Advanced Synthesis & Catalysis,
Journal Year:
2023,
Volume and Issue:
365(6), P. 900 - 905
Published: Feb. 20, 2023
Herein,
we
report
the
development
of
transition-metal-catalyst-
and
external-oxidant-free
electrochemical
cross-coupling
hydrogen-evolution
chemistry
involving
glycine
amides
diarylphosphine
oxides.
A
broad
range
biologically
active
α-aminophosphonates
was
obtained
in
moderate
to
good
yields
a
clean
sustainable
manner.
Moreover,
TBAB
(tetrabutylammonium
bromide)
electrolyte
recycled
four
times
without
obvious
loss
reaction
activity.
this
protocol
performed
on
gram
scale
under
slightly
modified
electrolytic
conditions
or
combination
with
continuous
flow
microreactor
technology.
Control
experiments
were
used
disclose
possible
free-radical
mechanism.
As
service
our
authors
readers,
journal
provides
supporting
information
supplied
by
authors.
Such
materials
are
peer
reviewed
may
be
re-organized
for
online
delivery,
but
not
copy-edited
typeset.
Technical
support
issues
arising
from
(other
than
missing
files)
should
addressed
Please
note:
The
publisher
is
responsible
content
functionality
any
Any
queries
content)
directed
corresponding
author
article.
Green Synthesis and Catalysis,
Journal Year:
2021,
Volume and Issue:
2(2), P. 165 - 178
Published: March 29, 2021
There
is
a
resurgence
of
interests
in
organic
electrochemistry,
which
generally
accepted
as
green
synthetic
tool.
In
this
context,
many
electrochemical
methods
have
been
developed
the
past
decade
to
access
various
nitrogen-centered
radicals
(NCRs)
from
readily
available
precursors
controlled
fashion,
enabling
rapid
development
NCR-mediated
new
reactions
for
construction
nitrogen-containing
compounds.
review,
recent
advances
chemistry
electrochemically
generated
NCRs
are
critically
highlighted,
based
on
strategies
their
formation
and
types
NCRs.
Focus
put
mechanism
generation
different
applications.
Green Chemistry,
Journal Year:
2021,
Volume and Issue:
23(11), P. 3950 - 3954
Published: Jan. 1, 2021
An
electrochemical
multicomponent
reaction
was
established
under
catalyst-,
chemical-oxidant-free
and
mild
conditions,
which
provides
an
eco-friendly
simple
protocol
for
constructing
4-selanylpyrazoles
from
easily
available
raw
materials
with
high
yields.
Green Synthesis and Catalysis,
Journal Year:
2021,
Volume and Issue:
2(1), P. 19 - 26
Published: Feb. 1, 2021
As
one
of
the
most
important
biogeochemical
cycles,
carbon
dioxide
(CO2)
cycle
between
atmosphere
and
biosphere
has
a
profound
impact
on
life
earth.
Therefore,
search
for
sustainable
solutions
to
normalize
currently
unbalanced
is
central
research
topic
many
scientific
disciplines.
The
green
electrocatalysis
offers
very
promising
answer
cycle.
In
this
review,
recent
advances
in
enabled
CO2
including
electrochemical
carboxylation
decarboxylative
functionalization
carboxylic
acids
are
highlighted.
Angewandte Chemie International Edition,
Journal Year:
2022,
Volume and Issue:
61(47)
Published: June 7, 2022
Over
the
past
two
decades,
electro-organic
synthesis
has
gained
significant
interest,
both
in
technical
and
academic
research
as
well
terms
of
applications.
The
omission
stoichiometric
oxidizers
or
reducing
agents
enables
a
more
sustainable
route
for
redox
reactions
organic
chemistry.
Even
if
it
is
well-known
that
every
electrochemical
oxidation
only
viable
with
an
associated
reduction
reaction
vice
versa,
relevance
counter
often
less
addressed.
In
this
Review,
importance
corresponding
highlighted
how
can
affect
performance
selectivity
electrolytic
conversion.
A
selection
common
strategies
unique
concepts
to
tackle
issue
are
surveyed
provide
guide
select
appropriate
synthesis.
Green Chemistry,
Journal Year:
2023,
Volume and Issue:
25(14), P. 5539 - 5542
Published: Jan. 1, 2023
With
formaldehyde
as
an
atom-economical
carbonyl
synthon,
the
EtOH-catalyzed
electrochemical
multicomponent
synthesis
of
various
imidazolidine-fused
sulfamidates
under
organic
oxidant-free,
energy-saving
and
mild
conditions
was
developed.
The Chemical Record,
Journal Year:
2021,
Volume and Issue:
21(9), P. 2585 - 2600
Published: April 8, 2021
Progress
in
electroorganic
synthesis
is
linked
to
innovation
of
new
synthetic
reactions
with
impact
on
medicinal
chemistry
and
drug
discovery
the
desire
minimise
waste
provide
energy-efficient
chemical
transformations
for
future
industrial
processes.
Paired
electrosynthetic
processes
that
combine
use
both
anode
cathode
(convergent
or
divergent)
minimal
(or
without)
intentionally
added
electrolyte
need
additional
reagents
are
growing
interest.
In
this
overview,
recent
progress
developing
paired
electrolytic
surveyed.
The
discussion
focuses
electrosynthesis
technology
proven
value
preparation
small
molecules.
Reactor
types
contrasted
concept
translating
light-energy
driven
photoredox
into
highlighted
as
a
newly
emerging
trend.
Green Synthesis and Catalysis,
Journal Year:
2021,
Volume and Issue:
2(2), P. 233 - 236
Published: April 8, 2021
An
electrochemical
transient
iodination
and
coupling
reaction
has
been
designed
for
constructing
selenylated
4-anilinocoumarins
via
the
domino
reactions
of
diorganyl
diselenides
under
base-,
chemical
oxidant-
external
electrolyte-free
conditions.
Green Chemistry,
Journal Year:
2022,
Volume and Issue:
24(13), P. 5058 - 5063
Published: Jan. 1, 2022
The
electrochemical
annulation
of
enaminones/analogous
enamines
and
thioureas
providing
2-aminothiazoles
has
been
realized.
Modulating
the
electrolyte
enables
diastereoselective
synthesis
4,5-dialkoxyl
thiazolines
by
dearomatization.
