Architecting Metal–Organic Frameworks at Molecular Level toward Direct Air Capture DOI
Zi‐Ming Ye, Yi Xie, Kent O. Kirlikovali

et al.

Journal of the American Chemical Society, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 7, 2025

Escalating carbon dioxide (CO2) emissions have intensified the greenhouse effect, posing a significant long-term threat to environmental sustainability. Direct air capture (DAC) has emerged as promising approach achieving net-zero future, which offers several practical advantages, such independence from specific CO2 emission sources, economic feasibility, flexible deployment, and minimal risk of leakage. The design optimization DAC sorbents are crucial for accelerating industrial adoption. Metal-organic frameworks (MOFs), with high structural order tunable pore sizes, present an ideal solution strong guest-host interactions under trace conditions. This perspective highlights recent advancements in using MOFs DAC, examines molecular-level effects water vapor on capture, reviews data-driven computational screening methods develop molecularly programmable MOF platform identifying optimal sorbents, discusses scale-up cost DAC.

Language: Английский

Metal–phenolic network composites: from fundamentals to applications DOI Creative Commons
Zhixing Lin, Hai Liu, Joseph J. Richardson

et al.

Chemical Society Reviews, Journal Year: 2024, Volume and Issue: 53(22), P. 10800 - 10826

Published: Jan. 1, 2024

This review provides a guideline for the rational design of metal–phenolic network (MPN) composites—which are fabricated from MPN and one or more functional components ( e.g. , drugs, proteins)—for various applications across diverse disciplines.

Language: Английский

Citations

18

The Road Ahead for Metal–Organic Frameworks: Current Landscape, Challenges and Future Prospects DOI
Michael L. Barsoum, Kira M. Fahy, William Morris

et al.

ACS Nano, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 3, 2025

This perspective highlights the transformative potential of Metal-Organic Frameworks (MOFs) in environmental and healthcare sectors. It discusses work that has advanced beyond technology readiness levels >4 including applications capture, storage, conversion gases to value added products. showcases efforts most salient MOFs which have been performed at a great cadence, enabled by federal government, large companies, startups commercialize these technologies despite facing significant challenges. article also forecasts role nanoscale healthcare, strides toward personalized medicine, advocating for their use custom-tailored drug delivery systems. Finally we underscore acceleration MOF research development through integration machine learning AI, positioning as versatile tools poised address global sustainability health

Language: Английский

Citations

5

Large language models for reticular chemistry DOI
Zhiling Zheng, Nakul Rampal,

Theo Jaffrelot Inizan

et al.

Nature Reviews Materials, Journal Year: 2025, Volume and Issue: unknown

Published: Jan. 31, 2025

Language: Английский

Citations

4

MOF membranes for gas separations DOI
Yiming Zhang, Hang Yin,

Lingzhi Huang

et al.

Progress in Materials Science, Journal Year: 2025, Volume and Issue: unknown, P. 101432 - 101432

Published: Jan. 1, 2025

Citations

3

Architecting Metal–Organic Frameworks at Molecular Level toward Direct Air Capture DOI
Zi‐Ming Ye, Yi Xie, Kent O. Kirlikovali

et al.

Journal of the American Chemical Society, Journal Year: 2025, Volume and Issue: unknown

Published: Feb. 7, 2025

Escalating carbon dioxide (CO2) emissions have intensified the greenhouse effect, posing a significant long-term threat to environmental sustainability. Direct air capture (DAC) has emerged as promising approach achieving net-zero future, which offers several practical advantages, such independence from specific CO2 emission sources, economic feasibility, flexible deployment, and minimal risk of leakage. The design optimization DAC sorbents are crucial for accelerating industrial adoption. Metal-organic frameworks (MOFs), with high structural order tunable pore sizes, present an ideal solution strong guest-host interactions under trace conditions. This perspective highlights recent advancements in using MOFs DAC, examines molecular-level effects water vapor on capture, reviews data-driven computational screening methods develop molecularly programmable MOF platform identifying optimal sorbents, discusses scale-up cost DAC.

Language: Английский

Citations

2