Global Biogeochemical Cycles,
Journal Year:
2024,
Volume and Issue:
38(9)
Published: Sept. 1, 2024
Abstract
This
paper
aims
to
study
the
changes
in
Indian
Ocean
seawater
pH
response
sea‐surface
temperature,
salinity,
dissolved
inorganic
carbon
(DIC),
and
total
alkalinity
(ALK)
over
period
1980–2019
its
driving
mechanisms
using
a
high‐resolution
regional
model
outputs.
The
analysis
indicates
that
rate
of
change
declining
Arabian
Sea
(AS),
Bay
Bengal
(BoB),
Equatorial
(EIO)
is
−0.014
0.002,
0.001,
−0.015
0.001
unit
dec
−1
,
respectively.
Both
AS
BoB
(EIO),
highest
(lowest)
decadal
DIC
trend
found
during
2000–2009.
surface
acidification
has
accelerated
throughout
IO
region
2010–2019
compared
previous
decades.
Further,
our
El
Ninõ
positive
Dipole
events
lead
an
enhancement
acidification.
increasing
anthropogenic
CO
2
uptake
by
ocean
dominantly
controls
80%
(94.5%
85.7%)
net
(1980–2019)
(BoB
EIO),
whereas
warming
14.4%
(13.4%
7.0%)
trends
EIO).
ALK
contribute
enhancing
5.0%.
dominates
after
EIO
and,
similar
AS,
contributes
negative
10.7%.
In
contrast,
it
buffering
effect
BoB,
suppressing
−5.4%.
Earth system science data,
Journal Year:
2023,
Volume and Issue:
15(12), P. 5301 - 5369
Published: Nov. 30, 2023
Abstract.
Accurate
assessment
of
anthropogenic
carbon
dioxide
(CO2)
emissions
and
their
redistribution
among
the
atmosphere,
ocean,
terrestrial
biosphere
in
a
changing
climate
is
critical
to
better
understand
global
cycle,
support
development
policies,
project
future
change.
Here
we
describe
synthesize
data
sets
methodology
quantify
five
major
components
budget
uncertainties.
Fossil
CO2
(EFOS)
are
based
on
energy
statistics
cement
production
data,
while
from
land-use
change
(ELUC),
mainly
deforestation,
bookkeeping
models.
Atmospheric
concentration
measured
directly,
its
growth
rate
(GATM)
computed
annual
changes
concentration.
The
ocean
sink
(SOCEAN)
estimated
with
biogeochemistry
models
observation-based
fCO2
products.
(SLAND)
dynamic
vegetation
Additional
lines
evidence
land
sinks
provided
by
atmospheric
inversions,
oxygen
measurements,
Earth
system
resulting
imbalance
(BIM),
difference
between
total
biosphere,
measure
imperfect
incomplete
understanding
contemporary
cycle.
All
uncertainties
reported
as
±1σ.
For
year
2022,
EFOS
increased
0.9
%
relative
2021,
fossil
at
9.9±0.5
Gt
C
yr−1
(10.2±0.5
when
carbonation
not
included),
ELUC
was
1.2±0.7
yr−1,
for
emission
(including
sink)
11.1±0.8
(40.7±3.2
yr−1).
Also,
GATM
4.6±0.2
(2.18±0.1
ppm
yr−1;
denotes
parts
per
million),
SOCEAN
2.8±0.4
SLAND
3.8±0.8
BIM
−0.1
(i.e.
sources
marginally
too
low
or
high).
averaged
over
2022
reached
417.1±0.1
ppm.
Preliminary
2023
suggest
an
increase
+1.1
(0.0
2.1
%)
globally
reaching
419.3
ppm,
51
above
pre-industrial
level
(around
278
1750).
Overall,
mean
trend
consistently
period
1959–2022,
near-zero
overall
imbalance,
although
discrepancies
up
around
1
persist
representation
semi-decadal
variability
fluxes.
Comparison
estimates
multiple
approaches
observations
shows
following:
(1)
persistent
large
uncertainty
estimate
emissions,
(2)
agreement
different
methods
magnitude
flux
northern
extra-tropics,
(3)
discrepancy
strength
last
decade.
This
living-data
update
documents
applied
this
most
recent
well
evolving
community
presented
work
available
https://doi.org/10.18160/GCP-2023
(Friedlingstein
et
al.,
2023).
Global Biogeochemical Cycles,
Journal Year:
2023,
Volume and Issue:
37(10)
Published: Sept. 11, 2023
Abstract
This
contribution
to
the
RECCAP2
(REgional
Carbon
Cycle
Assessment
and
Processes)
assessment
analyzes
processes
that
determine
global
ocean
carbon
sink,
its
trends
variability
over
period
1985–2018,
using
a
combination
of
models
observation‐based
products.
The
mean
sea‐air
CO
2
flux
from
1985
2018
is
−1.6
±
0.2
PgC
yr
−1
based
on
an
ensemble
reconstructions
history
sea
surface
pCO
(pCO
products).
Models
indicate
dominant
component
this
net
oceanic
uptake
anthropogenic
,
which
estimated
at
−2.1
0.3
by
biogeochemical
models,
−2.4
0.1
two
circulation
inverse
models.
also
degasses
about
0.65
terrestrially
derived
but
process
not
fully
resolved
any
used
here.
From
2001
2018,
products
reconstruct
trend
in
sink
−0.61
0.12
decade
while
diagnose
‐driven
−0.34
0.06
−0.41
0.03
respectively.
implies
climate‐forced
acceleration
recent
decades,
there
are
still
large
uncertainties
magnitude
cause
trend.
interannual
decadal
mainly
driven
climate
variability,
with
climate‐driven
exceeding
‐forced
2–3
times.
These
results
suggest
dominates
potentially
highly
uncertain
consistently
captured
across
different
methods.
Earth system science data,
Journal Year:
2024,
Volume and Issue:
16(4), P. 2047 - 2072
Published: April 30, 2024
Abstract.
The
Global
Ocean
Data
Analysis
Project
(GLODAP)
is
a
synthesis
effort
providing
regular
compilations
of
surface
to
bottom
ocean
biogeochemical
bottle
data,
with
an
emphasis
on
seawater
inorganic
carbon
chemistry
and
related
variables
determined
through
chemical
analysis
samples.
GLODAPv2.2023
update
the
previous
version,
GLODAPv2.2022
(Lauvset
et
al.,
2022).
major
changes
are
as
follows:
data
from
23
new
cruises
were
added.
In
addition,
number
made
included
in
GLODAPv2.2022.
includes
measurements
more
than
1.4
million
water
samples
global
oceans
collected
1108
cruises.
for
now
13
GLODAP
core
(salinity,
oxygen,
nitrate,
silicate,
phosphate,
dissolved
carbon,
total
alkalinity,
pH,
chlorofluorocarbon-11
(CFC-11),
CFC-12,
CFC-113,
CCl4,
SF6)
have
undergone
extensive
quality
control
focus
systematic
evaluation
bias.
available
two
formats:
(i)
submitted
by
originator
but
converted
World
Circulation
Experiment
(WOCE)
exchange
format
(ii)
merged
product
adjustments
applied
minimize
For
present
annual
update,
derived
comparing
those
1085
quality-controlled
using
crossover
analysis.
SF6
all
evaluated
comparison
CFC-12
measured
same
nutrients
dioxide
(CO2),
comparisons
estimates
based
empirical
algorithms
provided
additional
context
adjustment
decisions.
that
we
intended
remove
potential
biases
errors
measurement,
calibration,
data-handling
practices
without
removing
known
or
likely
time
trends
variations
evaluated.
compiled
adjusted
believed
be
consistent
better
0.005
salinity,
1
%
2
4
µmol
kg−1
0.01–0.02
pH
(depending
region),
5
halogenated
transient
tracers.
other
compilation,
such
isotopic
tracers
discrete
CO2
fugacity
(fCO2),
not
subjected
bias
adjustments.
original
their
documentation,
DOI
codes
at
Carbon
Acidification
System
NOAA
National
Centers
Environmental
Information
(NCEI),
which
also
provides
access
product.
This
single
file
four
regional
ones
–
Arctic,
Atlantic,
Indian,
Pacific
under
https://doi.org/10.25921/zyrq-ht66
2023).
These
bias-adjusted
files
include
significant
ancillary
approximated
obtained
interpolation
of,
calculation
from,
data.
living
documents
methods
broad
overview
secondary
procedures
results.
Earth system science data,
Journal Year:
2025,
Volume and Issue:
17(3), P. 965 - 1039
Published: March 14, 2025
Abstract.
Accurate
assessment
of
anthropogenic
carbon
dioxide
(CO2)
emissions
and
their
redistribution
among
the
atmosphere,
ocean,
terrestrial
biosphere
in
a
changing
climate
is
critical
to
better
understand
global
cycle,
support
development
policies,
project
future
change.
Here
we
describe
synthesize
datasets
methodologies
quantify
five
major
components
budget
uncertainties.
Fossil
CO2
(EFOS)
are
based
on
energy
statistics
cement
production
data,
while
from
land-use
change
(ELUC)
data
bookkeeping
models.
Atmospheric
concentration
measured
directly,
its
growth
rate
(GATM)
computed
annual
changes
concentration.
The
net
uptake
by
ocean
(SOCEAN,
called
sink)
estimated
with
biogeochemistry
models
observation-based
fCO2
products
(fCO2
fugacity
CO2).
land
(SLAND,
dynamic
vegetation
Additional
lines
evidence
sinks
provided
atmospheric
inversions,
oxygen
measurements,
Earth
system
sum
all
sources
results
imbalance
(BIM),
measure
imperfect
incomplete
understanding
contemporary
cycle.
All
uncertainties
reported
as
±1σ.
For
year
2023,
EFOS
increased
1.3
%
relative
2022,
fossil
at
10.1
±
0.5
GtC
yr−1
(10.3
when
carbonation
sink
not
included),
ELUC
was
1.0
0.7
yr−1,
for
total
emission
(including
11.1
0.9
(40.6
3.2
GtCO2
yr−1).
Also,
GATM
5.9
0.2
(2.79
0.1
ppm
yr−1;
denotes
parts
per
million),
SOCEAN
2.9
0.4
SLAND
2.3
near-zero
BIM
(−0.02
averaged
over
2023
reached
419.31
ppm.
Preliminary
2024
suggest
an
increase
+0.8
(−0.2
1.7
%)
globally
2.87
ppm,
reaching
422.45
52
above
pre-industrial
level
(around
278
1750).
Overall,
mean
trend
consistently
period
1959–2023,
overall
imbalance,
although
discrepancies
up
around
1
persist
representation
semi-decadal
variability
fluxes.
Comparison
estimates
multiple
approaches
observations
shows
following:
(1)
persistent
large
uncertainty
estimate
emissions,
(2)
low
agreement
between
different
methods
magnitude
flux
northern
extra-tropics,
(3)
discrepancy
sink.
This
living-data
update
documents
applied
this
most
recent
well
evolving
community
presented
work
available
https://doi.org/10.18160/GCP-2024
(Friedlingstein
et
al.,
2024).
Global Biogeochemical Cycles,
Journal Year:
2023,
Volume and Issue:
37(9)
Published: Aug. 24, 2023
Abstract
The
seasonal
cycle
is
the
dominant
mode
of
variability
in
air‐sea
CO
2
flux
most
regions
global
ocean,
yet
discrepancies
between
different
seasonality
estimates
are
rather
large.
As
part
Regional
Carbon
Cycle
Assessment
and
Processes
Phase
project
(RECCAP2),
we
synthesize
surface
ocean
p
from
models
observation‐based
estimates,
focusing
on
both
a
present‐day
climatology
decadal
changes
1980s
2010s.
Four
main
findings
emerge:
First,
biogeochemistry
(GOBMs)
(
products)
disagree
amplitude
phase,
primarily
due
to
DIC.
Second,
has
increased
over
last
three
decades
products
GOBMs.
Third,
increases
amplitudes
subtropical
biomes
for
GOBMs
driven
by
increasing
DIC
concentrations
stemming
uptake
anthropogenic
(C
ant
).
In
subpolar
Southern
Ocean
biomes,
however,
change
dominated
C
invasion,
whereas
an
indeterminate
combination
invasion
climate
modulates
changes.
Fourth,
biome‐aggregated
largely
detectable
against
mapping
uncertainty
(reducible)
natural
(irreducible),
but
not
at
gridpoint
scale
much
northern
oceans
Ocean,
underscoring
importance
sustained
high‐quality
seasonally
resolved
measurements
these
regions.
Journal of Advances in Modeling Earth Systems,
Journal Year:
2024,
Volume and Issue:
16(3)
Published: March 1, 2024
Abstract
The
ocean
is
a
major
carbon
sink
and
takes
up
25%–30%
of
the
anthropogenically
emitted
CO
2
.
A
state‐of‐the‐art
method
to
quantify
this
are
global
biogeochemistry
models
(GOBMs),
but
their
simulated
uptake
differs
between
systematically
lower
than
estimates
based
on
statistical
methods
using
surface
p
interior
measurements.
Here,
we
provide
an
in‐depth
evaluation
from
1980
2018
GOBM
ensemble.
As
sources
inter‐model
differences
ensemble‐mean
biases
our
study
identifies
(a)
model
setup,
such
as
length
spin‐up,
starting
date
simulation,
fluxes
rivers
into
sediments,
(b)
circulation,
Atlantic
Meridional
Overturning
Circulation
Southern
Ocean
mode
intermediate
water
formation,
(c)
oceanic
buffer
capacity.
Our
analysis
suggests
that
late
in
circulation
cause
too
low
anthropogenic
across
Surface
might
also
be
low,
current
setup
prevents
robust
assessment.
For
simulations
sink,
recommend
short‐term
start
at
common
before
industrialization
associated
atmospheric
increase,
conduct
sufficiently
long
spin‐up
GOBMs
reach
steady‐state,
key
metrics
for
biogeochemistry,
land‐ocean
interface.
In
long‐term,
improving
representation
these
GOBMs.
Elementa Science of the Anthropocene,
Journal Year:
2024,
Volume and Issue:
12(1)
Published: Jan. 1, 2024
The
air–sea
exchange
and
oceanic
cycling
of
greenhouse
gases
(GHG),
including
carbon
dioxide
(CO2),
nitrous
oxide
(N2O),
methane
(CH4),
monoxide
(CO),
nitrogen
oxides
(NOx
=
NO
+
NO2),
are
fundamental
in
controlling
the
evolution
Earth’s
atmospheric
chemistry
climate.
Significant
advances
have
been
made
over
last
10
years
understanding,
instrumentation
methods,
as
well
deciphering
production
consumption
pathways
GHG
upper
ocean
(including
surface
subsurface
down
to
approximately
1000
m).
global
under
current
conditions
is
now
established
a
major
sink
for
CO2,
source
N2O
minor
both
CH4
CO.
importance
or
NOx
largely
unknown
so
far.
There
still
considerable
uncertainties
about
processes
their
drivers
distributions
N2O,
CH4,
CO,
ocean.
Without
having
understanding
pathways,
our
knowledge
effects
ongoing
changes—warming,
acidification,
deoxygenation,
eutrophication—on
remains
rudimentary
at
best.
We
suggest
that
only
through
comprehensive,
coordinated,
interdisciplinary
approach
includes
data
collection
by
observation
networks
joint
process
studies
can
necessary
be
generated
(1)
identify
relevant
microbial
phytoplankton
communities,
(2)
quantify
rates
(3)
comprehend
drivers,
(4)
decipher
economic
cultural
implications
mitigation
solutions.
Global Biogeochemical Cycles,
Journal Year:
2024,
Volume and Issue:
38(4)
Published: April 1, 2024
Abstract
As
part
of
the
second
phase
Regional
Carbon
Cycle
Assessment
and
Processes
project
(RECCAP2),
we
present
an
assessment
carbon
cycle
Atlantic
Ocean,
including
Mediterranean
Sea,
between
1985
2018
using
global
ocean
biogeochemical
models
(GOBMs)
estimates
based
on
surface
dioxide
(CO
2
)
partial
pressure
(pCO
products)
interior
dissolved
inorganic
observations.
Estimates
basin‐wide
long‐term
mean
net
annual
CO
uptake
GOBMs
pCO
products
are
in
reasonable
agreement
(−0.47
±
0.15
PgC
yr
−1
−0.36
0.06
,
respectively),
with
higher
GOBM‐based
likely
being
a
consequence
deficit
representation
natural
outgassing
land
derived
carbon.
In
GOBMs,
increases
time
at
rates
close
to
what
one
would
expect
from
atmospheric
increase,
but
estimate
rate
twice
as
fast.
The
largest
disagreement
flux
is
found
north
50°N,
coinciding
seasonal
interannual
variability.
accumulation
anthropogenic
(C
ant
over
1994–2007
Ocean
0.52
0.11
according
28%
20%
lower
than
that
Around
70%
this
C
taken
up
atmosphere,
while
remainder
imported
Southern
through
lateral
transport.
Oceanography,
Journal Year:
2023,
Volume and Issue:
unknown
Published: Jan. 1, 2023
The
chemistry
of
the
global
ocean
is
rapidly
changing
due
to
uptake
anthropogenic
carbon
dioxide
(CO2).
This
process,
commonly
referred
as
acidification
(OA),
negatively
impacting
many
marine
species
and
ecosystems.
In
this
study,
we
combine
observations
in
surface
collected
by
NOAA
Pacific
Marine
Environmental
Laboratory
Atlantic
Oceanographic
Meteorological
scientists
their
national
international
colleagues
over
past
four
decades,
along
with
model
outputs,
provide
a
high-resolution,
regionally
varying
view
fugacity,
carbonate
ion
content,
total
hydrogen
pH
on
scale,
aragonite
calcite
saturation
states
selected
time
intervals
from
1961
2020.
We
discuss
major
roles
played
air-sea
CO2
uptake,
warming,
local
upwelling
processes,
declining
buffer
capacity
controlling
spatial
temporal
variability
these
parameters.
These
changes
are
occurring
regions
that
would
normally
be
considered
OA
refugia,
thus
threatening
protection
for
stocks
sensitive
increasing
potential
expanding
biological
impacts.