From trash to cash: current strategies for bio-upcycling of recaptured monomeric building blocks from poly(ethylene terephthalate) (PET) waste DOI
Adriano Carniel, Nathália Ferreira dos Santos, Filipe Smith Buarque

et al.

Green Chemistry, Journal Year: 2024, Volume and Issue: 26(10), P. 5708 - 5743

Published: Jan. 1, 2024

Bio-upcycling of monomers recovered from poly(ethylene terephthalate) (PET) waste is a novel alternative to turn recycling process more economically attractive by obtaining several products with higher added value.

Language: Английский

Advancing Textile Waste Recycling: Challenges and Opportunities Across Polymer and Non-Polymer Fiber Types DOI Open Access
Mehrdad Seifali Abbas‐Abadi, Brecht Tomme, Bahman Goshayeshi

et al.

Polymers, Journal Year: 2025, Volume and Issue: 17(5), P. 628 - 628

Published: Feb. 26, 2025

The growing environmental impact of textile waste, fueled by the rapid rise in global fiber production, underscores urgent need for sustainable end-of-life solutions. This review explores cutting-edge pathways waste management, spotlighting innovations that reduce reliance on incineration and landfilling while driving material circularity. It highlights advancements collection, sorting, pretreatment technologies, as well both established emerging recycling methods. Smart collection systems utilizing tags sensors show great promise streamlining logistics automating pick-up routes transactions. For automated technologies like near-infrared hyperspectral imaging lead way accurate scalable separation. Automated disassembly techniques are effective at removing problematic elements, though other pretreatments, such color finish removal, still to be customized specific streams. Mechanical is ideal textiles with strong mechanical properties but has limitations, particularly blended fabrics, cannot repeated endlessly. Polymer recycling-through melting or dissolving polymers-produces higher-quality recycled materials comes high energy solvent demands. Chemical recycling, especially solvolysis pyrolysis, excels breaking down synthetic polymers polyester, potential yield virgin-quality monomers. Meanwhile, biological methods, their infancy, natural fibers cotton wool. When methods not viable, gasification can used convert into synthesis gas. concludes future hinges integrating sorting advancing solvent-based chemical technologies. These innovations, supported eco-design principles, progressive policies, industry collaboration, essential building a resilient, circular economy.

Language: Английский

Citations

2

Recent Advancements in Plastic Packaging Recycling: A Mini-Review DOI Open Access
Valentina Beghetto, Roberto Sole,

Chiara Buranello

et al.

Materials, Journal Year: 2021, Volume and Issue: 14(17), P. 4782 - 4782

Published: Aug. 24, 2021

Today, the scientific community is facing crucial challenges in delivering a healthier world for future generations. Among these, quest circular and sustainable approaches plastic recycling one of most demanding several reasons. Indeed, massive use materials over last century has generated large amounts long-lasting waste, which, much time, not been object adequate recovery disposal politics. Most this waste by packaging materials. Nevertheless, decade, new trend imposed environmental concerns brought topic under magnifying glass, as testified increasing number related publications. Several methods have proposed polymeric based on chemical or mechanical methods. A panorama promising studies to polyethylene (PE), polypropylene (PP), terephthalate (PET), polystyrene (PS) given within review.

Language: Английский

Citations

103

Electrocatalytic reforming of waste plastics into high value-added chemicals and hydrogen fuel DOI
Rui Shi,

Kesheng Liu,

Fulai Liu

et al.

Chemical Communications, Journal Year: 2021, Volume and Issue: 57(94), P. 12595 - 12598

Published: Jan. 1, 2021

We report an electroreforming strategy to upcycle waste PET into value-added chemicals and H 2 using Pd as the anode Ni foam cathode.

Language: Английский

Citations

82

Reductive depolymerization as an efficient methodology for the conversion of plastic waste into value-added compounds DOI
Ana C. Fernandes

Green Chemistry, Journal Year: 2021, Volume and Issue: 23(19), P. 7330 - 7360

Published: Jan. 1, 2021

Reductive depolymerization allows the valorization of polyester, polycarbonate and polyamide waste in a wide variety value-added compounds with good yields

Language: Английский

Citations

74

Recycling of polyethylene terephthalate (PET Or PETE) plastics – An alternative to obtain value added products: A review DOI Open Access
Khodidas K. Bhanderi, Jeimin R. Joshi, Jigar V. Patel

et al.

Journal of the Indian Chemical Society, Journal Year: 2022, Volume and Issue: 100(1), P. 100843 - 100843

Published: Dec. 6, 2022

Language: Английский

Citations

53

Cyanamide as a Highly Efficient Organocatalyst for the Glycolysis Recycling of PET DOI
Zishuai Wang,

Yu Jin,

Yaoqiang Wang

et al.

ACS Sustainable Chemistry & Engineering, Journal Year: 2022, Volume and Issue: 10(24), P. 7965 - 7973

Published: June 8, 2022

Due to the antibiodegradable properties, numerous plastics have been accumulated in ecosystem and aggravate ecological pollution. Poly (ethylene terephthalate) (PET) is among most used plastics. Glycolysis of PET a useful approach solve waste pollution obtain bis(2-hydroxyethyl) terephthalate (BHET). In this paper, was efficiently depolymerized through glycolysis catalyzed by cyanamide. particular, compared with previously reported catalyst, cyanamide more readily available can be directly catalysis without complex preparation process. Under optimal conditions, completely up nearly 100% BHET yield. Even at temperature as low 150 °C, good yield obtained. The application potential procedure demonstrated its excellent performance various real wastes like transparent opaque samples polyester foam high quality obtained products. mechanism studied 1H NMR analysis, DFT calculations showed that higher activity than trimer, melamine, due stronger hydrogen bonds formed between or ethylene glycol.

Language: Английский

Citations

52

Cosolvent-promoted selective non-aqueous hydrolysis of PET wastes and facile product separation DOI
Shun Zhang, Wenhao Xu,

Rongcheng Du

et al.

Green Chemistry, Journal Year: 2022, Volume and Issue: 24(8), P. 3284 - 3292

Published: Jan. 1, 2022

Selective degradation and facile separation of PET wastes are achieved using EG as both reactant solvent to simply the THF cosolvent improve mass transfer, promote activity reduce solubility product.

Language: Английский

Citations

45

Low-Temperature Glycolysis of Polyethylene Terephthalate DOI

Ngan Hong Le,

Tran Thi Ngoc Van, Bonggeun Shong

et al.

ACS Sustainable Chemistry & Engineering, Journal Year: 2022, Volume and Issue: 10(51), P. 17261 - 17273

Published: Nov. 23, 2022

In this work, we developed a new catalytic method of glycolysis to efficiently convert post-consumer polyethylene terephthalate (PET) into bis(2-hydroxyethyl) (BHET). The addition an aromatic compound possessing the alkoxy group (e.g., anisole) reaction system facilitated conversion PET BHET at temperature near 153 °C, which is much lower than that without co-solvent (>197 °C), while overall performance remains almost unchanged. We found inexpensive metal salt or organic guanidine base could be used as effective catalyst for low-temperature glycolysis. Under optimal conditions catalyzed by alkali (Na K) acetate, completely decomposed in 2 h with yield 86%. also investigated detailed behaviors and possible intermolecular interactions between anisole other chemical species facilitate Based on experimental results, most probable steps were proposed kinetic model mechanistically describing behavior was developed. estimated apparent activation energy decomposition co-solvent-assisted low value 80.9 kJ mol–1, responsible high reactivity even co-solvent.

Language: Английский

Citations

45

Electrocatalysts for value-added electrolysis coupled with hydrogen evolution DOI Creative Commons
Endalkachew Asefa Moges, Chia‐Yu Chang, Meng‐Che Tsai

et al.

EES Catalysis, Journal Year: 2023, Volume and Issue: 1(4), P. 413 - 433

Published: Jan. 1, 2023

Recent progresses of value-added electrolysis that replace OER with anodic reactions. Representation the elements: hydrogen (white color), carbon (gray), oxygen (red), nitrogen (blue), and iodine (magenta).

Language: Английский

Citations

36

Design and synthesis of functional materials by chemical recycling of waste polyethylene terephthalate (PET) plastic: Opportunities and challenges DOI
Kayee Chan, Anatoly Zinchenko

Journal of Cleaner Production, Journal Year: 2023, Volume and Issue: 433, P. 139828 - 139828

Published: Nov. 20, 2023

Language: Английский

Citations

35