enhanced adsorption capacity selectivity, inorganic-organic composite synergistic effects, have been extensively explored. This review provides comprehensive overview of the recent advances in applications. The synthesis methods, properties, advantages are discussed, followed by detailed analysis different strategies their structure-performance relationships. performance functionalized materials removal pollutants, heavy ions, gases, biomolecules, well chromatographic solid-liquid separation, is critically evaluated. Despite significant progress, challenges opportunities future research identified, development low-cost sustainable routes, rational design SBA-15-based tailored integration into practical aims guide efforts developing advanced environmental industrial applications, an emphasis on green scalable strategies.
Language: Английский
Citations
7
Analytical and Bioanalytical Chemistry, Journal Year: 2024, Volume and Issue: 416(6), P. 1337 - 1347
Published: Feb. 3, 2024
Abstract Nowadays, molecularly imprinted polymers (MIPs) are well established and considered excellent materials for performing selective extractions. However, with the progressive implementation of principles green chemistry, it is necessary to find greener alternatives both synthesis further use MIPs in sample preparation. Accordingly, present work, different deep eutectic solvents (DES, hydrophilic hydrophobic), as an alternative conventional organic (i.e., toluene), were evaluated porogens fibers (monoliths), using fused silica capillaries molds, solid-phase microextraction (SPME). From this study, polymer prepared propazine (dummy template), methacrylic acid (monomer), ethylene glycol dimethacrylate (cross-linker), a formic acid:L-menthol (1:1) DES (porogen) showed best performance rebinding triazines. After optimization variables involved SPME, new successfully applied extraction target analytes (desisopropylatrazine, desethylatrazine, simazine, atrazine) from soil extracts, providing relative recoveries ranging 75.7 120.1%, reaching limits detection within range 6.2–15.7 ng g −1 , depending upon analyte. Graphical
Language: Английский
Citations
6