Small,
Journal Year:
2023,
Volume and Issue:
20(4)
Published: Sept. 15, 2023
Abstract
Conventional
designing
principal
of
electrocatalyst
is
focused
on
the
electronic
structure
tuning,
which
effectively
promotes
electrocatalysis.
However,
as
a
typical
kind
electrode–electrolyte
interface
reaction,
electrocatalysis
performance
also
closely
dependent
interfacial
micro‐environment
(IME),
including
pH,
reactant
concentration,
electric
field,
surface
geometry
structure,
hydrophilicity/hydrophobicity,
etc.
Recently,
organic
electro‐oxidation
reaction
(OEOR),
simultaneously
reduces
anodic
polarization
potential
and
produces
value‐added
chemicals,
has
emerged
competitive
alternative
to
oxygen
evolution
role
IME
played
in
OEOR
receiving
great
interest.
Thus,
this
article
provides
timely
review
its
applications
toward
OEOR.
In
review,
for
conventional
gas‐involving
reactions,
contrast,
first
presented,
then
recent
progresses
diverse
are
summarized;
especially,
some
representative
works
thoroughly
discussed.
Additionally,
cutting‐edge
analytical
methods
characterization
techniques
introduced
comprehensively
understand
last
section,
perspectives
challenges
regulation
shared.
Organic Process Research & Development,
Journal Year:
2024,
Volume and Issue:
28(2), P. 338 - 366
Published: Jan. 18, 2024
This
review
summarizes
examples
of
organic
electrosynthesis
from
the
peer-reviewed
literature
2000
to
2023
that
have
been
conducted
on
scales
20
g
or
above.
A
significant
portion
these
were
a
≤100
scale,
while
detailed
reports
kilogram-scale
remain
scarce
in
pharmaceutical
industry.
In
addition
chemical
transformation,
this
also
highlights
type
reactor
used
and
projected
productivity
metric
as
ways
compare
different
reports.
The
selected
scale-ups
described
herein
illustrate
remaining
challenges
currently
preventing
routine
use
large-scale
Science,
Journal Year:
2024,
Volume and Issue:
383(6679), P. 173 - 178
Published: Jan. 11, 2024
The
reactivity
of
molecular
oxygen
is
crucial
to
clean
energy
technologies
and
green
chemical
synthesis,
but
kinetic
barriers
complicate
both
applications.
In
dioxygen
should
be
able
undergo
atom
transfer
two
organic
molecules
with
perfect
economy,
such
rare.
Monooxygenase
enzymes
commonly
reductively
activate
by
sacrificing
one
the
atoms
generate
a
more
reactive
oxidant.
Here,
we
used
manganese-tetraphenylporphyrin
catalyst
pair
electrochemical
reduction
water
oxidation,
generating
manganese-oxo
at
electrodes.
This
process
supports
thioether
substrate
molecules,
equivalents
sulfoxide
single
equivalent
dioxygen.
net
dioxygenase
consumes
no
electrons
uses
overcome
barriers.
Chemical Society Reviews,
Journal Year:
2024,
Volume and Issue:
53(7), P. 3579 - 3605
Published: Jan. 1, 2024
After
sixty
years
of
development,
electrochemical
optical
spectroscopy
has
evolved
from
the
early
phase
proof-of-concept
to
an
advanced
with
various
spectroscopic
modes
and
contributed
significantly
field
electrochemistry.
Chemical Society Reviews,
Journal Year:
2024,
Volume and Issue:
53(13), P. 6917 - 6959
Published: Jan. 1, 2024
Electrochemical
energy
conversion
and
storage
are
playing
an
increasingly
important
role
in
shaping
the
sustainable
future.
Differential
electrochemical
mass
spectrometry
(DEMS)
offers
Organic Process Research & Development,
Journal Year:
2025,
Volume and Issue:
unknown
Published: Jan. 7, 2025
A
scalable
electrochemical
process
to
synthesize
iminophosphorane
ligands
is
reported.
The
application
of
these
iminophosphoranes
was
recently
reported
in
Ni-catalyzed
cross-electrophile
and
C–N
cross-couplings.
use
parallel
plate
flow
reactors
enables
the
synthesis
on
a
multigram
scale,
with
selected
examples
up
0.6
kg
scale.
Direct
crystallization
from
end
reaction
mixture
for
provides
facile
isolation
processes.
This
article
also
details
improvements
our
capabilities
across
scales,
including
addressing
material
compatibility
issues,
increasing
accessible
range
rates,
integration
analytical
technology
tools.
Chemical Reviews,
Journal Year:
2024,
Volume and Issue:
unknown
Published: Nov. 26, 2024
Cross-electrophile
coupling
(XEC),
defined
by
us
as
the
cross-coupling
of
two
different
σ-electrophiles
that
is
driven
catalyst
reduction,
has
seen
rapid
progression
in
recent
years.
As
such,
this
review
aims
to
summarize
field
from
its
beginnings
up
until
mid-2023
and
provide
comprehensive
coverage
on
synthetic
methods
current
state
mechanistic
understanding.
Chapters
are
split
type
bond
formed,
which
include
C(sp
Chemical Reviews,
Journal Year:
2024,
Volume and Issue:
124(20), P. 11348 - 11434
Published: Oct. 9, 2024
Environmental
catalysis
has
emerged
as
a
scientific
frontier
in
mitigating
water
pollution
and
advancing
circular
chemistry
reaction
microenvironment
significantly
influences
the
catalytic
performance
efficiency.
This
review
delves
into
engineering
within
liquid-phase
environmental
catalysis,
categorizing
microenvironments
four
scales:
atom/molecule-level
modulation,
nano/microscale-confined
structures,
interface
surface
regulation,
external
field
effects.
Each
category
is
analyzed
for
its
unique
characteristics
merits,
emphasizing
potential
to
enhance
efficiency
selectivity.
Following
this
overview,
we
introduced
recent
advancements
advanced
material
system
design
promote
(e.g.,
purification,
transformation
value-added
products,
green
synthesis),
leveraging
state-of-the-art
technologies.
These
discussions
showcase
was
applied
different
reactions
fine-tune
regimes
improve
from
both
thermodynamics
kinetics
perspectives.
Lastly,
discussed
challenges
future
directions
engineering.
underscores
of
intelligent
materials
drive
development
more
effective
sustainable
solutions
decontamination.
European Journal of Organic Chemistry,
Journal Year:
2024,
Volume and Issue:
27(27)
Published: May 21, 2024
Abstract
The
direct
functionalization
of
quinones
has
always
fascinated
research
communities
due
to
their
biological
and
redox
activities
subsequent
application.
Quinone
motifs
play
a
vital
role
as
precursors
for
many
bioactive
compounds
materials;
hence,
ingenious
methodologies
have
been
elaborated
exploring
these
units.
A
significant
part
the
synthetic
strategies
towards
functionalized
achieved
by
installing
substituents
on
hydroquinones,
phenols,
or
quinone
itself
different
oxidative
coupling
reactions
via
radical
pathways
with
without
utilization
metal
catalysts.
simple
C−H
bond
remains
challenging
inherited
electronic
nature
high
dissociation
energy.
This
review
article
summarizes
recent
advancement
made
through
quinones.
Our
primary
focus
will
be
approaches
mechanistic
that
appeared
in
last
two
decades,
along
short
historical
importance
family.
