Green Chemistry,
Journal Year:
2024,
Volume and Issue:
26(10), P. 5708 - 5743
Published: Jan. 1, 2024
Bio-upcycling
of
monomers
recovered
from
poly(ethylene
terephthalate)
(PET)
waste
is
a
novel
alternative
to
turn
recycling
process
more
economically
attractive
by
obtaining
several
products
with
higher
added
value.
Polymers,
Journal Year:
2025,
Volume and Issue:
17(5), P. 628 - 628
Published: Feb. 26, 2025
The
growing
environmental
impact
of
textile
waste,
fueled
by
the
rapid
rise
in
global
fiber
production,
underscores
urgent
need
for
sustainable
end-of-life
solutions.
This
review
explores
cutting-edge
pathways
waste
management,
spotlighting
innovations
that
reduce
reliance
on
incineration
and
landfilling
while
driving
material
circularity.
It
highlights
advancements
collection,
sorting,
pretreatment
technologies,
as
well
both
established
emerging
recycling
methods.
Smart
collection
systems
utilizing
tags
sensors
show
great
promise
streamlining
logistics
automating
pick-up
routes
transactions.
For
automated
technologies
like
near-infrared
hyperspectral
imaging
lead
way
accurate
scalable
separation.
Automated
disassembly
techniques
are
effective
at
removing
problematic
elements,
though
other
pretreatments,
such
color
finish
removal,
still
to
be
customized
specific
streams.
Mechanical
is
ideal
textiles
with
strong
mechanical
properties
but
has
limitations,
particularly
blended
fabrics,
cannot
repeated
endlessly.
Polymer
recycling-through
melting
or
dissolving
polymers-produces
higher-quality
recycled
materials
comes
high
energy
solvent
demands.
Chemical
recycling,
especially
solvolysis
pyrolysis,
excels
breaking
down
synthetic
polymers
polyester,
potential
yield
virgin-quality
monomers.
Meanwhile,
biological
methods,
their
infancy,
natural
fibers
cotton
wool.
When
methods
not
viable,
gasification
can
used
convert
into
synthesis
gas.
concludes
future
hinges
integrating
sorting
advancing
solvent-based
chemical
technologies.
These
innovations,
supported
eco-design
principles,
progressive
policies,
industry
collaboration,
essential
building
a
resilient,
circular
economy.
Materials,
Journal Year:
2021,
Volume and Issue:
14(17), P. 4782 - 4782
Published: Aug. 24, 2021
Today,
the
scientific
community
is
facing
crucial
challenges
in
delivering
a
healthier
world
for
future
generations.
Among
these,
quest
circular
and
sustainable
approaches
plastic
recycling
one
of
most
demanding
several
reasons.
Indeed,
massive
use
materials
over
last
century
has
generated
large
amounts
long-lasting
waste,
which,
much
time,
not
been
object
adequate
recovery
disposal
politics.
Most
this
waste
by
packaging
materials.
Nevertheless,
decade,
new
trend
imposed
environmental
concerns
brought
topic
under
magnifying
glass,
as
testified
increasing
number
related
publications.
Several
methods
have
proposed
polymeric
based
on
chemical
or
mechanical
methods.
A
panorama
promising
studies
to
polyethylene
(PE),
polypropylene
(PP),
terephthalate
(PET),
polystyrene
(PS)
given
within
review.
Green Chemistry,
Journal Year:
2021,
Volume and Issue:
23(19), P. 7330 - 7360
Published: Jan. 1, 2021
Reductive
depolymerization
allows
the
valorization
of
polyester,
polycarbonate
and
polyamide
waste
in
a
wide
variety
value-added
compounds
with
good
yields
ACS Sustainable Chemistry & Engineering,
Journal Year:
2022,
Volume and Issue:
10(24), P. 7965 - 7973
Published: June 8, 2022
Due
to
the
antibiodegradable
properties,
numerous
plastics
have
been
accumulated
in
ecosystem
and
aggravate
ecological
pollution.
Poly
(ethylene
terephthalate)
(PET)
is
among
most
used
plastics.
Glycolysis
of
PET
a
useful
approach
solve
waste
pollution
obtain
bis(2-hydroxyethyl)
terephthalate
(BHET).
In
this
paper,
was
efficiently
depolymerized
through
glycolysis
catalyzed
by
cyanamide.
particular,
compared
with
previously
reported
catalyst,
cyanamide
more
readily
available
can
be
directly
catalysis
without
complex
preparation
process.
Under
optimal
conditions,
completely
up
nearly
100%
BHET
yield.
Even
at
temperature
as
low
150
°C,
good
yield
obtained.
The
application
potential
procedure
demonstrated
its
excellent
performance
various
real
wastes
like
transparent
opaque
samples
polyester
foam
high
quality
obtained
products.
mechanism
studied
1H
NMR
analysis,
DFT
calculations
showed
that
higher
activity
than
trimer,
melamine,
due
stronger
hydrogen
bonds
formed
between
or
ethylene
glycol.
Green Chemistry,
Journal Year:
2022,
Volume and Issue:
24(8), P. 3284 - 3292
Published: Jan. 1, 2022
Selective
degradation
and
facile
separation
of
PET
wastes
are
achieved
using
EG
as
both
reactant
solvent
to
simply
the
THF
cosolvent
improve
mass
transfer,
promote
activity
reduce
solubility
product.
ACS Sustainable Chemistry & Engineering,
Journal Year:
2022,
Volume and Issue:
10(51), P. 17261 - 17273
Published: Nov. 23, 2022
In
this
work,
we
developed
a
new
catalytic
method
of
glycolysis
to
efficiently
convert
post-consumer
polyethylene
terephthalate
(PET)
into
bis(2-hydroxyethyl)
(BHET).
The
addition
an
aromatic
compound
possessing
the
alkoxy
group
(e.g.,
anisole)
reaction
system
facilitated
conversion
PET
BHET
at
temperature
near
153
°C,
which
is
much
lower
than
that
without
co-solvent
(>197
°C),
while
overall
performance
remains
almost
unchanged.
We
found
inexpensive
metal
salt
or
organic
guanidine
base
could
be
used
as
effective
catalyst
for
low-temperature
glycolysis.
Under
optimal
conditions
catalyzed
by
alkali
(Na
K)
acetate,
completely
decomposed
in
2
h
with
yield
86%.
also
investigated
detailed
behaviors
and
possible
intermolecular
interactions
between
anisole
other
chemical
species
facilitate
Based
on
experimental
results,
most
probable
steps
were
proposed
kinetic
model
mechanistically
describing
behavior
was
developed.
estimated
apparent
activation
energy
decomposition
co-solvent-assisted
low
value
80.9
kJ
mol–1,
responsible
high
reactivity
even
co-solvent.
EES Catalysis,
Journal Year:
2023,
Volume and Issue:
1(4), P. 413 - 433
Published: Jan. 1, 2023
Recent
progresses
of
value-added
electrolysis
that
replace
OER
with
anodic
reactions.
Representation
the
elements:
hydrogen
(white
color),
carbon
(gray),
oxygen
(red),
nitrogen
(blue),
and
iodine
(magenta).