Quaternary Ammonium Compounds (QACs) and Ionic Liquids (ILs) as Biocides: From Simple Antiseptics to Tunable Antimicrobials DOI Open Access
A. N. Vereshchagin, Nikita A. Frolov, Ksenia S. Egorova

et al.

International Journal of Molecular Sciences, Journal Year: 2021, Volume and Issue: 22(13), P. 6793 - 6793

Published: June 24, 2021

Quaternary ammonium compounds (QACs) belong to a well-known class of cationic biocides with broad spectrum antimicrobial activity. They are used as essential components in surfactants, personal hygiene products, cosmetics, softeners, dyes, biological antiseptics, and disinfectants. Simple but varied their structure, QACs divided into several subclasses: Mono-, bis-, multi-, poly-derivatives. Since the beginning 20th century, significant amount work has been dedicated advancement this biocides. Thus, more than 700 articles on were published only 2020, according modern literature. The structural variability diverse activity ionic liquids (ILs) make them highly prospective for developing new types ILs bear common key element molecular structure-quaternary positively charged nitrogen atoms within cyclic or acyclic framework. state-of-the-art research level paramount demand society recall rapid development generation tunable antimicrobials. This review focuses main exhibiting antifungal properties, commercial products based QACs, latest discoveries connected biocide development.

Language: Английский

Introduction: Ionic Liquids DOI Open Access
Zhigang Lei, Biaohua Chen,

Yoon-Mo Koo

et al.

Chemical Reviews, Journal Year: 2017, Volume and Issue: 117(10), P. 6633 - 6635

Published: May 24, 2017

ADVERTISEMENT RETURN TO ISSUEEditorialNEXTIntroduction: Ionic LiquidsZhigang Lei*, Biaohua Chen, Yoon-Mo Koo, and Douglas R. MacFarlaneView Author Information State Key Laboratory of Chemical Resource Engineering, Beijing University Technology, China Department Biological Inha University, Korea School Chemistry, Monash Australia*E-mail: [email protected]Cite this: Chem. Rev. 2017, 117, 10, 6633–6635Publication Date (Web):May 24, 2017Publication History Published online24 May 2017Published inissue 24 2017https://pubs.acs.org/doi/10.1021/acs.chemrev.7b00246https://doi.org/10.1021/acs.chemrev.7b00246editorialACS PublicationsCopyright © 2017 American Society. This publication is available under these Terms Use. Request reuse permissions free to access through this site. Learn MoreArticle Views98151Altmetric-Citations896LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum full text article downloads since November 2008 (both PDF HTML) across all institutions individuals. These metrics regularly updated reflect usage leading up last few days.Citations number other articles citing article, calculated by Crossref daily. Find more information about citation counts.The Altmetric Attention Score a quantitative measure attention that research has received online. Clicking on donut icon will load page at altmetric.com with additional details score social media presence for given article. how calculated. Share Add toView InAdd Full Text ReferenceAdd Description ExportRISCitationCitation abstractCitation referencesMore Options onFacebookTwitterWechatLinked InRedditEmail (199 KB) Get e-AlertscloseSUBJECTS:Catalysts,Extraction,Liquids,Salts,Solvents e-Alerts

Language: Английский

Citations

1136

Ionic liquids synthesis and applications: An overview DOI
Sandip K. Singh,

Anthony W. Savoy

Journal of Molecular Liquids, Journal Year: 2019, Volume and Issue: 297, P. 112038 - 112038

Published: Nov. 14, 2019

Language: Английский

Citations

963

Stretchable Conductive Polymers and Composites Based on PEDOT and PEDOT:PSS DOI
Laure V. Kayser, Darren J. Lipomi

Advanced Materials, Journal Year: 2019, Volume and Issue: 31(10)

Published: Jan. 2, 2019

Abstract The conductive polymer poly(3,4‐ethylenedioxythiophene) (PEDOT), and especially its complex with poly(styrene sulfonate) (PEDOT:PSS), is perhaps the most well‐known example of an organic conductor. It highly conductive, largely transmissive to light, processible in water, flexible. Much recent work on this ubiquitous material has been devoted increasing deformability beyond flexibility—a characteristic possessed by any that sufficiently thin—toward stretchability, a requires engineering structure at molecular‐ or nanoscale. Stretchability enabling range applications envisioned for PEDOT energy healthcare, such as wearable, implantable, large‐area electronic devices. High degrees mechanical allow intimate contact biological tissues solution‐processable printing techniques (e.g., roll‐to‐roll printing). PEDOT:PSS, however, only stretchable up around 10%. Here, strategies have reported enhance stretchability polymers composites based PEDOT:PSS are highlighted. These include blending plasticizers polymers, deposition elastomers, formation fibers gels, use intrinsically scaffolds polymerization PEDOT.

Language: Английский

Citations

894

Ionic liquids: a brief history DOI Creative Commons
Tom Welton

Biophysical Reviews, Journal Year: 2018, Volume and Issue: 10(3), P. 691 - 706

Published: April 26, 2018

Abstract There is no doubt that ionic liquids have become a major subject of study for modern chemistry. We used to ever more publications in the field each year, although there some evidence this beginning plateau at approximately 3500 papers year. They been several reviews and books, dealing with different applications aspects their behaviours. In article, I will show little how interest grew developed.

Language: Английский

Citations

827

Toxicity of Metal Compounds: Knowledge and Myths DOI Creative Commons
Ksenia S. Egorova, Valentine P. Ananikov

Organometallics, Journal Year: 2017, Volume and Issue: 36(21), P. 4071 - 4090

Published: Nov. 13, 2017

Organometallic reagents and metal catalysts are used ubiquitously in academia industry. Not surprisingly, the biological activity environmental danger of compounds have become topics outstanding importance. In spite rapid development toxicology during last decades, several common historically established "beliefs" still frequently circulating organometallic community. this Tutorial, we discuss existing opinions concerning (1) possibilities toxicity measurements, (2) high toxicities heavy-metal compounds, (3) correlation between structure a compound its toxicity, (4) effect direct/indirect contacts with (5) dangers nanoparticles. Basic concepts studies known data described Tutorial step by upon discussion these issues. The main goal is to demonstrate that cannot be regarded as constant property, since it depends on oxidation state, ligands, solubility, morphology particles, properties environment, other factors. As far such chemically labile species concerned, nature effects should not assumed or taken for granted; indeed, reliable conclusions made without dedicated measurements.

Language: Английский

Citations

604

New horizons in the extraction of bioactive compounds using deep eutectic solvents: A review DOI
Mohamad Hamdi Zainal-Abidin, Maan Hayyan, Adeeb Hayyan

et al.

Analytica Chimica Acta, Journal Year: 2017, Volume and Issue: 979, P. 1 - 23

Published: May 29, 2017

Language: Английский

Citations

534

The peculiar effect of water on ionic liquids and deep eutectic solvents DOI Creative Commons
Chunyan Ma, Aatto Laaksonen, Chang Liu

et al.

Chemical Society Reviews, Journal Year: 2018, Volume and Issue: 47(23), P. 8685 - 8720

Published: Jan. 1, 2018

Comprehensive review of unique effects water on ionic liquids and deep eutectic solvents observed in experimental theoretical studies.

Language: Английский

Citations

461

Pretreatment for biorefineries: a review of common methods for efficient utilisation of lignocellulosic materials DOI Creative Commons
Mats Galbe, Ola Wallberg

Biotechnology for Biofuels, Journal Year: 2019, Volume and Issue: 12(1)

Published: Dec. 1, 2019

Abstract The implementation of biorefineries based on lignocellulosic materials as an alternative to fossil-based refineries calls for efficient methods fractionation and recovery the products. focus biorefinery concept utilisation biomass has shifted, from design more or less energy-driven biorefineries, much versatile facilities where chemicals energy carriers can be produced. sugar-based platform requires pretreatment materials, which very recalcitrant, improve further processing through enzymatic hydrolysis, other downstream unit operations. This review summarises development in field (and some extent, fractionation) various materials. number publications indicates that plays a important role realised full scale. traditional methods, example, steam (explosion), organosolv hydrothermal treatment are covered review. In addition, rapidly increasing interest chemical employing ionic liquids deep-eutectic solvents discussed reviewed. It concluded huge variation makes it difficult find general process biorefinery. Therefore, is define “the best pretreatment” method. end, this depends proposed application, any recommendation suitable method must thorough techno-economic evaluation.

Language: Английский

Citations

407

Fully organic compliant dry electrodes self-adhesive to skin for long-term motion-robust epidermal biopotential monitoring DOI Creative Commons
Lei Zhang, Kirthika Senthil Kumar, Hao He

et al.

Nature Communications, Journal Year: 2020, Volume and Issue: 11(1)

Published: Sept. 17, 2020

Abstract Wearable dry electrodes are needed for long-term biopotential recordings but limited by their imperfect compliance with the skin, especially during body movements and sweat secretions, resulting in high interfacial impedance motion artifacts. Herein, we report an intrinsically conductive polymer electrode excellent self-adhesiveness, stretchability, conductivity. It shows much lower skin-contact noise static dynamic measurement than current standard gel electrodes, enabling to acquire high-quality electrocardiogram (ECG), electromyogram (EMG) electroencephalogram (EEG) signals various conditions such as wet skin movement. Hence, this can be used healthcare monitoring complex daily conditions. We further investigated capabilities of a clinical setting realized its ability detect arrhythmia features atrial fibrillation accurately, quantify muscle activity deep tendon reflex testing contraction against resistance.

Language: Английский

Citations

400

Materials for oral delivery of proteins and peptides DOI
Tyler Brown, Kathryn A. Whitehead, Samir Mitragotri

et al.

Nature Reviews Materials, Journal Year: 2019, Volume and Issue: 5(2), P. 127 - 148

Published: Dec. 24, 2019

Language: Английский

Citations

387