Recent progress of catalysts for synthesis of cyclic carbonates from CO2 and epoxides DOI Creative Commons
Ting Yan, Heng Liu,

Zhuoying Zeng

et al.

Journal of CO2 Utilization, Journal Year: 2022, Volume and Issue: 68, P. 102355 - 102355

Published: Dec. 21, 2022

With the continuous emission of greenhouse gases, rational transformation and utilization CO2 is particularly important. Cyclic carbonates are a kind versatile compounds have wide applications in Li-ion batteries, pharmaceutical manufacturing many fine chemicals. Cycloaddition epoxide to synthesize cyclic considered one most promising conversion routes because its 100% atomic economy, non-toxicity, as well more economic technical route for CO2. In this paper, review surveys synthesis employing building block. The mechanisms activation been described detail due thermodynamic stability molecule. reaction mechanism expounded, seven methods summarized compared, deeply analyzing research progress recent years. To reduce energy conversion, catalysts very crucial. Various types suitable derived from expounded depth. Finally, development trend prospected. improved strongly demanded successful commercialization technologies. This enables researchers timely seize current advancements thus may provide some rewarding insights future investigations on feedstock. It will good reference guide scholars achieve better improvements.

Language: Английский

Carbon capture and storage (CCS): the way forward DOI Creative Commons
Mai Bui, Claire S. Adjiman, André Bardow

et al.

Energy & Environmental Science, Journal Year: 2018, Volume and Issue: 11(5), P. 1062 - 1176

Published: Jan. 1, 2018

Carbon capture and storage (CCS) is vital to climate change mitigation, has application across the economy, in addition facilitating atmospheric carbon dioxide removal resulting emissions offsets net negative emissions. This contribution reviews state-of-the-art identifies key challenges which must be overcome order pave way for its large-scale deployment.

Language: Английский

Citations

3361
Green chemistry for nanoparticle synthesis DOI
Haohong Duan, Dingsheng Wang, Yadong Li

et al.

Chemical Society Reviews, Journal Year: 2015, Volume and Issue: 44(16), P. 5778 - 5792

Published: Jan. 1, 2015

This review describes the principles of green chemistry applied to field nanoparticle synthesis.

Language: Английский

Citations

1060
Catalytic Transformation of Lignocellulose into Chemicals and Fuel Products in Ionic Liquids DOI
Zhanrong Zhang, Jinliang Song, Buxing Han

et al.

Chemical Reviews, Journal Year: 2016, Volume and Issue: 117(10), P. 6834 - 6880

Published: Nov. 28, 2016

Innovative valorization of naturally abundant and renewable lignocellulosic biomass is great importance in the pursuit a sustainable future biobased economy. Ionic liquids (ILs) as an important kind green solvents functional fluids have attracted significant attention for catalytic transformation feedstocks into diverse range products. Taking advantage some unique properties ILs with different functions, processes can be carried out more efficiently potentially lower environmental impacts. Also, new product portfolio may derived from systems media. This review focuses on chemical conversion lignocellulose its primary ingredients (i.e., cellulose, hemicellulose, lignin) value-added chemicals fuel products using reaction An outlook provided at end this to highlight challenges opportunities associated interesting area.

Language: Английский

Citations

828
Formic acid as a hydrogen storage material – development of homogeneous catalysts for selective hydrogen release DOI
Dörthe Mellmann, Peter Sponholz, Henrik Junge

et al.

Chemical Society Reviews, Journal Year: 2016, Volume and Issue: 45(14), P. 3954 - 3988

Published: Jan. 1, 2016

Liquid energy: formic acid is an ideal candidate for catalytic release and storage of hydrogen.

Language: Английский

Citations

762
Multiscale Studies on Ionic Liquids DOI
Kun Dong, Xiaomin Liu, Haifeng Dong

et al.

Chemical Reviews, Journal Year: 2017, Volume and Issue: 117(10), P. 6636 - 6695

Published: May 10, 2017

Ionic liquids (ILs) offer a wide range of promising applications because their much enhanced properties. However, further development such materials depends on the fundamental understanding hierarchical structures and behaviors, which requires multiscale strategies to provide coupling among various length scales. In this review, we first introduce properties these typical ILs. Then, modeling methods that have been applied ILs, covering from molecular scale (QM/MM), mesoscale (CG, DPD), macroscale (CFD for unit thermodynamics COSMO-RS model environmental assessment GD method process scale). following section, discuss in some detail four scales including structures, aggregates dynamics, reactor design optimization IL applications. Finally, address concluding remarks predictive capabilities The present review aims summarize recent advances application

Language: Английский

Citations

689
Ionic liquids and their solid-state analogues as materials for energy generation and storage DOI
Douglas R. MacFarlane, Maria Forsyth, Patrick C. Howlett

et al.

Nature Reviews Materials, Journal Year: 2016, Volume and Issue: 1(2)

Published: Jan. 12, 2016

Language: Английский

Citations

590
Nanoconfined Ionic Liquids DOI
Shiguo Zhang, Jiaheng Zhang, Yan Zhang

et al.

Chemical Reviews, Journal Year: 2016, Volume and Issue: 117(10), P. 6755 - 6833

Published: Dec. 29, 2016

Ionic liquids (ILs) have been widely investigated as novel solvents, electrolytes, and soft functional materials. Nevertheless, the widespread applications of ILs in most cases hampered by their liquid state. The confinement into nanoporous hosts is a simple but versatile strategy to overcome this problem. Nanoconfined constitute new class composites with intrinsic chemistries original functions solid matrices. interplay between these two components, particularly effect interactions pore walls, further endows significantly distinct physicochemical properties restricted space compared corresponding bulk systems. aim article provide comprehensive review nanoconfined ILs. After brief introduction ILs, synthetic strategies investigation methods for are documented. local structure diverse porous summarized next sections. final section highlights potential fields, including catalysis, gas capture separation, ionogels, supercapacitors, carbonization, lubrication. Further research directions perspectives on topic also provided conclusion.

Language: Английский

Citations

577
Ionic liquids and derived materials for lithium and sodium batteries DOI
Qiwei Yang, Zhaoqiang Zhang, Xiao‐Guang Sun

et al.

Chemical Society Reviews, Journal Year: 2018, Volume and Issue: 47(6), P. 2020 - 2064

Published: Jan. 1, 2018

The ever-growing demand for advanced energy storage devices in portable electronics, electric vehicles and large scale power grids has triggered intensive research efforts over the past decade on lithium sodium batteries. key to improve their electrochemical performance enhance service safety lies development of electrode, electrolyte, auxiliary materials. Ionic liquids (ILs) are consisting entirely ions near room temperature, characterized by many unique properties such as ultralow volatility, high ionic conductivity, good thermal stability, low flammability, a wide window, tunable polarity basicity/acidity. These create possibilities designing batteries with excellent safety, energy/power density long-term also provide better ways synthesize known IL-derived materials, poly(ionic liquids), ionogels IL-tethered nanoparticles, retain most characteristics ILs while being endowed other favourable features, thus they have received great deal attention well. This review provides comprehensive various applications derived materials including Li/Na-ion, dual-ion, Li/Na-S Li/Na-air (O2) batteries, particular emphasis recent advances literature. Their enable them serve resources, medium, or ingredient almost all components electrodes, liquid electrolytes, solid artificial solid-electrolyte interphases, current collectors. Some thoughts emerging challenges opportunities presented this further development.

Language: Английский

Citations

539
Active chemisorption sites in functionalized ionic liquids for carbon capture DOI
Guokai Cui, Jianji Wang,

Suojiang Zhang

et al.

Chemical Society Reviews, Journal Year: 2016, Volume and Issue: 45(15), P. 4307 - 4339

Published: Jan. 1, 2016

Carbon capture with site-containing ionic liquids is reviewed particular attention on the activation and design of interaction sites.

Language: Английский

Citations

422
Imidazolium Ionic Liquids, Imidazolylidene Heterocyclic Carbenes, and Zeolitic Imidazolate Frameworks for CO2 Capture and Photochemical Reduction DOI
Sibo Wang, Xinchen Wang

Angewandte Chemie International Edition, Journal Year: 2015, Volume and Issue: 55(7), P. 2308 - 2320

Published: Dec. 18, 2015

Abstract Imidazolium ionic liquids (ILs), imidazolylidene N‐heterocyclic carbenes (NHCs), and zeolitic imidazolate frameworks (ZIFs) are motifs which have been extensively investigated for CO 2 adsorption conversion applications. Summarized in this minireview is the recent progress capture, activation, photochemical reduction of with these three building blocks, from homogeneous molecular entities (ILs NHCs) to heterogeneous crystalline scaffolds (ZIFs). The developments existing shortcomings their use utilizations assessed, more focus on photoredox catalysis. opportunities challenges future advancement artificial photosynthesis discussed.

Language: Английский

Citations

413