Carbon capture and storage (CCS): the way forward

Energy & Environmental Science, Journal Year: 2018, Volume and Issue: 11(5), P. 1062 - 1176

Published: Jan. 1, 2018

Carbon capture and storage (CCS) is vital to climate change mitigation, has application across the economy, in addition facilitating atmospheric carbon dioxide removal resulting emissions offsets net negative emissions. This contribution reviews state-of-the-art identifies key challenges which must be overcome order pave way for its large-scale deployment.

Language: Английский

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Biological Activity of Ionic Liquids and Their Application in Pharmaceutics and Medicine

Chemical Reviews, Journal Year: 2017, Volume and Issue: 117(10), P. 7132 - 7189

Published: Jan. 26, 2017

Ionic liquids are remarkable chemical compounds, which find applications in many areas of modern science. Because their highly tunable nature and exceptional properties, ionic have become essential players the fields synthesis catalysis, extraction, electrochemistry, analytics, biotechnology, etc. Apart from physical features liquids, high biological activity has been attracting significant attention biochemists, ecologists, medical scientists. This Review is dedicated to activities with a special emphasis on potential employment pharmaceutics medicine. The accumulated data including antimicrobial cytotoxic discussed view possible drug delivery systems. Dedicated given novel active pharmaceutical ingredient-ionic liquid (API-IL) concept, suggests using traditional drugs form species. main aim this attract broad audience chemical, biological, scientists study advantages pharmaceutics. Overall, highlight importance research direction defined as “Ioliomics”, studies ions chemistry, biology,

Language: Английский

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The E factor 25 years on: the rise of green chemistry and sustainability

Green Chemistry, Journal Year: 2016, Volume and Issue: 19(1), P. 18 - 43

Published: Sept. 30, 2016

The global impact of green chemistry and sustainability the pivotal role theEfactor concept, over last twenty five years, is reviewed.

Language: Английский

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Azole-Based Energetic Salts

Chemical Reviews, Journal Year: 2011, Volume and Issue: 111(11), P. 7377 - 7436

Published: Aug. 12, 2011

ADVERTISEMENT RETURN TO ISSUEPREVReviewNEXTAzole-Based Energetic SaltsHaixiang Gao*† and Jean'ne M. Shreeve*‡View Author Information† Department of Applied Chemistry, China Agricultural University, Beijing, 100193 China‡ University Idaho, Moscow, Idaho 83844-2343, United StatesE-mail: [email protected] (H.G.); (J.M.S.).Cite this: Chem. Rev. 2011, 111, 11, 7377–7436Publication Date (Web):August 12, 2011Publication History Received31 January 2011Published online12 August inissue 9 November 2011https://pubs.acs.org/doi/10.1021/cr200039chttps://doi.org/10.1021/cr200039creview-articleACS PublicationsCopyright © 2011 American Chemical SocietyRequest reuse permissionsArticle Views10662Altmetric-Citations1020LEARN ABOUT THESE METRICSArticle Views are the COUNTER-compliant sum full text article downloads since 2008 (both PDF HTML) across all institutions individuals. These metrics regularly updated to reflect usage leading up last few days.Citations number other articles citing this article, calculated by Crossref daily. Find more information about citation counts.The Altmetric Attention Score is a quantitative measure attention that research has received online. Clicking on donut icon will load page at altmetric.com with additional details score social media presence for given article. how calculated. Share Add toView InAdd Full Text ReferenceAdd Description ExportRISCitationCitation abstractCitation referencesMore Options onFacebookTwitterWechatLinked InRedditEmail Other access optionsGet e-Alertsclose SUBJECTS:Anions,Cations,Explosives,Materials,Salts Get e-Alerts

Language: Английский

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State-of-the-Art of CO₂Capture with Ionic Liquids

Industrial & Engineering Chemistry Research, Journal Year: 2012, Volume and Issue: 51(24), P. 8149 - 8177

Published: June 1, 2012

Economical and environmental aspects are the main motivation for research on energy efficient processes search environment friendly materials CO2 capture. Currently, capture is dominated by amine-based (e.g., monoethanolamine) technologies, which very intensive less attractive from an point of view due to emissions used volatile solvent components. Ionic liquids have been proposed as a promising alternative conventional solvents, because their low volatility other interesting properties. This remarkable interest has led rapid growth literature this specific subject. The aim present review paper provide detailed overview achievements difficulties that encountered in finding suitable ionic liquid flue-gas streams. A major part includes experimental data solubility, selectivity, diffusivity different liquids. effect anions, cations, functional groups biodegradability, toxicity highlighted. Recent developments task-specific supported membranes also discussed. Scarcely available results molecular simulations, valuable tool designing evaluating liquids, reviewed. trends highlighted here can be designers navigate through massive amount theoretically possible ILs.

Language: Английский

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Deep Eutectic Solvents: Physicochemical Properties and Gas Separation Applications

Energy & Fuels, Journal Year: 2015, Volume and Issue: 29(4), P. 2616 - 2644

Published: Feb. 27, 2015

Sustainable technologies applied to energy-related applications should develop a pivotal role in the next decades. In particular, carbon dioxide capture from flue gases emitted by fossil-fueled power plants play controlling and reducing greenhouse effect. Therefore, development of new materials for purposes has merged as central research line, which many alternatives have been proposed. Ionic liquids (ILs) emerged one most promising choices capture, but spite their properties, some serious drawbacks also appeared. Deep eutectic solvents (DESs) recently considered ILs that maintain relevant such task-specific character, at same time avoid problems, mainly economic environmental viewpoints. DES production low-cost natural sources, together with almost null toxicity total biodegradability, makes these suitable platform developing gas separation agents within green chemistry framework. because characteristics DESs CO2 absorbents general separating agents, state art on physicochemical properties relationship influence mechanisms studies solubility are discussed. The objective this review work is analyze current knowledge using DESs, comparing capturing abilities those ILs, inferring weaknesses strengths proposing future directions subject.

Language: Английский

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Ionic-Liquid-Based CO₂ Capture Systems: Structure, Interaction and Process

Chemical Reviews, Journal Year: 2017, Volume and Issue: 117(14), P. 9625 - 9673

Published: July 7, 2017

The inherent structure tunability, good affinity with CO2, and nonvolatility of ionic liquids (ILs) drive their exploration exploitation in CO2 separation field, has attracted remarkable interest from both industries academia. aim this Review is to give a detailed overview on the recent advances IL-based materials, including pure ILs, solvents, membranes for capture viewpoint molecule engineering. effects anions, cations functional groups solubility selectivity as well studies degradability ILs are reviewed, developments functionalized also discussed. mechanism solvents explained by combining molecular simulation experimental characterization. Taking into consideration applications industrialization, achievements transport properties IL fluids process design processes highlighted. Finally, future research challenges perspectives commercialization materials posed.

Language: Английский

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Carbon capture with ionic liquids: overview and progress

Energy & Environmental Science, Journal Year: 2012, Volume and Issue: 5(5), P. 6668 - 6668

Published: Jan. 1, 2012

As an emerging carbon dioxide (CO2) capture technology, separating CO2 from industrial gases with ionic liquids is increasingly attracting remarkable interests. In this paper, the research progress on reviewed particular attention viewpoint of potential applications. We investigate and compare capacities pure liquids, including conventional task-specific liquid-based mixtures. The mechanisms chemisorption physisorption are explained experimental characteristics molecular simulation, which show more important roles for screening suitable tremendous candidates. Considering scaling up novel units fluids, studies transport properties hydrodynamics liquid fluids presented. process design assessment processes discussed, thermodynamic prediction models. Besides giving overview each issue above, we also provide discussions future work to try identify gap between current demand by real Finally, present some perspectives technologies, challenges will be faced while developing industrially available technologies.

Language: Английский

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Ionic Liquid Crystals: Versatile Materials

Chemical Reviews, Journal Year: 2016, Volume and Issue: 116(8), P. 4643 - 4807

Published: April 18, 2016

This Review covers the recent developments (2005–2015) in design, synthesis, characterization, and application of thermotropic ionic liquid crystals. It was designed to give a comprehensive overview "state-of-the-art" field. The discussion is focused on low molar mass dendrimeric mesogens, as well selected metal-containing compounds (metallomesogens), but some references polymeric and/or lyotropic crystals particularly liquids will also be provided. Although zwitterionic mesoionic mesogens are treated extent, emphasis directed toward liquid-crystalline materials consisting organic cations organic/inorganic anions that not covalently bound interact via electrostatic other noncovalent interactions.

Language: Английский

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Advances and Challenges for the Electrochemical Reduction of CO₂ to CO: From Fundamentals to Industrialization

Angewandte Chemie International Edition, Journal Year: 2021, Volume and Issue: 60(38), P. 20627 - 20648

Published: April 17, 2021

Abstract The electrochemical carbon dioxide reduction reaction (CO 2 RR) provides an attractive approach to convert renewable electricity into fuels and feedstocks in the form of chemical bonds. Among different CO RR pathways, conversion is considered one most promising candidate reactions because its high technological economic feasibility. Integrating catalyst electrolyte design with understanding catalytic mechanism will yield scientific insights promote this technology towards industrial implementation. Herein, we give overview recent advances challenges for selective CO. Multidimensional engineering are also summarized. Furthermore, studies on large‐scale production highlighted facilitate industrialization . To conclude, remaining future directions application generate highlighted.

Language: Английский

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