Yolk-shell Bi2O3/Bi2O2CO3 heterojunction for enhanced CO2 electroreduction into formate DOI
Jianzhong Xu, Yun‐Xiang Ma,

Yanli Zhao

et al.

Science China Chemistry, Journal Year: 2024, Volume and Issue: unknown

Published: Nov. 11, 2024

Language: Английский

Well-constructed CeO2-coated CuBi2O4 heterojunction: Enhanced charge carriers transportation DOI
Chenglin Zhang, Su Zhan, Feng Zhou

et al.

Surfaces and Interfaces, Journal Year: 2025, Volume and Issue: unknown, P. 105921 - 105921

Published: Jan. 1, 2025

Language: Английский

Citations

2
High-selectivity electroreduction of low-concentration CO2 with large concentration fluctuation DOI

M. Qi,

Yanbin Ma,

Chao Zhang

et al.

Science China Chemistry, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 2, 2025

Language: Английский

Citations

1
Tuning strategies and electrolyzer design for Bi-based nanomaterials towards efficient CO2 reduction to formic acid DOI
Di Wang, Qingsong Chen,

Yiran Lin

et al.

Chinese Journal of Structural Chemistry, Journal Year: 2024, Volume and Issue: 43(8), P. 100346 - 100346

Published: May 21, 2024

Language: Английский

Citations

6
Porous Bi Nanosheets Derived from β-Bi2O3 for Efficient Electrocatalytic CO2 Reduction to Formate DOI

Yongyu Pang,

Ruikuan Xie,

Huan Xie

et al.

ACS Applied Materials & Interfaces, Journal Year: 2024, Volume and Issue: 16(32), P. 42109 - 42117

Published: Aug. 1, 2024

The electrochemical CO2 reduction reaction (ECO2RR) is a promising strategy for converting into high-value chemical products. However, the synthesis of effective and stable electrocatalysts capable transforming specified product remains huge challenge. Herein, we report template-regulated preparation Bi2O3-derived nanosheet catalyst with abundant porosity to achieve expectantly efficient CO2-to-formate conversion. resultant porous bismuth (p-Bi) not only exhibited marked Faradaic efficiency formate (FEformate), beyond 91% in broad potential range from −0.75 −1.1 V H-type cell, but also demonstrated an appreciable FEformate 94% at high current density 262 mA cm–2 commercially important gas diffusion cell. State-of-the-art X-ray absorption near edge structure spectroscopy (XANES) theoretical calculation unraveled distinct production performance p-Bi catalyst, which was cocontributed by its smaller size, plentiful structure, stronger Bi–O bond, thus accelerating promoting subsequent formation intermediates. This work provides avenue fabricate bismuth-based catalysts planar morphologies portfolio applications.

Language: Английский

Citations

5
Advances and challenges about Ni-based dual functional materials for alternating cycles of CO2 storage and in-situ hydrogenation to CH4 DOI Creative Commons

Xinyue Su,

Laihong Shen

Carbon Capture Science & Technology, Journal Year: 2024, Volume and Issue: 13, P. 100278 - 100278

Published: Aug. 30, 2024

Language: Английский

Citations

4
Catalyst Design and Engineering for CO2‐to‐Formic Acid Electrosynthesis for a Low‐Carbon Economy DOI

Karthik Peramaiah,

Moyu Yi,

Indranil Dutta

et al.

Advanced Materials, Journal Year: 2024, Volume and Issue: unknown

Published: Oct. 12, 2024

Abstract Formic acid (FA) has emerged as a promising candidate for hydrogen energy storage due to its favorable properties such low toxicity, flammability, and high volumetric capacity under ambient conditions. Recent analyses have suggested that FA produced by electrochemical carbon dioxide (CO 2 ) reduction reaction (eCO RR) using low‐carbon electricity exhibits lower fugitive (H emissions global warming potential (GWP) during the H carrier production, transportation processes compared those of other alternatives like methanol, methylcyclohexane, ammonia. eCO RR can enable industrially relevant current densities without need pressures, temperatures, or auxiliary sources. However, widespread implementation is hindered requirement highly stable selective catalysts. Herein, aim explore evaluate catalyst engineering in designing nanostructured catalysts facilitate economically viable production FA.

Language: Английский

Citations

4
Boron-Doped Oxidized Carbon Black Hybridizing Bismuth Oxide for Electrocatalytic CO2 to Formate at a Large Current Density DOI
Yujie Cao, Xiaoling Liu,

Mingdong Sun

et al.

Industrial & Engineering Chemistry Research, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 12, 2025

Language: Английский

Citations

0
Electrochemical CO2 Reduction Technology Toward Practical Application: Status Quo and Challenges DOI

Ziye Cheng,

D. Lu,

Jiayi Chen

et al.

ChemistrySelect, Journal Year: 2025, Volume and Issue: 10(7)

Published: Feb. 1, 2025

Abstract Electrochemical CO 2 reduction (denoted as ECO R) technology is expected to transform greenhouse gas into a range of fuels and chemicals combined with renewable electricity. A wide fundamental research has been dedicated the clarification reaction mechanisms developing catalyst materials, which have significantly facilitated level R technology. Nevertheless, still encounters limitations such low utilization efficiency insufficient selectivity high‐value products. Addressing these challenges crucial for be implemented in practical applications. In an electrolysis system, electrolyzer represents core component system primary site. Therefore, composition structure will directly affect performance. This review begins by outlining recent progress at large‐scale level, followed comprehensive analysis industrial configuration, including detailed considerations electrode, diffusion layer, membrane electrolyzer. Finally, we elucidate remaining associated industrialization this offer suggestions advancing it.

Language: Английский

Citations

0
Integrated CO2 capture and electrochemical reduction: From mechanism understanding to gas diffusion electrode and catalyst design DOI

Xinyu Zhang,

Ming Zhu Sun, Yao Wang

et al.

Journal of Energy Chemistry, Journal Year: 2025, Volume and Issue: unknown

Published: March 1, 2025

Language: Английский

Citations

0
Cubi Nanosheets from In-Situ Topotactic Transformation for Efficient Electrocatalytic Co2 Reduction to Formate DOI
Guowu Zhan, Lirong Zhong, Wendong Wang

et al.

Published: Jan. 1, 2025

Language: Английский

Citations

0