ACS Applied Nano Materials, Journal Year: 2025, Volume and Issue: unknown
Published: March 19, 2025
Language: Английский
ACS Applied Nano Materials, Journal Year: 2025, Volume and Issue: unknown
Published: March 19, 2025
Language: Английский
Journal of environmental chemical engineering, Journal Year: 2024, Volume and Issue: 12(2), P. 111950 - 111950
Published: Jan. 17, 2024
Language: Английский
Citations
25iScience, Journal Year: 2024, Volume and Issue: 27(2), P. 108993 - 108993
Published: Jan. 23, 2024
The rapid development of nuclear energy posed a great threat to the environment and human health. Herein, two hydroxyl-functionalized hyper-crosslinked polymers (PIHCP-1 PIHCP-2) containing different electron active sites have been synthesized via Friedel-Crafts alkylation reaction polyimides. resulting showed micro/mesoporous morphology good thermal chemical stability. Rely on high porosity multi-active sites, PIHCPs show an ultrahigh iodine uptake capacity reached 6.73 g g−1 removal efficiency from aqueous solution also reaches 99.7%. Kinetic analysis demonstrates that adsorption was happened heterogeneous surfaces in form multilayer chemisorption. Electrostatic potential (ESP) calculation proves contribution hydroxyl groups capture performance. In addition, both adsorbents can be maintained over 91% after four cyclic experiments which ensures their recyclability for further practical applications.
Language: Английский
Citations
20International Journal of Biological Macromolecules, Journal Year: 2025, Volume and Issue: 294, P. 139412 - 139412
Published: Jan. 5, 2025
Language: Английский
Citations
2Separation and Purification Technology, Journal Year: 2023, Volume and Issue: 332, P. 125771 - 125771
Published: Nov. 22, 2023
Language: Английский
Citations
30Process Safety and Environmental Protection, Journal Year: 2023, Volume and Issue: 174, P. 770 - 777
Published: April 29, 2023
Language: Английский
Citations
27Journal of Hazardous Materials, Journal Year: 2024, Volume and Issue: 465, P. 133488 - 133488
Published: Jan. 10, 2024
Language: Английский
Citations
14Colloids and Surfaces A Physicochemical and Engineering Aspects, Journal Year: 2024, Volume and Issue: 699, P. 134658 - 134658
Published: June 28, 2024
Language: Английский
Citations
13Journal of environmental chemical engineering, Journal Year: 2024, Volume and Issue: 12(2), P. 112279 - 112279
Published: Feb. 20, 2024
Language: Английский
Citations
10Chemistry Africa, Journal Year: 2025, Volume and Issue: unknown
Published: Jan. 24, 2025
Language: Английский
Citations
1ACS Applied Materials & Interfaces, Journal Year: 2025, Volume and Issue: unknown
Published: Jan. 29, 2025
Sulfur dioxide (SO2), a pervasive air pollutant, poses significant environmental and health risks, necessitating advanced materials for its efficient capture. Nanoporous organic polymers (NOPs) have emerged as promising candidates; however, their development is often hindered by high synthesis temperatures, complex precursors, limited SO2 selectivity. Herein, we report room-temperature, cost-effective of carbazole-based nanoporous (CNOPs) using 1,3,5-trioxane paraldehyde, offering advancement over traditional Friedel-Crafts alkylation methods. The resulting CNOPs exhibit surface area up to 842 m2·g-1 feature ultramicroporous structures optimized adsorption. At 298 K 1 bar, the demonstrated adsorption capacities 9.39 mmol·g-1. Ideal adsorbed solution theory (IAST) calculations revealed outstanding selectivities 105 SO2/CO2 6139 SO2/N2 mixtures, supported breakthrough experiments demonstrating superior separation performance. This work not only provides straightforward synthetic route but also offers valuable insights into design porous tailored enhanced capture, addressing critical challenges.
Language: Английский
Citations
1