A General and Practical Approach for the Synthesis of 1,2,4‐Trioxanes Catalyzed by Silica‐Ferric Chloride DOI
Mo Zhang, Yi Han,

Jialiang Niu

et al.

Advanced Synthesis & Catalysis, Journal Year: 2017, Volume and Issue: 359(20), P. 3618 - 3625

Published: July 18, 2017

Abstract An efficient and practical method has been developed for the facile synthesis of 1,2,4‐trioxanes by condensation β‐hydroperoxy alcohols carbonyl compounds in presence a catalytic amount silica‐supported ferric chloride (FeCl 3 /SiO 2 ) at room temperature. The benefits operational simplicity, high yields potential large‐scale application. Moreover, catalyst can be readily recovered simple filtration reused up to five times while almost maintaining its activity. magnified image

Language: Английский

L-Proline functionalized magnetic nanoparticles: A novel magnetically reusable nanocatalyst for one-pot synthesis of 2,4,6-triarylpyridines DOI Creative Commons
Ali Maleki,

Razieh Firouzi‐Haji

Scientific Reports, Journal Year: 2018, Volume and Issue: 8(1)

Published: Nov. 19, 2018

In this work, an efficient method for the immobilization of L-proline on magnetic nanoparticles was offered and evaluated as a recoverable nanocatalyst synthesis 2,4,6-triarylpyridines through one-pot three-component reaction acetophenone, aryl aldehydes ammonium acetate. This article is first report catalytic application functionalized in organic reactions nanocatalyst. novel proved to be effective provided products high excellent yield under solvent-free conditions. The structure obtained characterized by Fourier transform infrared spectrophotometry (FT-IR), field-emission scanning electron microscopy (FE-SEM), thermogravimetric analysis (TGA) energy-dispersive X-ray spectroscopy (EDX). TGA result revealed that it stable up 200 °C using catalyst reactions. FE-SEM image synthesized showed has nearly core-shell spherical shape uniform size distribution with average about 80 nm. Moreover, could easily recovered facile separation forces recycled several times without significant loss its activity. benefits study are simplicity, nontoxicity, low cost, simple workup, environmentally benign nature.

Language: Английский

Citations

61

Recent developments in the synthesis of polysubstituted pyridinesviamulticomponent reactions using nanocatalysts DOI
Fatemeh Majidi Arlan, Ahmad Poursattar Marjani, Ramin Javahershenas

et al.

New Journal of Chemistry, Journal Year: 2021, Volume and Issue: 45(28), P. 12328 - 12345

Published: Jan. 1, 2021

This review describes the evolution and application of active metal-based heterometallic NPs as efficient heterogeneous catalysts for synthesis pyridine derivatives by multicomponent reactions in last decade (2010–2020).

Language: Английский

Citations

52

A Bird's‐Eye View on Deep Eutectic Solvent‐Mediated Multicomponent Synthesis of N‐Heterocycles DOI

Lokesh Kumar S,

Anushka Servesh,

Yash Kumar Sriwastav

et al.

ChemistrySelect, Journal Year: 2023, Volume and Issue: 8(16)

Published: April 24, 2023

Abstract Multicomponent reactions are crucial for operating organic synthesis. In today's world, chemists concentrate on greener methodologies that cater to rising environmental concerns. Most conventional solvents harsh the environment, which can be addressed by environmentally and pocket‐friendly Deep eutectic (DES). Organic synthesis via MCR in presence of DES has resulted blend green methodology solvent transformations. Forasmuch as addressing concerns developing higher heterocycles, our review focuses literature published DES‐mediated N ‐Heterocyclic compounds.

Language: Английский

Citations

20

Preparation and Application of Porous Materials based on Deep Eutectic Solvents DOI
Xiaoxia Li, Jinsub Choi, Wha‐Seung Ahn

et al.

Critical Reviews in Analytical Chemistry, Journal Year: 2017, Volume and Issue: 48(1), P. 73 - 85

Published: Sept. 29, 2017

Deep eutectic solvents (DESs) are a common successor to ionic liquids (ILs) with similar physicochemical properties. DESs have attracted considerable interest in related chemical research based on the superiority of over ILs and preparation porous materials. In addition, DESs-based materials been applied widely research. This review highlights properties DESs. The application DES silica polymers is also discussed. available data references this field reviewed summarize applications developments Based development DESs, exploitation new DES-based expected diversify into

Language: Английский

Citations

57

Multicomponent domino reactions in deep eutectic solvent: An efficient strategy to synthesize multisubstituted cyclohexa-1,3-dienamines DOI Creative Commons
Najmedin Azizi,

Tahereh Soleymani Ahooie,

Mohammad Mahmoudi Hashemi

et al.

Journal of Molecular Liquids, Journal Year: 2017, Volume and Issue: 246, P. 221 - 224

Published: Sept. 19, 2017

Language: Английский

Citations

55

Magnetically Separable Transition Metal Ferrites: Versatile Heterogeneous Nano‐Catalysts for the Synthesis of Diverse Bioactive Heterocycles DOI
Gurpreet Kaur, Pooja Devi,

Sheetal Thakur

et al.

ChemistrySelect, Journal Year: 2019, Volume and Issue: 4(7), P. 2181 - 2199

Published: Feb. 20, 2019

Abstract This review compiles the up to date literatures on preparations and applications of transition metal ferrites as an efficient, heterogeneous, magnetically separable nano‐catalyst for synthesis diverse bioactive heterocycles.

Language: Английский

Citations

51

Synthesis and characterization of an acidic nanostructure based on magnetic polyvinyl alcohol as an efficient heterogeneous nanocatalyst for the synthesis of α-aminonitriles DOI
Ali Maleki, Jamal Rahimi, Zoleikha Hajizadeh

et al.

Journal of Organometallic Chemistry, Journal Year: 2018, Volume and Issue: 881, P. 58 - 65

Published: Dec. 4, 2018

Language: Английский

Citations

48

Nanomagnetic reusable catalysts in organic synthesis DOI

Massoud Ghobadi,

Maryam Kargar, Ramin Javahershenas

et al.

Synthetic Communications, Journal Year: 2020, Volume and Issue: 51(5), P. 647 - 669

Published: Sept. 11, 2020

Catalysis is a key component of "green chemistry", and strategically vital for the efficient eco-friendly organic transformations. Easy recovery catalysts their reusability hot research topic in synthesis especially from perspective green chemistry. In recent times, magnetic separation has received profound attention because nanocatalysts (due to insoluble paramagnetic nature) can be readily separated reaction medium by using an external magnet, without need filtration, centrifugation or other tedious workup processes. During last decade, many magnetically recoverable have been utilized catalyze diverse range chemical reactions. The aim this review highlight progress catalytic applications various

Language: Английский

Citations

43

Based on MFe2O4(M=Co, Cu, and Ni): Magnetically recoverable nanocatalysts in synthesis of heterocyclic structural scaffolds DOI
Mosstafa Kazemi

Synthetic Communications, Journal Year: 2020, Volume and Issue: 50(13), P. 1899 - 1935

Published: Feb. 19, 2020

Catalysis research under magnetically recoverable nanocatalysts is a well-known topic in organic synthesis. In recent times, catalysis has clearly experienced renaissance the area of utility ferrite nanoparticles based on their ability to recovery and reusability. this review, focus fabrication, characterization application MFe2O4 (M=Co, Cu, Ni) synthesis heterocyclic structural scaffolds.

Language: Английский

Citations

40

DESs: Green solvents for transition metal catalyzed organic reactions DOI
Lifen Peng,

Zhifang Hu,

Qichao Lu

et al.

Chinese Chemical Letters, Journal Year: 2019, Volume and Issue: 30(12), P. 2151 - 2156

Published: June 1, 2019

Language: Английский

Citations

43