ACS Materials Letters,
Journal Year:
2023,
Volume and Issue:
5(8), P. 1982 - 1991
Published: June 26, 2023
Fluorescent
supramolecular
cages
have
attracted
significant
scientific
interest
owing
to
their
widespread
applications
in
molecular
sensing,
luminescent
materials,
and
biological
systems.
However,
the
modular
construction
of
such
assemblies
with
tunable
emission
behaviors
affording
high-performance
bioimaging
is
still
challenging.
Herein,
we
developed
a
general
straightforward
protocol
formulate
an
aggregation-induced
(AIE)
tendency
by
using
"donor–acceptor–donor
(D–A–D)"
adducts
as
building
blocks.
A
series
box-shaped
MA–MG
adjustable
fluorescence
from
red
second
near-infrared
(NIR-II)
region
were
successfully
prepared.
In
particular,
maximum
MG
was
located
at
981
nm,
behaving
like
rare
NIR-II
emissive
thus
far,
cage-loaded
nanoparticles
MGNPs
featured
high
absolute
quantum
yield
region,
which
enabled
them
perform
well
blood
vessel
imaging.
Advanced Materials,
Journal Year:
2023,
Volume and Issue:
unknown
Published: Aug. 10, 2023
Rapid
advancements
in
materials
science
and
nanotechnology,
intertwined
with
oncology,
have
positioned
photothermal
therapy
(PTT)
as
a
promising
noninvasive
treatment
strategy
for
cancer.
The
breast's
superficial
anatomical
location
aesthetic
significance
render
breast
cancer
particularly
pertinent
candidate
the
clinical
application
of
PTT
following
melanoma.
This
review
comprehensively
explores
research
conducted
on
various
types
nanoparticles
employed
elaborates
their
specific
roles
mechanisms
action.
integration
existing
therapies
is
scrutinized,
underscoring
its
potential
synergistic
outcomes.
Additionally,
underlying
consequential
modifications
to
tumor
microenvironment
after
are
elaborated
from
medical
perspective.
Future
directions
suggested,
an
emphasis
development
integrative
platforms
that
combine
multiple
therapeutic
approaches
optimization
nanoparticle
synthesis
enhanced
efficacy.
goal
push
boundaries
toward
comprehensive,
clinically
applicable
Journal of the American Chemical Society,
Journal Year:
2023,
Volume and Issue:
145(14), P. 7692 - 7711
Published: March 28, 2023
Self-assembled
discrete
molecular
architectures
that
show
selective
recognition
within
their
internal
cavities
are
highly
desirable.
Such
hosts
often
guest
through
several
noncovalent
interactions.
This
emulates
the
activity
of
naturally
occurring
enzymes
and
proteins.
Research
in
formation
3D
cages
different
shapes
sizes
has
progressed
rapidly
since
development
coordination-driven
self-assembly
dynamic
covalent
chemistry.
find
applications
catalysis,
stabilization
metastable
molecules,
purification
isomeric
mixtures
via
encapsulation,
even
biomedical
applications.
Most
these
stem
from
ability
host
to
bind
guests
strongly
a
fashion,
providing
suitable
environment
for
perform
functions.
Molecular
having
closed
with
small
windows
either
poor
encapsulation
or
inhibit
easy
release
while
those
wide
open
structures
fail
form
stable
host-guest
complexes.
In
this
context,
barrels
obtained
by
metal-ligand/covalent
bond
techniques
possess
optimized
architectures.
With
hollow-walled
cavity
two
large
openings,
satisfy
structural
requirements
many
perspective,
we
will
discuss
detail
synthetic
strategies
obtaining
barrel-like
employing
coordination
interactions,
structure-based
classification,
storing
transient
separation
chemicals,
photoinduced
antibacterial
activity.
We
aim
highlight
advantages
over
other
efficiently
carrying
out
functions
new
Angewandte Chemie International Edition,
Journal Year:
2024,
Volume and Issue:
63(18)
Published: Feb. 21, 2024
The
development
of
artificial
light-harvesting
systems
mimicking
the
natural
photosynthesis
method
is
an
ever-growing
field
research.
Numerous
such
as
polymers,
metal
complexes,
POFs,
COFs,
supramolecular
frameworks
etc.
have
been
fabricated
to
accomplish
more
efficient
energy
transfer
and
storage.
Among
them,
coordination
complexes
(SCCs)
formed
by
non-covalent
metal-ligand
interaction,
shown
capacity
not
only
undergo
single
multistep
migration
but
also
utilize
harvested
for
a
wide
variety
applications
photocatalysis,
tunable
emissive
systems,
encrypted
anti-counterfeiting
materials,
white
light
emitters
This
review
sheds
on
behavior
both
2D
metallacycles
3D
metallacages
where
design
ingenuity
has
executed
afford
harvesting
donor
ligands
well
acceptors.
Angewandte Chemie International Edition,
Journal Year:
2022,
Volume and Issue:
61(39)
Published: Aug. 5, 2022
The
structures
of
the
crosslinks
in
supramolecular
polymer
networks
play
an
important
role
on
their
properties
and
functions.
Herein,
emissive
metallacages
are
used
as
to
prepare
metallacage-cored
polyurethanes.
mechanical
including
storage
modulus,
toughness,
Young's
modulus
breaking
strength
polymers
greatly
enhanced
with
increase
crosslinking
densities.
Moreover,
such
not
only
exhibit
good
fluorescence
solid
state,
but
also
show
self-healing
shape
memory
owing
dynamic
reversible
non-covalent
bonds
structures.
This
study
offers
a
convenient
strategy
metallacage-crosslinked
networks,
explores
applications
materials,
which
will
promote
smart
materials.
Journal of the American Chemical Society,
Journal Year:
2023,
Volume and Issue:
145(13), P. 7446 - 7453
Published: March 22, 2023
Herein,
a
series
of
face-capped
(Tr2M3)4L4
(Tr
=
cycloheptatrienyl
cationic
ring;
M
metal;
L
organosulfur
ligand)
tetrahedral
cages
1-3
functionalized
with
12
appended
crown
ether
moieties
were
designed
and
synthesized.
The
reversible
binding
ammonium
cations
peripheral
to
adjust
internal
guest-binding
was
realized.
Combination
bisammonium
linker
cage
3
led
the
formation
supramolecular
gel
SPN1
via
host-guest
interactions
between
salts.
obtained
exhibited
multiple-stimuli
responsiveness,
injectability,
excellent
self-healing
properties
could
be
further
developed
SPN1-based
drug
delivery
system.
In
addition,
storage
modulus
20
times
higher
than
that
model
without
Pd-Pd
bonded
blocks,
had
better
compared
latter,
demonstrating
importance
such
in
improving
mechanical
strength
losing
dynamic
material.
cytotoxicity
vitro
drug-loaded
(doxorubicin
or
methotrexate)
significantly
improved
free
drugs.
Angewandte Chemie International Edition,
Journal Year:
2023,
Volume and Issue:
63(4)
Published: Nov. 15, 2023
Abstract
The
development
of
multimode
photopatterning
systems
based
on
supramolecular
coordination
complexes
(SCCs)
is
considerably
attractive
in
chemistry
and
materials
science,
because
SCCs
can
serve
as
promising
platforms
for
the
incorporation
multiple
functional
building
blocks.
Herein,
we
report
a
light‐responsive
liquid‐crystalline
metallacycle
that
constructed
by
coordination‐driven
self‐assembly.
By
exploiting
its
fascinating
liquid
crystal
features,
bright
emission
properties,
facile
photocyclization
capability,
unique
system
with
spatially‐controlled
fluorescence‐resonance
energy
transfer
(FRET)
built
through
introduction
photochromic
spiropyran
derivative,
which
led
to
realization
first
example
orthogonal
three‐modes,
namely
holography,
fluorescence,
photochromism.
ACS Materials Letters,
Journal Year:
2023,
Volume and Issue:
5(4), P. 1061 - 1082
Published: March 8, 2023
Due
to
their
precise
three-dimensional
structures
and
tunable
cavities,
metallacages
covalent
cages
have
been
widely
used
in
various
fields,
such
as
catalysis,
separation,
sensing,
biomedicine.
As
a
result
of
the
unique
pattern
directed
synthesis
modular
assembly,
can
be
modified
many
different
ways
construct
stimuli-responsive
for
marker
detection
imaging
biological
applications.
Additionally,
agents
drugs
loaded
into
cavity
achieve
disease
diagnosis
treatment.
This
Review
summarizes
recent
advances
applications
presents
representative
examples
therapeutics.
The
problems
future
development
directions
are
emphasized,
which
may
provide
clear
guidance
design
application
controllable
diagnostic
reagents.
Angewandte Chemie International Edition,
Journal Year:
2023,
Volume and Issue:
62(28)
Published: May 11, 2023
Construction
of
metal-organic
cages
with
unique
architecture
and
guest
binding
abilities
is
highly
desirable.
Herein,
we
report
the
synthesis
a
distorted
trigonal
cage
(1)
from
twisted
tetratopic
ligand
(L)
PdII
acceptor.
Surprisingly,
1
exhibited
complete
structural
reorganization
its
building
units
in
presence
C70
C60
to
form
guest-encapsulated
tetragonal
cages,
(C70
)2
@2
(C60
@2,
respectively.
These
guest-bound
were
found
be
potential
O2
generators,
former
effectively
catalyzing
two
different
varieties
-mediated
oxidation
reactions.
