Chemical exposure in females of childbearing age associated with sex hormones: Evidence from an untargeted exposomic approach DOI Creative Commons
Minmin Hou, Song Tang, Feng Zhang

et al.

Environment International, Journal Year: 2025, Volume and Issue: 197, P. 109362 - 109362

Published: March 1, 2025

Language: Английский

First Evidence of the Bioaccumulation and Trophic Transfer of Tire Additives and Their Transformation Products in an Estuarine Food Web DOI

Li-Ni Wei,

Nian-Nian Wu,

Ru Xu

et al.

Environmental Science & Technology, Journal Year: 2024, Volume and Issue: 58(14), P. 6370 - 6380

Published: March 18, 2024

The discovery of the significant lethal impacts tire additive transformation product N-(1,3-dimethylbutyl)-N′-phenyl-p-phenylenediamine quinone (6PPD-Q) on coho salmon has garnered global attention. However, bioaccumulation and trophic transfer additives their products (TATPs) within food webs remain obscure. This study first characterized levels compositions 15 TATPs in Pearl River Estuary, estimated potential 21 estuarine species, identified priority contaminants. Our observations indicated that were prevalent environment. Eight, six, seven, 10 quantified shrimp, sea cucumber, snail, fish samples, with total mean 45, 56, 64, 67 ng/g (wet weight), respectively. N,N′-Diphenyl-p-phenylenediamine (DPPD) N,N′-bis(2-methylphenyl)-1,4-benzenediamine (DTPD) exhibited high bioaccumulation. Significant biodilution was only for benzothiazole, while DPPD DTPD displayed biomagnification trends based Monte Carlo simulations. mechanisms trophodynamics could be explained by chemical hydrophobicity, molecular mass, metabolic rates. Based a multicriteria scoring technique, DPPD, DTPD, 6PPD-Q as work emphasizes importance biomonitoring, particularly specific hydrophobic additives.

Language: Английский

Citations

32

Discovering Novel Organophosphorus Compounds in Wastewater Treatment Plant Effluents through Suspect Screening and Nontarget Analysis DOI
Jingrun Hu,

Yitao Lyu,

Mingzhen Li

et al.

Environmental Science & Technology, Journal Year: 2024, Volume and Issue: 58(14), P. 6402 - 6414

Published: March 28, 2024

Limited knowledge on the structure of emerging organophosphorus compounds (OPCs) hampers our comprehensive understanding their environmental occurrence and potential risks. Through suspect nontarget screening, combining data-dependent acquisition, data-independent parallel reaction monitoring modes, we identified 60 OPCs (17 traditional 43 compounds) in effluents 14 wastewater treatment plants (WWTPs) Beijing Qinghai, China. These comprise 26 organophosphate triesters, 17 diesters, 6 organophosphonates, 7 organothiophosphate esters, 4 other OPCs. Notably, were newly WWTP effluents, 16 discovered matrices. Specifically, cyclic phosphonate, (5-ethyl-2-methyl-1,3,2-dioxaphosphorinan-5-yl)methyl dimethyl phosphonate P-oxide (PMMMPn), consistently appeared all with semiquantitative concentrations ranging from 44.4 to 282 ng/L. Its analogue, di-PMMMPn, presented 93% samples. Compositional differences between two cities mainly attributed Hazard ecological risk assessment underscored substantial contribution chlorinated esters overall risks effluents. This study provides most OPC profiles date, highlighting need for further research occurrence, fate, risks, particularly

Language: Английский

Citations

16

Nontarget Identification of Novel Organophosphorus Flame Retardants and Plasticizers in Rainfall Runoffs and Agricultural Soils around a Plastic Recycling Industrial Park DOI
Xiaoxiao Li, Yiming Yao, Maosen Zhao

et al.

Environmental Science & Technology, Journal Year: 2023, Volume and Issue: 57(34), P. 12794 - 12805

Published: Aug. 14, 2023

Plastic recycling and reprocessing activities may release organophosphate ester (OPE) flame retardants plasticizers into the surrounding environment. However, relevant contamination profiles impacts remain not well studied. This study investigated occurrence of 28 OPEs their metabolites (mOPEs) in rainfall runoffs agricultural soils around one largest plastic industrial parks North China identified novel organophosphorus compounds (NOPs) using high-resolution mass spectrometry-based nontarget analysis. Twenty twenty-seven were detected runoff water soil samples, with total concentrations 86.0–2491 ng/L 2.53–199 ng/g dw, respectively. Thirteen NOPs identified, which eight reported environment for first time, including a chlorine-containing OPE, an heterocycle, phosphite, three OPE metabolites, two oligomers. Triphenylphosphine oxide diphenylphosphinic acid occurred ubiquitously soils, up to 390 40.2 The downwind areas park showed elevated levels NOPs. contribution hydroxylated mOPEs was higher than runoffs. These findings suggest that are significant sources biotransformation further increase ecological human exposure risk.

Language: Английский

Citations

24

Unveiling the existence and ecological hazards of trace organic pollutants in wastewater treatment plant effluents across China DOI Creative Commons
Jianchao Liu, Fang Yang,

Yuanfei Cai

et al.

Eco-Environment & Health, Journal Year: 2023, Volume and Issue: 3(1), P. 21 - 29

Published: Oct. 14, 2023

The presence of trace organic pollutants in the effluent wastewater treatment plants (WWTPs) poses considerable risks to aquatic organisms and human health. A large-scale survey 302 46 Chinese WWTPs was conducted gain an improved understanding their occurrence ecological risks. data showed that 216 compounds 11 chemical classes had been detected effluents. sum concentrations contaminants ranged from 1,392 ng/L 35,453 ng/L, with maximum concentration perfluoroalkyl substances (PFASs) recorded as highest (30,573 ng/L), which markedly less than reported 185,000 for 38 American WWTPs. bisphenol analogs (BPs) up 4,422 significantly higher those France, Germany, Japan, Korea, U.S. PFASs BPs were major pollutants, accounting 59% total pollution. Additionally, a 119 found have (RQ > 0.01). Among these, 23 1.0) warrant attention should be prioritized removal. This study lists valuable information controlling priority WWTP China.

Language: Английский

Citations

23

Synthesis of N-doped porous biochar from chemical pollutant for efficient sulfadiazine degradation: Performance, mechanism and bio-toxicity assessment DOI
Qiuyan Li, Fangyu Fu, Jiaying Yan

et al.

Separation and Purification Technology, Journal Year: 2024, Volume and Issue: 353, P. 128432 - 128432

Published: June 15, 2024

Language: Английский

Citations

14

Water Analysis: Emerging Contaminants and Current Issues DOI
Susan D. Richardson, Tarek Manasfi

Analytical Chemistry, Journal Year: 2024, Volume and Issue: 96(20), P. 8184 - 8219

Published: May 3, 2024

ADVERTISEMENT RETURN TO ISSUEPREVReviewNEXTWater Analysis: Emerging Contaminants and Current IssuesSusan D. Richardson*Susan RichardsonDepartment of Chemistry Biochemistry, University South Carolina, JM Palms Center for GSR, 631 Sumter Street, Columbia, Carolina 29208, United States*[email protected]More by Susan RichardsonView Biographyhttps://orcid.org/0000-0001-6207-4513 Tarek ManasfiTarek ManasfiEawag, Environmental Chemistry, Uberlandstrasse 133, Dubendorf 8600, SwitzerlandMore ManasfiView BiographyCite this: Anal. Chem. 2024, 96, 20, 8184–8219Publication Date (Web):May 3, 2024Publication History Received16 March 2024Accepted16 April 2024Revised14 2024Published online3 May inissue 21 2024https://pubs.acs.org/doi/10.1021/acs.analchem.4c01423https://doi.org/10.1021/acs.analchem.4c01423review-articleACS PublicationsCopyright © 2024 American Chemical SocietyRequest reuse permissionsArticle Views826Altmetric-Citations-LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum full text article downloads since November 2008 (both PDF HTML) across all institutions individuals. These metrics regularly updated to reflect usage leading up last few days.Citations number other articles citing this article, calculated Crossref daily. Find more information about citation counts.The Altmetric Attention Score is a quantitative measure attention that research has received online. Clicking on donut icon will load page at altmetric.com with additional details score social media presence given article. how calculated. Share Add toView InAdd Full Text ReferenceAdd Description ExportRISCitationCitation abstractCitation referencesMore Options onFacebookTwitterWechatLinked InRedditEmail Other access optionsGet e-Alertsclose SUBJECTS:Drinking water,Extraction,Impurities,Liquid chromatography,Mass spectrometry Get e-Alerts

Language: Английский

Citations

12

Contamination Status of Novel Organophosphate Esters Derived from Organophosphite Antioxidants in Soil and the Effects on Soil Bacterial Communities DOI
Meng Gao, Qiuyue Zhang,

Shanxing Wu

et al.

Environmental Science & Technology, Journal Year: 2024, Volume and Issue: 58(24), P. 10740 - 10751

Published: May 21, 2024

The contamination status of novel organophosphate esters (NOPEs) and their precursors organophosphite antioxidants (OPAs) hydroxylated/diester transformation products (OH-OPEs/di-OPEs) in soils across a large-scale area China were investigated. total concentrations the three test NOPEs soil 82.4–716 ng g–1, which considerably higher than those traditional OPEs (4.50–430 g–1), OPAs (n.d.–30.8 OH-OPEs (n.d.–0.49 di-OPEs (0.57–21.1 g–1). One NOPE compound, i.e., tris(2,4-di-tert-butylphenyl) phosphate (AO168 = O) contributed over 65% studied OPE-associated contaminants. A 30-day incubation experiment was performed to confirm influence AO168 O on bacterial communities. Specific genera belonging Proteobacteria, such as Lysobacter Ensifer, enriched O-contaminated soils. Moreover, ecological function methylotrophy observed be significantly enhanced (t-test, p < 0.01) treated with O, while nitrogen fixation inhibited 0.01). These findings comprehensively revealed contaminants environment provided first evidence effects microbial

Language: Английский

Citations

12

Unraveling the Pollution and Discharge of Aminophenyl Sulfone Compounds, Sulfonamide Antibiotics, and Their Acetylation Products in Municipal Wastewater Treatment Plants DOI

Yilin Xiao,

Qing Zhang, Yingying Yang

et al.

Environmental Science & Technology, Journal Year: 2024, Volume and Issue: 58(26), P. 11695 - 11706

Published: June 15, 2024

Aminophenyl sulfone compounds (ASCs) are widely used in various fields, such as the pharmaceutical and textile industries. ASCs their primary acetylation products inevitably discharged into environment. However, high toxicity of could be released from deacetylation products. Still, occurrence ecological risks remain largely unknown. Here, we integrated all existing based on core structure, together with potential products, to establish a database covering 1105 compounds. By combining R programming, 45 ASCs, sulfonamides, were identified influent effluent 19 municipal wastewater treatment plants 4 cities China. 13 them detected for first time aquatic environment, 12 newly identified. The cumulative concentrations range 231-9.96 × 10

Language: Английский

Citations

11

Percarbonate activation catalyzed by nanoblocks of basic copper molybdate for antibiotics degradation: High performance, degradation pathways and mechanism DOI

Xiao‐Tao Jin,

Yanlan Wang, Yingping Huang

et al.

Chinese Chemical Letters, Journal Year: 2024, Volume and Issue: 35(10), P. 109499 - 109499

Published: Jan. 10, 2024

Language: Английский

Citations

9

Catalytic wastewater dephosphorization for phosphorus recycling to fertilizers DOI Creative Commons

Zhangli Li,

Xiang Liu, Jiaying Yan

et al.

Applied Catalysis B Environment and Energy, Journal Year: 2025, Volume and Issue: unknown, P. 125154 - 125154

Published: Feb. 1, 2025

Language: Английский

Citations

1