Facile synthesis of sulfinate esters from aryl iodides via direct oxidation of thioesters DOI Creative Commons
Keisuke Nakamura,

Yukiko Kumagai,

Akihiro Kobayashi

et al.

Organic & Biomolecular Chemistry, Journal Year: 2023, Volume and Issue: 21(34), P. 6886 - 6891

Published: Jan. 1, 2023

A practical method to synthesize sulfinate esters from aryl iodides is disclosed. Direct oxidation of thioesters prepared by copper-catalyzed C–S formation realized the efficient synthesis esters.

Language: Английский

Hydrogen evolution-enabled rhodaelectro-catalyzed [4+2] annulations of purines and 7-deazapurines with alkynes DOI
Chao Xu, Zhensheng Zhang, Tao Liu

et al.

Chemical Communications, Journal Year: 2022, Volume and Issue: 58(68), P. 9508 - 9511

Published: Jan. 1, 2022

A series of polycyclic purinium and 7-deazapurinium salts were obtained via rhodaelectro-catalyzed [4+2] annulations with H 2 evolution.

Language: Английский

Citations

13
Electrochemical Synthesis of Sulfinic and Sulfonic Esters from Sulfonyl Hydrazides DOI

Suji Kim,

Sunwoo Lee

Organic & Biomolecular Chemistry, Journal Year: 2024, Volume and Issue: 22(22), P. 4436 - 4444

Published: Jan. 1, 2024

Electrochemical synthesis of sulfinic and sulfonic esters from sulfonyl hydrazides yields insights into radical-mediated pathways, optimizing ester production.

Language: Английский

Citations

2
Copper‐Catalyzed Synthesis of Sulfinic Esters via Oxidative Coupling of Thiols or Disulfides with Alcohols DOI
Nobukazu Taniguchi

Asian Journal of Organic Chemistry, Journal Year: 2024, Volume and Issue: 13(8)

Published: June 5, 2024

Abstract The copper‐catalyzed coupling of thiols with alcohols was achieved under air atmosphere. reaction proceeded smoothly in the presence a base such as Cs 2 CO 3 or Rb affording sulfinic esters good yields. Furthermore, disulfides were also available procedure. Both sulfide‐groups on disulfide efficiently consumed.

Language: Английский

Citations

2
Controllable cross-coupling of thiophenols with dichloromethane mediated by consecutively paired electrolysis DOI Creative Commons

Ting Zeng,

Jianjing Yang, Kelu Yan

et al.

Green Synthesis and Catalysis, Journal Year: 2022, Volume and Issue: 4(1), P. 35 - 40

Published: April 9, 2022

Chloroalkanes are important building blocks in the synthesis, but their use redox chemistry is limited by negative reduction potentials. Electrosynthesis can precisely control reaction energy just adjusting current or voltage to achieve selectivity of regulation. In this study, consecutively paired electrolytic-mediated controllable radical cross-coupling thiophenols with dichloromethane was developed deliver dithioacetals, sulfides, and sulfoxides absence electrochemical mediator conditions. It features broad substrate scope, simple operation, gram-scale eco-friendly. Mechanistic studies reveal that radical-induced dichloromethane.

Language: Английский

Citations

10
Facile synthesis of sulfinate esters from aryl iodides via direct oxidation of thioesters DOI Creative Commons
Keisuke Nakamura,

Yukiko Kumagai,

Akihiro Kobayashi

et al.

Organic & Biomolecular Chemistry, Journal Year: 2023, Volume and Issue: 21(34), P. 6886 - 6891

Published: Jan. 1, 2023

A practical method to synthesize sulfinate esters from aryl iodides is disclosed. Direct oxidation of thioesters prepared by copper-catalyzed C–S formation realized the efficient synthesis esters.

Language: Английский

Citations

6