The Science of The Total Environment,
Journal Year:
2024,
Volume and Issue:
946, P. 174062 - 174062
Published: June 24, 2024
The
concern
on
the
fate
and
distribution
of
contaminants
emerging
(CECs)
is
a
burning
topic
due
to
their
persistence
potential
harmful
effects.
Particularly,
antibiotics
have
received
great
attention
implications
in
antimicrobial
resistance
occurrence.
impact
wastewater
treatment
plants
(WWTP)
remarkable,
being
one
main
pathways
for
introduction
CECs
into
aquatic
systems.
combination
novel
analytical
methodologies
risk
assessment
strategies
promising
tool
find
out
environmentally
relevant
compounds
posing
major
concerns
freshwater
ecosystems
impacted
by
those
effluents.
Within
this
context,
multi-target
approach
was
applied
three
Spanish
river
basins
affected
different
WWTP
treated
effluents
spatio-temporal
monitoring
chemical
status.
Solid
phase
extraction
followed
ultra-high-performance
liquid
chromatography
were
used
quantification
large
panel
(n
=
270),
including
pharmaceuticals
other
consumer
products,
pesticides
industrial
chemicals.
To
end,
water
samples
collected
four
sampling
campaigns
at
locations
each
basin:
(i)
upstream
from
WWTPs;
(ii)
effluent
discharge
points
(effluent
outfall);
(iii)
downstream
WWTPs
(500
m
downriver
outfall).
Likewise,
24-h
composite
provided
all
periods.
First
occurrence
these
assessed.
Diverse
seasonal
trends
observed
depending
group
compounds,
though
COVID-19
outbreak
variations
certain
pharmaceuticals.
Detection
frequencies
concentrations
generally
exceeded
measured
low
or
non-quantifiable.
Finally,
risks
associated
with
maximum
contamination
levels
evaluated
using
two
approaches
account
antibiotic
selection
as
well.
From
studied
89
evidenced
environmental
least
occasion
study.
Science Advances,
Journal Year:
2024,
Volume and Issue:
10(39)
Published: Sept. 25, 2024
Global
monitoring
of
persistent
organic
pollutants
(POPs)
has
intensified
following
regulatory
efforts
aimed
at
reducing
their
release.
In
this
context,
we
compiled
over
10,000
POP
measurements,
reported
from
1980
to
2023,
assess
the
effectiveness
these
legislative
measures
in
global
marine
environments.
While
a
general
decreasing
trend
legacy
concentrations
is
evident
across
various
maritime
regions,
highlighting
success
source
control
measures,
Arctic
Ocean
and
its
marginal
seas
have
experienced
rise
levels.
This
increase
suggests
northward
migration
via
ocean
currents
mid-latitude
regions
polar
areas.
Despite
reduce
emissions,
continued
transport
accumulation
may
substantial
ecological
impacts.
Addressing
environmental
challenges
demands
thorough
understanding
dynamics,
including
response
times,
multiphase
transport,
biogeochemical
cycling.
Continued
research
into
processes
vital
accurately
map
distribution
temporal
variations
within
systems.
Environmental Toxicology and Chemistry,
Journal Year:
2025,
Volume and Issue:
unknown
Published: Jan. 6, 2025
Abstract
Surface
water
concentrations
of
per-
and
polyfluoroalkyl
substances
(PFAS)
potential
for
resulting
biological
effects
were
estimated
in
a
study
using
Polar
Organic
Chemical
Integrative
Samplers
(POCIS)
from
60
tributary
sites
within
20
watersheds
the
Great
Lakes
Basin
2018.
Sites
represented
range
urban
to
agricultural,
forested,
wetland
land
uses
included
gradient
wastewater
treatment
effluent
zero
44%
annual
streamflow.
Several
also
had
airport
influence.
Twenty-one
32
targeted
PFAS
compounds
detected
POCIS
samplers,
which,
16
available
sampling
rates
enabling
time-weighted
concentration
estimates
comparison
with
data.
Estimated
compared
published
quality
guidelines
(available
nine
PFAS),
effect
reported
primary
literature
ECOTOX
Knowledgebase
apical
endpoints
(10
PFAS)
non-apical
vitro
high-throughput
screening
data
ToxCast
(14
PFAS).
Based
on
conservative
evaluation
approach
that
was
weighted
persistence
limitations
toxicological
information,
five
individual
PFAS,
including
Perfluorooctanesulfonic
acid,
Perfluorohexanesulfonic
Perfluorobutanesulfonic
Perfluorooctanoic
Perfluorononanoic
acid
identified
as
warranting
additional
investigation.
Possible
increased
potency
mixtures
over
chemical
effects,
by
summation
exposure-activity
ratios
(EARs)
chemicals
influence
common
assays
specified
gene
targets,
indicated
EAR
values
up
5.6-fold
14
contributing
mixture
predictions.
Potential
summed
ratios,
correlated
use
proportion
streamflow
contributed
effluent.